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公开(公告)号：US09938467B2
公开(公告)日：2018-04-10
申请号：US15357039
申请日：2016-11-21
申请人： UT-BATTELLE, LLC
IPC分类号： B01J29/42 , B01J29/48 , C10G3/00 , B01J29/46 , C12P7/06 , C12P7/08 , C12P7/10 , B01J37/02 , B01J29/06 , B01J29/072 , B01J29/076 , B01J35/02 , B01J35/04 , C07C1/22 , C12P7/16 , B01J29/14 , B01J29/16 , B01J29/68 , B01J29/69 , B01J29/76 , B01J29/78
CPC分类号： C10G3/49 , B01J29/061 , B01J29/072 , B01J29/076 , B01J29/143 , B01J29/146 , B01J29/163 , B01J29/166 , B01J29/46 , B01J29/48 , B01J29/68 , B01J29/69 , B01J29/7615 , B01J29/7661 , B01J29/7669 , B01J29/7692 , B01J29/7815 , B01J29/7861 , B01J29/7869 , B01J29/7892 , B01J35/023 , B01J35/04 , B01J37/0246 , B01J2229/183 , B01J2229/186 , C07C1/22 , C10G3/45 , C10G2300/1011 , C10G2300/1014 , C10G2300/4006 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C12P7/06 , C12P7/08 , C12P7/10 , C12P7/16 , Y02E50/10 , Y02E50/16 , Y02E50/17 , Y02P30/20
摘要： A method for converting an alcohol to a hydrocarbon, the method comprising contacting said alcohol with a metal-loaded zeolite catalyst at a temperature of at least 100° C. and up to 550° C., wherein said alcohol can be produced by a fermentation process, said metal is a positively-charged metal ion, and said metal-loaded zeolite catalyst is catalytically active for converting said alcohol to said hydrocarbon.
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公开(公告)号：US20180085742A1
公开(公告)日：2018-03-29
申请号：US15829316
申请日：2017-12-01
IPC分类号： B01J29/74 , B01J37/18 , B01J37/10 , B01J37/08 , B01J29/72 , C07C5/27 , B01J37/02 , B01J37/00 , B01J35/10 , B01J29/76 , C07C15/08
CPC分类号： B01J29/74 , B01J29/7269 , B01J29/7469 , B01J29/7669 , B01J35/1042 , B01J35/1047 , B01J35/108 , B01J37/0009 , B01J37/0201 , B01J37/08 , B01J37/10 , B01J37/18 , B01J2229/14 , B01J2229/18 , B01J2229/36 , B01J2229/42 , C07C5/2737 , C07C5/2775 , C07C2529/74 , Y02P20/52 , C07C15/08
摘要： The invention concerns a catalyst comprising at least one zeolite with structure type MTW, a matrix, at least one metal from group VIII of the periodic classification of the elements, said catalyst having a mesopore volume increased by at least 10% compared with its initial mesopore volume, which is generally in the range 0.55 to 0.75 mL/g, at the end of a treatment with steam at a partial pressure in the range 0.01 to 0.07 MPa and at a temperature in the range 300° C. to 400° C. for at least 0.5 hour. The invention concerns the process for the preparation of said catalyst as well as an isomerization process employing said catalyst.
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公开(公告)号：US20170144947A1
公开(公告)日：2017-05-25
申请号：US15240830
申请日：2016-08-18
CPC分类号： C07C2/76 , B01J29/405 , B01J29/44 , B01J29/46 , B01J29/48 , B01J29/655 , B01J29/67 , B01J29/68 , B01J29/69 , B01J29/708 , B01J29/7084 , B01J29/7088 , B01J29/7092 , B01J29/7096 , B01J29/7461 , B01J29/7469 , B01J29/7476 , B01J29/7484 , B01J29/7492 , B01J29/7661 , B01J29/7669 , B01J29/7676 , B01J29/7684 , B01J29/7692 , B01J29/7861 , B01J29/7869 , B01J29/7876 , B01J29/7884 , B01J29/7892 , B01J29/80 , B01J29/87 , B01J29/90 , B01J35/023 , B01J38/14 , B01J2229/18 , B01J2229/32 , C07C1/20 , C07C2/64 , C07C2/78 , C07C2/82 , C07C5/333 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/48 , C07C2529/65 , C07C2529/67 , C07C2529/68 , C07C2529/69 , C07C2529/70 , C07C2529/74 , C07C2529/76 , C07C2529/78 , Y02P20/584 , C07C15/02 , C07C11/02
摘要： The invention relates to the production of aromatic hydrocarbon by the conversion of a feed comprising saturated hydrocarbon. At least a portion of the saturated hydrocarbon is converted to olefinic hydrocarbon. Aromatic hydrocarbon is produced from at least a portion of the olefinic hydrocarbon using at least one dehydrocyclization catalyst comprising dehydrogenation and molecular sieve components.
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公开(公告)号：US09597670B2
公开(公告)日：2017-03-21
申请号：US13002381
申请日：2009-06-24
申请人： Carolus Maria Ballegoy , Dinyar Khushroo Captain , Joseph Cornelis Van Giezen , Lucas Petrus Simon Keyzer , Nicoleta Cristina Nenu , Ingrid Maria Van Vegchel
发明人： Carolus Maria Ballegoy , Dinyar Khushroo Captain , Joseph Cornelis Van Giezen , Lucas Petrus Simon Keyzer , Nicoleta Cristina Nenu , Ingrid Maria Van Vegchel
IPC分类号： B01J29/06 , B01J29/74 , B01J29/76 , C07C5/27 , B01J35/02 , B01J29/72 , B01J35/00 , B01J35/10
CPC分类号： B01J29/7469 , B01J29/7269 , B01J29/7669 , B01J35/0026 , B01J35/023 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J2229/16 , B01J2229/20 , B01J2229/42 , C07C5/2754 , C07C5/2791 , C07C2529/70 , C07C2529/72 , C07C2529/74 , C07C2529/76 , Y02P20/52 , C07C15/08
摘要： An alkylaromatics isomerisation catalyst, which catalyst comprises at least 50 wt % of an inorganic binder; at least 0.01 wt % of a Group VIII metal and 1-9 wt % ZSM-12 zeolite wherein the silica to alumina molar ratio (SAR) of the ZSM-12 zeolite is in the range of from 60 to 200, and a process for the isomerisation of alkylaromatics to provide a reaction mixture, said process comprising contacting a hydrocarbon stream comprising alkylaromatics with such catalyst.
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5.发明申请MODIFIED CATALYST WITH STRUCTURE TYPE MTW, A METHOD FOR ITS PREPARATION AND ITS USE IN A PROCESS FOR THE ISOMERIZATION OF AN AROMATIC C8 CUT 审中-公开具有结构类型MTW的改性催化剂，其制备方法及其在芳族C8 CUT异构化方法中的用途公开(公告)号：US20150321183A1
公开(公告)日：2015-11-12
申请号：US14654117
申请日：2013-12-04
CPC分类号： B01J29/74 , B01J29/7269 , B01J29/7469 , B01J29/7669 , B01J35/1042 , B01J35/1047 , B01J35/108 , B01J37/0009 , B01J37/0201 , B01J37/08 , B01J37/10 , B01J37/18 , B01J2229/14 , B01J2229/18 , B01J2229/36 , B01J2229/42 , C07C5/2737 , C07C5/2775 , C07C2529/74 , Y02P20/52 , C07C15/08
摘要： The invention concerns a catalyst comprising at least one zeolite with structure type MTW, a matrix, at least one metal from group VIII of the periodic classification of the elements, said catalyst having a mesopore volume increased by at least 10% compared with its initial mesopore volume, which is generally in the range 0.55 to 0.75 mL/g, at the end of a treatment with steam at a partial pressure in the range 0.01 to 0.07 MPa and at a temperature in the range 300° C. to 400° C. for at least 0.5 hour. The invention concerns the process for the preparation of said catalyst as well as an isomerization process employing said catalyst.
摘要翻译： 本发明涉及包含至少一种结构类型为MTW的沸石的催化剂，一种基质，至少一种元素周期分级的VIII族金属，所述催化剂的中孔体积比其初始中孔增加至少10％ 体积，其通常在0.55至0.75mL / g的范围内，在分压为0.01至0.07MPa的蒸汽处理结束时和在300℃至400℃的温度下。 至少0.5小时。 本发明涉及制备所述催化剂的方法以及采用所述催化剂的异构化方法。
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6.发明授权Process for improving quality as a fuel of hydrotreated hydrocarbon blends 有权用于提高作为加氢处理的烃共混物的燃料的质量的方法公开(公告)号：US08236171B2
公开(公告)日：2012-08-07
申请号：US11480369
申请日：2006-07-05
申请人： Roberto Giardino , Vincenzo Calemma , Ugo Cornaro
发明人： Roberto Giardino , Vincenzo Calemma , Ugo Cornaro
CPC分类号： B01J35/1061 , B01J21/12 , B01J23/40 , B01J29/7469 , B01J29/7669 , B01J35/1023 , B01J35/1038 , B01J35/1042 , B01J35/1057 , C10G2300/1044 , C10G2300/1051 , C10G2300/1055 , C10G2300/307 , C10G2300/4018 , C10G2400/04
摘要： A process is described for improving the quality as a fuel of hydrotreated hydrocarbon blends by reaction with hydrogen in the presence of a bifunctional catalytic system comprising one or more metals selected from Pt, Pd, Ir, Ru, Rh and Re, and a silico-aluminate of an acidic nature, selected from a micro-mesoporous silico-alumina and a zeolite belonging to the MTW family. The process of the invention produces an increase in the cetane index and a decrease in the density and T95.
摘要翻译： 描述了一种方法，用于在包含一种或多种选自Pt，Pd，Ir，Ru，Rh和Re的金属的双功能催化体系存在下，通过与氢反应，提高作为加氢处理的烃共混物的燃料的质量， 酸性的铝酸盐，选自微孔介质硅 - 氧化铝和属于MTW族的沸石。 本发明的方法产生十六烷指数的增加和密度的降低以及T95。
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公开(公告)号：US20180273852A1
公开(公告)日：2018-09-27
申请号：US15762009
申请日：2016-06-01
发明人： Raman RAVISHANKAR , Sunil MEHLA , Somnath KUKADE , Peddy Venkata Chalapathi RAO , Nettem Venkateswarlu CHOUDARY
CPC分类号： C10G11/05 , B01J29/46 , B01J29/7615 , B01J29/7653 , B01J29/7661 , B01J29/7669 , B01J29/7676 , B01J29/80 , B01J29/85 , B01J37/0045 , B01J2229/186 , B01J2229/42 , C10G11/18 , C10G2300/70
摘要： The present disclosure relates to an additive and a catalyst composition for a catalytic cracking process of vacuum gas oil for preparing cracked run naphtha having reduced liquid olefin content, and increased propylene and butylene yields in the LPG fraction. The process makes use of a catalyst composition which is a mixture of an FCC equilibrated catalyst and an additive comprising a zeolite, phosphorus and a combination of metal promoters. The process is successful in achieving high propylene and butylene yields in the LPG fraction along with a lower liquid olefin content and increased aromatic content with increase in RON unit in the resultant cracked run naphtha, as compared to that achieved using an FCC equilibrated catalyst alone.
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公开(公告)号：US10071938B2
公开(公告)日：2018-09-11
申请号：US15240829
申请日：2016-08-18
CPC分类号： C07C2/76 , B01J29/40 , B01J29/405 , B01J29/44 , B01J29/46 , B01J29/48 , B01J29/655 , B01J29/67 , B01J29/68 , B01J29/69 , B01J29/708 , B01J29/7084 , B01J29/7088 , B01J29/7092 , B01J29/7096 , B01J29/7461 , B01J29/7469 , B01J29/7476 , B01J29/7484 , B01J29/7492 , B01J29/7661 , B01J29/7669 , B01J29/7676 , B01J29/7684 , B01J29/7692 , B01J29/7861 , B01J29/7869 , B01J29/7876 , B01J29/7884 , B01J29/7892 , B01J29/80 , B01J29/87 , B01J29/90 , B01J35/023 , B01J38/14 , B01J2229/18 , B01J2229/32 , C07C2529/40 , Y02P20/52 , Y02P20/584 , C07C15/04 , C07C15/06 , C07C15/08
摘要： The invention relates to the production of aromatic hydrocarbon by the conversion of a feed comprising C2+ non-aromatic hydrocarbon, e.g., natural gas. The invention is particularly useful in converting natural gas to liquid-phase aromatic hydrocarbon, which can be more easily transported away from remote natural gas production facilities. The conversion is carried out in the presence of a dehydrocyclization catalyst comprising dehydrogenation and molecular sieve components. The dehydrocyclization catalyst has an average residence time of 90 seconds or less.
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公开(公告)号：US20170072387A1
公开(公告)日：2017-03-16
申请号：US15121905
申请日：2015-02-26
发明人： Nagesh Sharma , Ajay Kumar , Anilkumar Mettu , Veera Venkata Satya Bhaskara Sita Rama Murthy Katravulapalli , Kalpana Gopalakrishna , Raksh Vir Jasra
IPC分类号： B01J29/068 , C10G35/095 , B01J37/08 , B01J37/02 , B01J37/06
CPC分类号： B01J29/068 , B01J29/072 , B01J29/076 , B01J29/084 , B01J29/088 , B01J29/126 , B01J29/146 , B01J29/18 , B01J29/185 , B01J29/22 , B01J29/24 , B01J29/26 , B01J29/40 , B01J29/405 , B01J29/42 , B01J29/44 , B01J29/46 , B01J29/48 , B01J29/7007 , B01J29/7034 , B01J29/7038 , B01J29/7057 , B01J29/7415 , B01J29/7469 , B01J29/7615 , B01J29/7669 , B01J29/7815 , B01J29/7869 , B01J35/0006 , B01J35/023 , B01J37/0215 , B01J37/0236 , B01J37/0242 , B01J37/0246 , B01J37/06 , B01J37/08 , B01J2229/186 , B01J2229/64 , C10G35/09 , C10G35/095
摘要： The present disclosure relates to a process for preparing a catalyst. The process comprises coating zeolite gel over the alumina support to obtain a chloride free zeolite gel coated alumina support, crystallizing the chloride free zeolite gel coated alumina support, washing, drying and calcining the crystallized zeolite coated alumina support to obtain a calcined crystallized chloride free zeolite coated alumina support, treating the calcined crystallized chloride free zeolite coated alumina support with ammonium nitrate to obtain sodium free support, washing, drying, and calcining the support to obtain a calcined chloride free zeolite coated alumina support, immersing the calcined chloride free zeolite coated alumina support in an active metal and a promoter metal solution mixture followed by stirring to obtain a metal coated chloride free zeolite coated alumina support, and drying and calcining the metal coated chloride free zeolite coated alumina support to obtain the catalyst.
摘要翻译： 本发明涉及制备催化剂的方法。 该方法包括在氧化铝载体上涂布沸石凝胶以获得无氯化物的沸石凝胶涂覆的氧化铝载体，结晶无氯化物的沸石凝胶涂覆的氧化铝载体，洗涤，干燥和煅烧结晶的沸石涂覆的氧化铝载体以获得煅烧的无结晶氯化物的沸石 涂覆氧化铝载体，用硝酸铵处理煅烧的无结晶氯化物的沸石涂层的氧化铝载体以获得无钠载体，洗涤，干燥和煅烧载体以获得无煅烧氯化物的沸石涂覆的氧化铝载体，将煅烧过的无氯化物的沸石涂覆的氧化铝 在活性金属和助催化剂金属溶液混合物中进行支持，随后搅拌以获得金属涂覆的无氯化物沸石涂层的氧化铝载体，并干燥和煅烧金属涂覆的无氯化物的沸石涂覆的氧化铝载体以获得催化剂。
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公开(公告)号：US20150105236A1
公开(公告)日：2015-04-16
申请号：US14574741
申请日：2014-12-18
CPC分类号： B01J29/80 , B01J29/7669 , B01J35/006 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J37/0009 , B01J37/0201 , B01J37/04 , B01J2229/186 , C10G2/33 , C10G2/332 , C10G2/333 , C10G2/334
摘要： Disclosed are hybrid Fischer-Tropsch catalysts containing cobalt deposited on hybrid supports. The hybrid supports contain an acidic zeolite component and a silica-containing material. It has been found that the use of the hybrid Fischer-Tropsch catalysts in synthesis gas conversion reactions results in high C5+ productivity, high CO conversion rates and low olefin formation.
摘要翻译： 公开了含有沉积在混合载体上的钴的混合费 - 托催化剂。 杂化载体含有酸性沸石组分和含二氧化硅的材料。 已经发现，在合成气转化反应中使用混合费 - 托催化剂导致高的C5 +生产率，高CO转化率和低烯烃形成。
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