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    Process for the production of paraffinic middle distillates
    3.
    发明授权
    Process for the production of paraffinic middle distillates 有权
    生产石蜡中间馏分的方法

    公开(公告)号：US07427348B2

    公开(公告)日：2008-09-23

    申请号：US10481878

    申请日：2002-06-26

    申请人： Vincenzo Calemma ,  Silvia Guanziroli ,  Silvia Pavoni ,  Roberto Giardino

    发明人： Vincenzo Calemma ,  Silvia Guanziroli ,  Silvia Pavoni ,  Roberto Giardino

    IPC分类号： C10G45/00 ,  C10G47/02

    CPC分类号： C10G65/12 ,  Y10S208/95

    摘要： A process with an increased efficiency for the preparation of middle distillates with excellent properties at low temperatures and substantially without oxygenated organic compounds, starting from a synthetic mixture of hydrocarbons at least partly waxy, containing a fraction of alcohols, comprising the separation of the mixture into a low-boiling fraction and a high-boiling fraction; the subsequent hydrogenation of the low-boiling fraction under such conditions as to avoid any substantial variation in its average molecular weight; the joining of at least a part of the hydrogenated fraction with said high-boiling fraction, and the subsequent catalytic hydrocracking treatment of the mixture of hydrocarbons thug formed, to obtain a substantial conversion of the waxy part into middle distillate.

    摘要翻译： 一种具有提高效率的方法，其在低温下基本上没有含氧有机化合物具有优异性能的中间馏分的制备，起始于含有一部分醇的至少部分蜡状的烃的合成混合物，包括将混合物分离成 低沸点馏分和高沸点馏分; 随后在这样的条件下对低沸点馏分进行氢化，以避免其平均分子量的任何实质性变化; 氢化部分的至少一部分与所述高沸点馏分的接合以及所形成的碳氢化合物混合物的随后的催化加氢裂化处理，以获得将蜡状部分实质上转化为中间馏分。

    Process for the preparation of middle distillates and lube bases starting from synthetic hydrocarbon feedstocks
    5.
    发明授权
    Process for the preparation of middle distillates and lube bases starting from synthetic hydrocarbon feedstocks 有权
    从合成烃原料开始制备中间馏分和润滑油基料的方法

    公开(公告)号：US07534340B2

    公开(公告)日：2009-05-19

    申请号：US10563449

    申请日：2004-06-28

    申请人： Vincenzo Calemma ,  Cristina Flego ,  Luciano Cosimo Carluccio ,  Wallace Parker ,  Roberto Giardino ,  Giovanni Faraci

    发明人： Vincenzo Calemma ,  Cristina Flego ,  Luciano Cosimo Carluccio ,  Wallace Parker ,  Roberto Giardino ,  Giovanni Faraci

    IPC分类号： C10G47/00 ,  C10G45/00 ,  C10G7/00 ,  C07C4/02 ,  C07C5/22 ,  B01J21/00

    CPC分类号： C10G47/14

    摘要： Process for the contemporaneous production of fuels and lubricating bases from synthetic paraffinic mixtures, which includes a hydrocracking step in the presence of a solid bi-functional catalyst comprising: (A) a support of an acidic nature consisting of a catalytically active porous solid, including silicon, aluminum, phosphorus and oxygen bonded to one another in such a way as to form a mixed amorphous solid characterized by an Si/Al atomic ratio of between 15 and 250, a P/Al ratio of at least 0.1, but lower than 5, a total pore volume ranging from 0.5 to 2.0 ml/g, with an average pore diameter ranging from 3 nm. to 40 nm, and a specific surface area ranging from 200 to 1000 M2/g; (B) at least one metal with a hydro-dehydrogenating activity selected from groups 6 to 10 of the periodic table of elements, dispersed on said support (A) in an amount of between 0.05 and 5% by weight with respect to the total weight of the catalyst.

    摘要翻译： 同时生产来自合成链烷烃混合物的燃料和润滑基料的方法，其包括在固体双功能催化剂存在下的加氢裂化步骤，其包括：（A）由催化活性多孔固体组成的酸性载体，包括 硅，铝，磷和氧彼此结合，以形成以Si / Al原子比为15至250，P / Al比至少为0.1但小于5的混合无定形固体 ，总孔体积为0.5-2.0ml / g，平均孔径为3nm。 至40nm，比表面积为200〜1000M2 / g; （B）至少一种具有选自元素周期表第6至10族的加氢脱氢活性的金属，相对于总重量分散在所述载体（A）上的量为0.05-5重量％ 的催化剂。

    Difunctional catalyst effective in wax hydroisomerization and process for preparing it
    7.
    发明授权
    Difunctional catalyst effective in wax hydroisomerization and process for preparing it 失效
    在蜡加氢异构化中有效的双官能催化剂及其制备方法

    公开(公告)号：US5981419A

    公开(公告)日：1999-11-09

    申请号：US197698

    申请日：1998-11-23

    申请人： Angela Carati ,  Cristina Flego ,  Vincenzo Calemma

    发明人： Angela Carati ,  Cristina Flego ,  Vincenzo Calemma

    IPC分类号： B01J29/86 ,  C10G45/64 ,  B01J29/064

    CPC分类号： B01J29/86 ,  C10G45/64

    摘要： Process for the hydroisomerization of n-paraffins in the presence of a difunctional catalyst which comprises:(a) a porous crystalline material isostructural with beta-zeolite selected from boro-silicate (BOR-B) and boro-alumino-silicate (AL-BOR-B) in which the molar SiO.sub.2 :Al.sub.2 O.sub.3 ratio is higher than 300:1;(b) one or more metal(s) belonging to Group VIIIA, selected from platinum and palladium, in an amount comprised within the range of from 0.05 to 5% by weight.

    摘要翻译： 在双官能催化剂存在下，正链烷烃的加氢异构化方法，该方法包括：（a）使用选自硼硅酸盐（BOR-B）和硼硅铝酸盐（AL-BOR）的β-沸石同构结构的多孔结晶材料 -B），其中SiO 2：Al 2 O 3摩尔比高于300:1; （b）选自铂和钯的属于VIIIA族的一种或多种金属，其量为0.05-5重量％。