公开(公告)号：US11655157B2

公开(公告)日：2023-05-23

申请号：US16698636

申请日：2019-11-27

Applicant: NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITY ,  FURUKAWA ELECTRIC CO., LTD.

Inventor： Takao Masuda ,  Yuta Nakasaka ,  Takuya Yoshikawa ,  Sadahiro Kato ,  Masayuki Fukushima ,  Kojiro Inamori ,  Hiroko Takahashi ,  Yuichiro Banba ,  Kaori Sekine

IPC: B01J29/06 ,  C01B39/02 ,  B01J29/18 ,  B01J35/02 ,  B01J35/10 ,  B01J37/02 ,  B01J37/10 ,  B01J29/035 ,  B01J29/04 ,  B01J37/08 ,  B01J29/12 ,  B01J29/03 ,  B01J29/14 ,  B01J29/072 ,  B01J29/08 ,  B01J29/20 ,  B01J29/24 ,  B01J29/064 ,  B01J29/10 ,  B01J29/076 ,  B01J29/44 ,  B01J29/42 ,  B01J29/16 ,  B01J29/22 ,  B01J29/65 ,  B01J29/48 ,  B01J29/40 ,  B01J29/64 ,  B01J29/61 ,  B01J29/63 ,  B01J29/46 ,  B01J29/26 ,  B01J29/62 ,  B01J29/60 ,  B01J29/70 ,  B01J29/66 ,  B01J29/69 ,  B01J29/68 ,  B01J29/76 ,  B01J29/67 ,  B01J29/72 ,  B01J29/78 ,  B01J29/74 ,  B01J23/32 ,  B01J23/34 ,  B01J23/36 ,  B01J23/38 ,  B01J23/06 ,  B01J23/10 ,  B01J23/16 ,  B01J23/745 ,  B82Y30/00

CPC classification number: C01B39/026 ,  B01J23/06 ,  B01J23/10 ,  B01J23/16 ,  B01J23/32 ,  B01J23/34 ,  B01J23/36 ,  B01J23/38 ,  B01J23/745 ,  B01J29/035 ,  B01J29/0308 ,  B01J29/0352 ,  B01J29/0354 ,  B01J29/0356 ,  B01J29/0358 ,  B01J29/041 ,  B01J29/043 ,  B01J29/044 ,  B01J29/064 ,  B01J29/072 ,  B01J29/076 ,  B01J29/085 ,  B01J29/10 ,  B01J29/12 ,  B01J29/14 ,  B01J29/16 ,  B01J29/18 ,  B01J29/185 ,  B01J29/20 ,  B01J29/22 ,  B01J29/24 ,  B01J29/26 ,  B01J29/405 ,  B01J29/42 ,  B01J29/44 ,  B01J29/46 ,  B01J29/48 ,  B01J29/605 ,  B01J29/61 ,  B01J29/62 ,  B01J29/63 ,  B01J29/64 ,  B01J29/65 ,  B01J29/655 ,  B01J29/66 ,  B01J29/67 ,  B01J29/68 ,  B01J29/69 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/7038 ,  B01J29/7057 ,  B01J29/7088 ,  B01J29/7215 ,  B01J29/7276 ,  B01J29/7415 ,  B01J29/7476 ,  B01J29/7676 ,  B01J29/7815 ,  B01J29/7876 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1057 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/08 ,  B01J37/10 ,  B01J2229/126 ,  B01J2229/18 ,  B01J2229/20 ,  B01J2229/22 ,  B01J2229/32 ,  B01J2229/34 ,  B01J2229/37 ,  B01J2229/38 ,  B01J2229/40 ,  B82Y30/00 ,  Y02P30/20 ,  Y02P30/40

Abstract: A functional structural body that can realize a prolonged life time by suppressing the decrease in function and that can fulfill resource saving without requiring a complicated replacement operation is provided. A functional structural body includes a skeletal body of a porous structure composed of a zeolite-type compound; and at least one solid acid present in the skeletal body, the skeletal body has channels connecting with each other, and the solid acid is present at least in the channels of the skeletal body.

公开(公告)号：US20180021762A1

公开(公告)日：2018-01-25

申请号：US15720185

申请日：2017-09-29

Applicant: Saudi Arabian Oil Company

Inventor： Ola S. Ali ,  Hussain Al Yami ,  Mark P. Kaminsky ,  Sohel Shaikh ,  Wei Xu

IPC: B01J29/18 ,  B01J29/20 ,  B01J29/24 ,  C10G11/05 ,  B01J29/26 ,  C10G11/04 ,  C10G11/18

CPC classification number: B01J29/18 ,  B01J29/185 ,  B01J29/20 ,  B01J29/24 ,  B01J29/26 ,  B01J29/40 ,  B01J29/405 ,  B01J29/42 ,  B01J29/46 ,  B01J29/48 ,  B01J29/90 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/023 ,  B01J37/0201 ,  B01J37/0209 ,  B01J37/035 ,  B01J37/14 ,  B01J37/28 ,  B01J38/12 ,  B01J2229/186 ,  C10G11/04 ,  C10G11/05 ,  C10G11/10 ,  C10G11/16 ,  C10G11/18 ,  C10G2400/20 ,  C10G2400/22

Abstract: A method of using a heat generating catalyst in a hydrocarbon cracking process. The method includes providing a catalyst bed reactor which includes a catalyst bed of the heat generating catalyst disposed in the catalyst bed reactor. The heat generating catalyst includes at least one mordenite framework-inverted (MFI) zeolite catalyst having a Si/Al molar ratio of 15 or greater, and at least one metal oxide dispersed within a microstructure of the MFI zeolite catalyst. The method additionally includes introducing a hydrocarbon feed to the catalyst bed reactor and cracking the hydrocarbon feed to produce a cracking product. Additionally, an associated method of making the heat generating catalyst for hydrocarbon cracking is provided.

公开(公告)号：US09168517B2

公开(公告)日：2015-10-27

申请号：US14353620

申请日：2012-05-02

Applicant: Alexandr Yu Stakheev ,  Marie Grill ,  Arkady Kustov

Inventor： Alexandr Yu Stakheev ,  Marie Grill ,  Arkady Kustov

IPC: B01J29/00 ,  B01D53/94 ,  B01J29/88 ,  B01J29/46 ,  B01J29/76 ,  B01J29/70 ,  B01J29/68 ,  B01J23/72 ,  B01J37/02 ,  B01J29/08 ,  B01J29/14 ,  B01J29/16 ,  B01J29/18 ,  B01J29/24 ,  B01J29/26 ,  B01J29/40 ,  B01J29/48 ,  B01J29/65 ,  B01J29/69 ,  B01J29/72 ,  B01J29/78 ,  B01J35/04

CPC classification number: B01J29/88 ,  B01D53/9418 ,  B01D53/944 ,  B01D2251/2062 ,  B01D2255/2065 ,  B01D2255/2073 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/2092 ,  B01D2255/407 ,  B01D2255/502 ,  B01J23/72 ,  B01J29/085 ,  B01J29/14 ,  B01J29/16 ,  B01J29/185 ,  B01J29/24 ,  B01J29/26 ,  B01J29/405 ,  B01J29/46 ,  B01J29/48 ,  B01J29/655 ,  B01J29/68 ,  B01J29/69 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/7049 ,  B01J29/7057 ,  B01J29/7065 ,  B01J29/72 ,  B01J29/7215 ,  B01J29/723 ,  B01J29/7615 ,  B01J29/763 ,  B01J29/7815 ,  B01J29/783 ,  B01J35/04 ,  B01J37/0215 ,  B01J37/0244

Abstract: Catalyst composition for selective reduction of nitrogen oxides and soot oxidation comprising a physical mixture of one or more acidic zeolite or zeotype components with one ore more redox active metal compounds and a method for selective reduction of nitrogen oxides and soot oxidation by use of the catalyst composition.

Abstract translation: 用于选择性还原氮氧化物和烟灰氧化的催化剂组合物，其包含一种或多种酸性沸石或沸石型组分与一种或多种氧化还原活性金属化合物的物理混合物，以及通过使用催化剂组合物选择性还原氮氧化物和烟灰氧化的方法 。

公开(公告)号：US09024102B2

公开(公告)日：2015-05-05

申请号：US13900827

申请日：2013-05-23

Applicant: UOP LLC

Inventor： Edwin P. Boldingh

IPC: C07C6/00 ,  C07C15/08 ,  B01J29/80 ,  B01J37/00 ,  B01J37/02 ,  B01J37/20 ,  C07C6/12 ,  C07C6/06 ,  B01J29/18 ,  B01J29/26 ,  B01J29/40 ,  B01J29/48

CPC classification number: B01J29/80 ,  B01J29/18 ,  B01J29/26 ,  B01J29/40 ,  B01J29/48 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/20 ,  C07C6/06 ,  C07C6/126 ,  C07C2521/02 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2521/14 ,  C07C2523/14 ,  C07C2523/26 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/36 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2527/04 ,  C07C2527/12 ,  C07C2527/132 ,  C07C2529/80 ,  Y02P20/52 ,  C07C15/08

Abstract: A catalyst comprising an aluminosilicate zeolite having an MOR framework type, an acidic MFI molecular sieve component having a Si/Al2 molar ratio of less than 80, a metal component comprising one or more elements selected from groups VIB, VIIB, VIII, and IVA, an inorganic oxide binder, and a fluoride component.

Abstract translation: 一种催化剂，其包含具有MOR骨架型的硅铝酸盐沸石，Si / Al 2摩尔比小于80的酸性MFI分子筛组分，包含选自VIB，VIIB，VIII和IVA族中的一种或多种元素的金属组分， 无机氧化物粘合剂和氟化物组分。

公开(公告)号：US20140294706A1

公开(公告)日：2014-10-02

申请号：US14353620

申请日：2012-05-02

Applicant: Alexandr Yu Stakheev ,  Marie Grill ,  Arkady Kustov

Inventor： Alexandr Yu Stakheev ,  Marie Grill ,  Arkady Kustov

IPC: B01J29/88 ,  B01J29/68 ,  B01J29/70 ,  B01D53/94 ,  B01J29/46 ,  B01J29/76

CPC classification number: B01J29/88 ,  B01D53/9418 ,  B01D53/944 ,  B01D2251/2062 ,  B01D2255/2065 ,  B01D2255/2073 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/2092 ,  B01D2255/407 ,  B01D2255/502 ,  B01J23/72 ,  B01J29/085 ,  B01J29/14 ,  B01J29/16 ,  B01J29/185 ,  B01J29/24 ,  B01J29/26 ,  B01J29/405 ,  B01J29/46 ,  B01J29/48 ,  B01J29/655 ,  B01J29/68 ,  B01J29/69 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/7049 ,  B01J29/7057 ,  B01J29/7065 ,  B01J29/72 ,  B01J29/7215 ,  B01J29/723 ,  B01J29/7615 ,  B01J29/763 ,  B01J29/7815 ,  B01J29/783 ,  B01J35/04 ,  B01J37/0215 ,  B01J37/0244

Abstract: Catalyst composition for selective reduction of nitrogen oxides and soot oxidation comprising a physical mixture of one or more acidic zeolite or zeo-type components with one ore more redox active metal compounds and a method for selective reduction of nitrogen oxides and soot oxidation by use of the catalyst composition.

Abstract translation: 用于选择性还原氮氧化物和烟灰氧化的催化剂组合物，其包含一种或多种酸性沸石或沸石型组分与一种或多种氧化还原活性金属化合物的物理混合物，以及通过使用所述氧化还原活性金属化合物选择性还原氮氧化物和烟灰氧化的方法 催化剂组成。

公开(公告)号：US08653315B2

公开(公告)日：2014-02-18

申请号：US13687982

申请日：2012-11-28

Applicant: King Fahd University of Petroleum and Minerals

Inventor： Mohammad A. Ashraf Ali

IPC: C07C6/12

CPC classification number: C07C2/66 ,  B01J29/005 ,  B01J29/061 ,  B01J29/064 ,  B01J29/076 ,  B01J29/18 ,  B01J29/26 ,  B01J29/40 ,  B01J29/48 ,  B01J29/80 ,  B01J29/85 ,  B01J37/0009 ,  B01J2229/20 ,  B01J2229/42 ,  C07C6/123 ,  C07C2521/04 ,  C07C2523/28 ,  C07C2529/18 ,  C07C2529/40 ,  C07C2529/80 ,  Y02P20/52 ,  C07C15/08

Abstract: The multiple zeolite catalyst is a catalytic composition used to convert alkylaromatic hydrocarbons to BTX, particularly to commercially valuable xylenes. The catalyst is formed by mixing at least two zeolites selected from mordenite, beta zeolite, ZSM-5, ZSM-11, ZSM-12, ZSM-22, ZSM-23, MFI topology zeolite, NES topology zeolite, EU-1, MAPO-36, SAPO-5, SAPO-11, SAPO-34, and SAPO-41, and adding at least one metal component selected from Group VI of the Periodic Table of the Elements. The two zeolites have different physical and chemical characteristics, such as pore size and acidity. An exemplary catalyst includes mordenite, ZSM-5, and 3 wt % molybdenum. The multiple zeolite catalyst may further be used to convert toluene to mixed xylene isomers, particularly with a ZSM-5:mordenite ratio of 2:1 by weight.

Abstract translation: 多重沸石催化剂是用于将烷基芳族烃转化为BTX，特别是商业上有价值的二甲苯的催化组合物。 催化剂是通过混合至少两种选自丝光沸石，β沸石，ZSM-5，ZSM-11，ZSM-12，ZSM-22，ZSM-23，MFI拓扑沸石，NES拓扑沸石，EU-1，MAPO -36，SAPO-5，SAPO-11，SAPO-34和SAPO-41，并加入至少一种选自元素周期表第Ⅵ族的金属组分。 两种沸石具有不同的物理和化学特性，如孔径和酸度。 示例性催化剂包括丝光沸石，ZSM-5和3重量％的钼。 多沸石催化剂还可用于将甲苯转化为混合二甲苯异构体，特别是ZSM-5：丝光沸石比例为2:1重量比。

公开(公告)号：US20140008605A1

公开(公告)日：2014-01-09

申请号：US13979965

申请日：2012-01-19

Applicant: Kyung Byung Yoon ,  Hyun Sung Kim ,  Nak Cheon Jeong

Inventor： Kyung Byung Yoon ,  Hyun Sung Kim ,  Nak Cheon Jeong

IPC: H01L21/02 ,  H01L29/66

CPC classification number: H01L21/02601 ,  B01J29/061 ,  B01J29/076 ,  B01J29/087 ,  B01J29/088 ,  B01J29/163 ,  B01J29/166 ,  B01J29/185 ,  B01J29/26 ,  B01J29/605 ,  B01J29/64 ,  B01J29/84 ,  B01J29/85 ,  B01J29/86 ,  B01J29/87 ,  B01J35/0013 ,  B01J37/20 ,  B01J2229/186 ,  B01J2229/38 ,  B82Y10/00 ,  C01B39/026 ,  C01B39/24 ,  H01L21/02422 ,  H01L21/02521 ,  H01L21/02603 ,  H01L21/02628 ,  H01L29/125 ,  H01L29/127 ,  H01L29/66977

Abstract: The present application relates to a method for dispersing quantum dots (QDs) or quantum wires in zeolite, to zeolite containing quantum dots or quantum wires dispersed by the method, and to a method for stabilizing quantum dots or quantum wires in zeolite.

Abstract translation: 本发明涉及一种将量子点（QD）或量子线分散在沸石中的方法，涉及通过该方法分散的含沸石的量子点或量子线以及在沸石中稳定量子点或量子线的方法。

公开(公告)号：US08575054B2

公开(公告)日：2013-11-05

申请号：US11572095

申请日：2005-07-15

Applicant: Tomoo Ikoma ,  Takanobu Sakurai ,  Yoshiki Nakano

Inventor： Tomoo Ikoma ,  Takanobu Sakurai ,  Yoshiki Nakano

IPC: B01D53/56

CPC classification number: B01J29/46 ,  B01D53/8621 ,  B01D53/8634 ,  B01J21/063 ,  B01J23/42 ,  B01J29/072 ,  B01J29/076 ,  B01J29/24 ,  B01J29/26 ,  B01J35/023 ,  B01J37/0246 ,  B01J37/0248 ,  B01J37/04

Abstract: The present invention provides a catalyst composition which can decompose an organic nitrogen compound at a relatively low temperature to convert the compound to N2 and render it harmless in the purification of an exhaust gas containing the compound (nitrogen-based exhaust gas); a catalyst containing the catalyst composition; a method for producing the catalyst; and an exhaust gas purification apparatus containing the catalyst.By using a catalyst composition formed by mixing copper oxide particles and zeolite particles, an organic nitrogen compound and/or ammonia can be converted to N2 highly selectively. The catalyst composition of the present invention may further contain a manganese oxide and/or a precious metal.

Abstract translation: 本发明提供一种催化剂组合物，其能够在较低温度下分解有机氮化合物以将化合物转化为N 2，并使其在含有化合物（氮系废气）的废气的净化中无害化; 含有催化剂组合物的催化剂; 催化剂的制造方法; 和含有该催化剂的废气净化装置。 通过使用通过混合氧化铜颗粒和沸石颗粒形成的催化剂组合物，有机氮化合物和/或氨可以高度选择性地转化为N 2。 本发明的催化剂组合物还可以含有氧化锰和/或贵金属。

公开(公告)号：US08569388B2

公开(公告)日：2013-10-29

申请号：US13807349

申请日：2011-06-23

Applicant: Michiel Johannes Franciscus Maria Verhaak

Inventor： Michiel Johannes Franciscus Maria Verhaak

IPC: C07C27/00

CPC classification number: C07C1/02 ,  B01J23/34 ,  B01J23/8892 ,  B01J29/076 ,  B01J29/26 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/035 ,  C07C1/0435 ,  C07C1/0445 ,  C07C11/02

Abstract: The invention relates to a process for preparing olefins from synthesis gas, wherein the synthesis gas is contacted with a catalyst which contains cobalt, manganese and a third element selected from the group consisting of aluminium, gallium, indium, thallium, tin, lead and bismuth. Further, the invention relates to a process for preparing such catalyst, and to the catalyst so obtained.

Abstract translation: 本发明涉及从合成气制备烯烃的方法，其中合成气与含有钴，锰的催化剂和选自铝，镓，铟，铊，锡，铅和铋的第三元素接触 。 此外，本发明涉及制备这种催化剂的方法，以及如此得到的催化剂。

公开(公告)号：US20130190166A1

公开(公告)日：2013-07-25

申请号：US13821376

申请日：2011-09-05

Applicant: Yasuyoshi Kato ,  Seiji Ikemoto

Inventor： Yasuyoshi Kato ,  Seiji Ikemoto

IPC: B01D53/56 ,  B01J29/26

CPC classification number: B01D53/565 ,  B01D53/8628 ,  B01D2251/2062 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01D2255/50 ,  B01D2255/504 ,  B01D2255/70 ,  B01J21/063 ,  B01J23/002 ,  B01J23/28 ,  B01J23/30 ,  B01J27/199 ,  B01J29/084 ,  B01J29/088 ,  B01J29/18 ,  B01J29/185 ,  B01J29/26 ,  B01J29/40 ,  B01J29/405 ,  B01J29/48 ,  B01J35/0006 ,  B01J35/04 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/0225 ,  B01J37/08 ,  B01J37/088 ,  B01J37/28 ,  B01J2229/20 ,  B01J2229/42 ,  B01J2523/00 ,  B01J2523/31 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/51 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69

Abstract: To provide a catalyst having excellent performance and durability by improving a NOx reduction ratio at 350° C. or higher without deteriorating excellent durability of a Ti—V—Mo—P catalyst in view of problems of conventional art. A NOx reduction catalyst for exhaust gas, which is composed of a catalyst composition that comprises titanium (Ti), an oxide of phosphorous, molybdenum (Mo) and/or tungsten (W), oxide of vanadium (V), and high-silica zeolite that has an SiO2/Al2O3 ratio of not less than 20 is obtained by kneading in the presence of water, drying and calcining (1) titanium oxide, and phosphoric acid or an ammonium salt of phosphoric acid in an amount of more than 1% by weight and not more than 15% by weight relative to the titanium oxide in terms of H3PO4, (2) an oxo acid or oxo acid salt of molybdenum (Mo) and/or tungsten (W) and an oxo acid salt of vanadium (V) or vanadyl salt respectively in an amount of more than 0% by atom and not more than 8% by atom relative to the titanium oxide and (3) high-silica zeolite in an amount of more than 0% by weight and not more than 20% by weight relative to the titanium oxide.

Abstract translation: 考虑到现有技术的问题，通过提高350℃以上的NOx还原率而不劣化Ti-V-Mo-P催化剂的优异耐久性，提供具有优异性能和耐久性的催化剂。 用于排气的NOx还原催化剂由包含钛（Ti），磷的氧化物，钼（Mo）和/或钨（W），钒（V）的氧化物）和高二氧化硅 通过在水的存在下捏合，干燥和煅烧（1）氧化钛，磷酸或磷酸铵盐的量大于1重量％，得到SiO 2 / Al 2 O 3比不小于20的沸石， （ⅱ）钼（Mo）和/或钨（W）和钒（W）的含氧酸盐的含氧酸或含氧酸盐（V）和钒的含氧酸盐（重量），并且不超过15重量％ V）或氧钒盐分别以相对于氧化钛大于0原子％且不超过8原子％的量，和（3）高于0重量％且不超过0重量％的高硅石沸石 相对于氧化钛为20重量％以下。