Abstract:
Catalyst beds in refinery reactors require periodic change out due to build-up of contamination and loss of activity. The instant invention mists a liquid chemical solvent in nitrogen carrier gas to solubilize oils and heavy hydrocarbons and to further desorb light hydrocarbons and remove hydrogen sulfide (H2S), to effect decontamination. This process can be advantageously combined with nitrogen cool-down processes in preparation for catalyst unloading.
Abstract:
Described herein are improved chemical reactors for carrying out partial oxidation reactions. The chemical reactor permits the use of levels of oxygen above the lower explosion limit (LEL) typically used in partial oxidation reactions, which increases both volumetric reactivity and conversion per pass, resulting in reduced separation and reactant recycle costs. Also described are methods of using the reactors.
Abstract:
This disclosure relates to an improved method to produce titanium tetrachloride continuously from titanium-bearing materials containing high concentrations of alkaline earth metal impurities through fluidized-bed carbochlorination. Agglomerated heavy particles in a reaction are taken out continuously from a chlorination reactor without clogging and stopping. The reactors and related methods disclosed apply to the chlorination of titanium slag containing high content of alkaline earth metal oxides of up to 15% by weight.
Abstract:
The present disclosure relates to reactor components and their use, e.g., in regenerative reactors. A process and apparatus for utilizing different wetted areas along the flow path of a fluid in a pyrolysis reactor, e.g., a thermally regenerating reactor, such as a regenerative, reverse-flow reactor, is described.
Abstract:
The present invention relates to a classifying fluid bed granulator, comprising a granulation chamber with a fluidizing air chamber (7) with a bed floor (10), a ceiling (3c), an end wall (3d), a feed inlet (5), a seed inlet (6), an outlet (4) defined by walls (3a, 3b) for air, and an outlet (9) for produced granules. The granulation chamber is divided into an agglomeration and seed control section (1) and a granulation and classification section (2) where said section (2) is divided into two or more consecutive compartments having an asymmetric design. Section (2) may contain tilted baffle plates (12). Furthermore, the present invention relates to a method for fluid bed granulation of a feed being a solution, slurry, melt, emulsion, suspension or solids into granules of a desired classified size. Inlet seed particles are given a controlled size in an agglomeration and seed section ahead of being granulated with the feed in a granulation and classification section. The classification of the granules is performed in asymmetric compartments in the granulation and classification section.
Abstract:
In method for enhancing heat transfer in a bed of powder comprising cohesive Geldart type C particles confined by a wall of a vertically oriented container and being fluidized by the upward flow of fluidizing gas through the bed of powder, heat is transferred between the bed of powder and the wall of the container, and, prior to fluidizing the particles, the fluidizing gas is selected so as to comprise a sufficient amount of helium, hydrogen, or mixtures thereof for obtaining a thermal conductivity of the fluidizing gas of at least four times that of nitrogen for enhancing heat transfer between the wall and the bed.
Abstract:
A process for preparing acrylonitrile which comprises passing a gaseous mixture comprising propylene, ammonia and molecular oxygen and an ammoxidation catalyst through a reaction zone while controlling the superficial linear gas velocity and solids feeds rate to achieve a state of fast fluidization.
Abstract:
The present invention relates to a reactor and to a process for synthesis of hydrogen sulphide from elemental sulphur and hydrogen at elevated pressure and elevated temperature. The invention further relates to the use of the reactor for preparation of hydrogen sulphide in high yield and with a low H2SX content.
Abstract:
This disclosure relates to an improved method to produce titanium tetrachloride continuously from titanium-bearing materials containing high concentrations of alkaline earth metal impurities through fluidized-bed carbochlorination. Agglomerated heavy particles in a reaction are taken out continuously from a chlorination reactor without clogging and stopping. The reactors and related methods disclosed apply to the chlorination of titanium slag containing high content of alkaline earth metal oxides of up to 15% by weight.