公开(公告)号：US20180037989A1

公开(公告)日：2018-02-08

申请号：US15667817

申请日：2017-08-03

Applicant: Tokyo Electron Limited

Inventor： Miyako Kaneko ,  Naotaka Noro ,  Tsuyoshi Takahashi ,  Kazuyoshi Yamazaki

IPC: C23C16/40 ,  C23C16/455 ,  C23C16/34

CPC classification number: C23C16/402 ,  C01C1/00 ,  C01G23/022 ,  C23C16/0227 ,  C23C16/0272 ,  C23C16/30 ,  C23C16/34 ,  C23C16/45525 ,  C23C16/45531 ,  C23C16/54 ,  C23C28/04 ,  C23C28/042

Abstract: A metal-containing film can be formed with high continuity with respect to a base when forming the metal-containing film on the base by CVD or ALD. A film forming method of forming, by ALD or CVD, a Ti-containing film on a base film of a processing target object having a SiO2 film as the base film includes performing a surface processing of accelerating formation of a silanol group on a surface of the SiO2 film by bringing a fluid containing O and H into contact with the surface of the SiO2 film; and performing a film forming processing of forming the Ti-containing film on the SiO2 film, on which the surface processing is performed, by the ALD or the CVD with a Ti source gas which reacts with the silanol group.

公开(公告)号：US09656879B2

公开(公告)日：2017-05-23

申请号：US14429588

申请日：2014-03-06

Applicant: TOHO TITANIUM CO., LTD.

Inventor： Matsuhide Horikawa ,  Eiichi Fukasawa

IPC: C01G23/00 ,  C01G23/02 ,  B09B3/00 ,  B09B5/00 ,  C01G49/02 ,  C01G49/10 ,  C01B7/03

CPC classification number: C01G23/024 ,  B09B3/00 ,  B09B5/00 ,  C01B7/035 ,  C01G23/022 ,  C01G49/02 ,  C01G49/10

Abstract: A method for producing titanium tetrachloride is provided, in which valuable materials such as unreacted titanium-containing raw material, carbon raw material and chlorine can be recovered from solid recovered material generated in chlorinating process of titanium-containing raw material, and titanium-containing raw material can be efficiently used. The treatment method of titanium-containing raw material includes the steps: separating and removing impurities selectively from the titanium-containing raw material as chlorides so as to obtain high titanium-containing raw material, producing titanium tetrachloride using the high titanium-containing raw material, and performing separating process of impurities from solid recovered material byproduced in the production of titanium tetrachloride, together with selective chlorinating treatment of the titanium-containing raw material. Thus, the high titanium-containing raw material can be produced while recovering chlorine and impure oxides.

公开(公告)号：US09656231B2

公开(公告)日：2017-05-23

申请号：US14585610

申请日：2014-12-30

Applicant: BIC TECHNOLOGIES GROUP INC.

Inventor： Young Jin Kwon ,  Gordon Chun ,  Jeong Hi Kim

IPC: B01J8/18 ,  B01J8/44 ,  C01G23/02

CPC classification number: B01J8/1809 ,  B01J8/1827 ,  B01J8/1836 ,  B01J8/44 ,  B01J2208/00327 ,  B01J2208/00548 ,  B01J2208/00681 ,  B01J2208/00752 ,  B01J2208/00902 ,  B01J2208/00991 ,  C01G23/022

Abstract: This disclosure relates to an improved method to produce titanium tetrachloride continuously from titanium-bearing materials containing high concentrations of alkaline earth metal impurities through fluidized-bed carbochlorination. Agglomerated heavy particles in a reaction are taken out continuously from a chlorination reactor without clogging and stopping. The reactors and related methods disclosed apply to the chlorination of titanium slag containing high content of alkaline earth metal oxides of up to 15% by weight.

公开(公告)号：US20150368119A1

公开(公告)日：2015-12-24

申请号：US14429675

申请日：2014-03-06

Applicant: TOHO TITANIUM CO., LTD.

Inventor： Matsuhide HORIKAWA ,  Seiichiro TANI ,  Ryota HORIGUCHI ,  Eiichi FUKASAWA

IPC: C01G23/02

CPC classification number: C01G23/022

Abstract: A technique is provided in which valuable material is recovered from solid recovered material generated during chlorinating process of titanium-containing raw material, and in particular, in which chlorine gas and titanium-containing raw material can be efficiently separated and recovered from the solid recovered material. The method for production of titanium tetrachloride includes: a chlorinating process in which titanium-containing raw material, coke and chlorine are reacted, a recovering process in which chlorine gas, titanium oxide and coke are recovered by treating solid recovered material which is byproduced during the chlorinating process, and a reusing process in which these recovered material are reused as raw material for the chlorinating process.

Abstract translation: 提供了一种技术，其中有用材料从含钛原料的氯化过程中产生的固体回收材料回收，特别是其中可以从固体回收材料中有效地分离和回收氯气和含钛原料 。 四氯化钛的制造方法包括：使含钛原料，焦炭和氯反应的氯化工艺，通过处理在该过程中产生的固体回收材料回收氯气，氧化钛和焦炭的回收方法 这些回收材料被重新用作氯化工艺的原料，并且重新使用过程。

公开(公告)号：US20140154167A1

公开(公告)日：2014-06-05

申请号：US14177248

申请日：2014-02-11

Applicant: E I DU PONT DE NEMOURS AND COMPANY

Inventor： TIMOTHY J. BECNEL ,  Yung-Hsing Samson Hsu ,  Joseph J. Zaher ,  Charles David Musick

IPC: C01G23/02

CPC classification number: C01G23/022 ,  C01G23/07 ,  C01G25/04

Abstract: This disclosure relates to an improved process for preparing titanium tetrachloride comprising a first carbo-chlorination reaction comprising reacting ores comprising silica and/or zirconium with chlorine and a carbon compound at a temperature of about 900° C. to about 1300° C. to form an unscrubbed off gas comprising carbon monoxide, and using the unscrubbed off gas in a second carbo-chlorination reaction comprising titanium to form titanium tetrachloride.

Abstract translation: 本公开涉及一种改进的制备四氯化钛的方法，其包括第一碳氯化反应，其包括在约900℃至约1300℃的温度下将包含二氧化硅和/或锆的矿石与碳和碳化合物反应以形成 包含一氧化碳的未分解气体，并且在包含钛的第二碳氯化反应中使用未循环气体形成四氯化钛。

公开(公告)号：US08735162B2

公开(公告)日：2014-05-27

申请号：US13392614

申请日：2010-09-02

Applicant: James Elliott Merkle, Jr. ,  Raymond Roy Beets, Jr.

Inventor： James Elliott Merkle, Jr. ,  Raymond Roy Beets, Jr.

IPC: G01N35/00 ,  C22B34/12 ,  C01G23/02 ,  B01J8/18

CPC classification number: B01J8/1809 ,  C01G23/022 ,  C01G23/047 ,  C01G23/0475 ,  C01G23/07 ,  C09C1/3653 ,  C22B1/10 ,  C22B34/1222 ,  C22B34/1231 ,  Y02P10/23 ,  Y10T436/12

Abstract: This disclosure relates to a process for controlling chlorination reactions in manufacturing titanium tetrachloride in a fluidized bed reactor, followed by processing to form a titanium product comprising an amount of silica, the process comprising: (a) feeding carbonaceous material, titanium bearing material comprising an amount of silica, and chlorine to the fluidized bed reactor to form a gaseous stream, and condensing the gaseous stream to form titanium tetrachloride, a non-condensed gas stream and a condensable product stream; (b) processing the titanium tetrachloride to form a titanium product comprising an amount of silica; (c) analyzing the titanium product comprising an amount of silica to determine the analyzed concentration of silica; (d) identifying a set point concentration of silica; (e) calculating the difference between the analyzed concentration of silica and the set point concentration of silica; (f) measuring the titanium tetrachloride flow to a processing reactor that releases chlorine; (g) measuring the flow of fresh chlorine added to the fluidized bed; (h) measuring the flow of the titanium bearing material added to the fluidized bed reactor and establishing a historic average flow of the titanium bearing material added to the fluidized bed reactor; (i) calculating the chlorine released from the titanium tetrachloride that is processed using the titanium tetrachloride flow data from step (f); (j) calculating the total chlorine flow to the fluidized bed reactor by adding the chlorine flow in step (g) to the chlorine flow calculated in step (i) and establishing a historic average chlorine flow; (k) calculating a unit titanium bearing material consumption per unit chlorine; (l) calculating an estimated current consumption rate of titanium bearing material based on the total chlorine flow from step (j) times the unit titanium bearing material consumption per unit chlorine from step (k); (l) calculating an estimated current consumption rate of titanium bearing material based on the total chlorine flow from step (j) times the unit titanium bearing material consumption per unit chlorine from step (k); and (m) generating a signal based on difference generated in step (e) that provides a feedback response and combining this to the estimated current consumption rate of titanium bearing material from step (l) to provide a feed forward response to control the flow of the titanium bearing material into the fluidized bed reactor.

公开(公告)号：US20140042010A1

公开(公告)日：2014-02-13

申请号：US13884623

申请日：2011-11-11

Applicant: Mikko Lylykangas ,  Jukka Räsänen ,  Klaus Nyfors ,  Pekka Malinen

Inventor： Mikko Lylykangas ,  Jukka Räsänen ,  Klaus Nyfors ,  Pekka Malinen

IPC: B01D1/22

CPC classification number: B01D1/22 ,  B01D1/222 ,  B01D3/14 ,  B01D3/28 ,  C01G1/06 ,  C01G23/022 ,  C01G23/024 ,  C01P2006/80 ,  C22B34/1231 ,  Y02P10/23

Abstract: The present invention provides a process for recovering transition metal tetrahalides from a waste stream coming from a catalyst manufacturing process by (a) establishing a mixed stream comprising transition metal tetrahalide and transition metal alkoxyhalides; (b) forming a falling liquid film from the mixed stream of step (a) at a temperature of from 25 to 85° C. and an absolute pressure of from 0.05 to 0.6 bar; and (c) establishing from the film of step (b) a first vapour stream containing from 90 to 100% of recoverable components and a second liquid stream containing about 10 to 80% of titanium haloalkoxides.

Abstract translation: 本发明提供从（a）建立包含过渡金属四卤化物和过渡金属烷氧基卤化物的混合物流，从催化剂制造方法的废料流中回收过渡金属四卤化物的方法; （b）在步骤（a）的混合物流中，在25至85℃的温度和绝对压力为0.05至0.6巴的条件下形成降液体膜; 和（c）从步骤（b）的膜确定含有90至100％可回收组分的第一蒸气流和含有约10至80％钛卤代烷氧化物的第二液流。

公开(公告)号：US08309042B2

公开(公告)日：2012-11-13

申请号：US12523736

申请日：2008-01-23

Applicant: Matthew Donnel Eisenmann ,  Jorge Lavastida ,  Timothy Josiah McKeon ,  James Elliott Merkle, Jr.

Inventor： Matthew Donnel Eisenmann ,  Jorge Lavastida ,  Timothy Josiah McKeon ,  James Elliott Merkle, Jr.

IPC: C01G23/00

CPC classification number: C01G23/07 ,  B07B1/00 ,  B07B13/18 ,  B07B2230/01 ,  C01G23/022 ,  C01G23/047 ,  C01G23/0475 ,  C01G23/0536 ,  C22B34/1222 ,  C22B34/1231 ,  Y02P10/23

Abstract: The disclosure provides a process for recycling ore in the chloride process, without the build-up of silica-containing gangue in the chlorination reactor.

Abstract translation: 本公开提供了一种在氯化方法中回收矿石的方法，而不会在氯化反应器中堆积含二氧化硅的脉石。

公开(公告)号：US07588741B2

公开(公告)日：2009-09-15

申请号：US11092286

申请日：2005-03-28

Applicant: Wendell E. Dunn, Jr. ,  Jeffrey Van Jahnke

Inventor： Wendell E. Dunn, Jr. ,  Jeffrey Van Jahnke

IPC: C01F7/00

CPC classification number: C01G23/022 ,  C01G23/02 ,  C22B1/08 ,  C22B26/12

Abstract: Cyclical batch processes for halogenation, such as chlorination, of minerals in a fixed bed using a plurality of cycles which include the steps of at least partially evacuating the bed, charging the bed with reactant gas, maintaining the reactant gas in the bed for a predetermined time, and exhausting reaction products under vacuum. Also disclosed is the chlorination of spodumene in its beta crystalline form produced by calcining spodumene in its naturally-occurring alpha crystalline form to preferentially extract lithium as lithium chloride.

Abstract translation: 使用多个循环对固定床中的矿物进行卤化，例如氯化的循环间歇方法，其包括以下步骤：至少部分抽空床，将反应气体加入床中，将反应气体保持在床中预定的 时间和耗尽的反应产物在真空下。 还公开了以其天然存在的α结晶形式煅烧锂辉石，以优先提取锂作为氯化锂产生的其晶体形式的锂辉石的氯化。

公开(公告)号：US20060039845A1

公开(公告)日：2006-02-23

申请号：US10910203

申请日：2004-08-03

Applicant: Thomas Messer ,  Peter Carter

Inventor： Thomas Messer ,  Peter Carter

IPC: C01G23/047

CPC classification number: C01G1/06 ,  C01B7/01 ,  C01B9/02 ,  C01G23/022 ,  C01G23/07

Abstract: The present invention is directed to the suppression of the formation noxious compounds such as furans. According to the present invention, a venturi device is used to rapidly quench a chlorinator reaction gas. The rapid quench minimizes the resonance time that furan precursors are at conditions conducive to furan formation.