摘要:
A compound of formula (I): ##STR1## in which Ar is an optionally substituted aryl or heterocyclic ring system; W is O or NR.sup.1 where R.sup.1 is hydrogen or lower alkyl;A is .dbd.CH or >CH.sub.2 and G is .dbd.C--R.sup.2, >CR.sup.3 R.sup.4 or >C.dbd.R.sup.5 such that --G--A-- is --CR.sup.2 .dbd.CH--, where R.sup.2 is H or CR.sup.6 R.sup.7 XR.sup.8 ; or --G--A-- is CR.sup.3 R.sup.4 --CH.sub.2 where CR.sup.3 R.sup.4 is CH--CR.sup.6 R.sup.7 XR.sup.8, CH--OCR.sup.6 R.sup.7 XR.sup.8, C(R.sup.9)OCOR.sup.10, CR.sup.9 R.sup.10, C(R.sup.9)OR.sup.10, C(OR.sup.9)OR.sup.10, or CH--CH.sub.2 (CO.sub.2 R.sup.11); or --G--A-- is --CR.sup.5 --CH.sub.2 -- where R.sup.5 is .dbd.CR.sup.7 XR.sup.8, .dbd.NOCR.sup.6 R.sup.7 XR.sup.8, .dbd.NOR.sup.11 or .dbd.NOCOR.sup.11 ;X is (CH.sub.2).sub.n, CH.dbd.CH, CH(OR.sup.20)CH.sub.2, or COCH.sub.2 ;n is 0, 1 or 2;R.sup.6 and R.sup.7 are independently selected from H, optionally substituted alkyl, alkenyl or alkynyl, halogen, NR.sup.9 R.sup.10, or R.sup.6 and R.sup.7 together with the carbon to which they are attached form an optionally substituted alkenyl or cycloalkyl group;R.sup.8 is CO.sub.2 R.sup.12, CN, COR.sup.12, CH.sub.2 OR.sup.12, CH(OH)R.sup.12, CH(OR.sup.12)R.sup.13, CSNH.sub.2, COSR.sup.12, CSOR.sup.12, CONHSO.sub.2 R.sup.12, CONR.sup.14 R.sup.15, CONHNR.sup.14 R.sup.15, CONHN.sup.+ R.sup.14 R.sup.15 R.sup.16 R.sup.17, CO.sub.2.sup.-+ R.sup.19+ or COON.dbd.CR.sup.14 R.sup.15 ;R.sup.19+ is an agriculturally acceptable cation;R.sup.17- is an agriculturally acceptable anion;R.sup.9, R.sup.10, R.sup.14, R.sup.15 and R.sup.16 are independently selected from H or an optionally substituted alkyl, alkenyl, aryl or alkynyl group or any two of R.sup.9, R.sup.10, R.sup.14 and R.sup.15, R.sup.16 together with the atom to which they are attached form a cycloalkyl or heterocyclic ring, and R.sup.14 and R.sup.15 may additionally be a heterocyclic ring, provided that when G is CR.sup.9 R.sup.10 or C(R.sup.9)OR.sup.10, R.sup.9 and R.sup.10 are not both hydrogen.
摘要:
A herbicidal compound of formula (I): ##STR1## in which Ar is an optionally substituted aryl or heterocyclic ring system:R.sup.1 and R.sup.2 are independently selected from H, optionally substituted alkyl, alkenyl or akynyl, halogen, NR.sup.a R.sup.b, or R.sup.1 and R.sup.2 together with the carbon to which they are attached form an optionally substituted alkenyl or cycloalkyl group;R.sup.3 is CO.sub.2 R.sup.4, CN, COR.sup.4, CH.sub.2 OR.sup.4, CH.sub.4 (OH)R.sup.4, CH(OR.sup.4)R.sup.5, CH.sub.2 OSO.sub.6 R.sup.4, CH.sub.2 OSO.sub.6 R.sub.4, CH.sub.2 ONR.sup.6 R.sup.7, CSNH.sub.2, COSR.sup.4, SCOR.sup.4, COHNSO.sub.2 R.sup.4, CONR.sup.6 R.sup.7, CONHNR.sup.6 R.sup.7, CONHN.sup.+ R.sup.6 R.sup.7 R.sup.8 Y.sup.-2, CO.sub.2.sup.- M.sup.+ or COON.dbd.CR.sup.6 R.sup.7 ;M.sup.+ is an agriculturally acceptable cation;Y.sup.- is an agriculturally acceptable anion;R.sup.4, and R.sup.5 are independently selected from H or an optionally substituted alkyl, aryl, alkenyl or alkynyl group;R.sup.6, R.sup.7, R.sup.8, R.sup.9, R.sup.a and R.sup.b are independently selected from H or an optionally substituted alkyl alkenyl, aryl or akynyl group or any two of R.sup.6, R.sup.7, R.sup.8, R.sup.9, R.sup.a and R.sup.b together with the atom to which they are attached form a cycloalkyl or heterocyclic ring;R.sup.6 and R.sup.7 may also be a heterocyclic ring;W is O or NR.sup.10 where R.sup.10 is H or lower alkyl;X is (CH.sub.2).sub.n, CH.dbd.CH, CH(OR.sup.c)CH.sub.2, COCH.sub.2 ;where R.sup.c is H or an optionally substituted alkyl, aryl, alkynyl or alkynyl group; andn is O, 1 or 2.
摘要:
A compound of formula (I): ##STR1## or a salt, enamine or the like, acylate, sulphonate, carbamate or ether derivative thereof; wherein X, X.sup.1 and X.sup.2 are independently oxygen or sulphur, R.sup.1 is an optionally substituted heterocyclic or cycloalkyl group, and Y is an optionally substituted C.sub.2 -C.sub.4 alkylene group which is optionally interposed, by an oxygen atom, a group ##STR2## a group ##STR3## or an optionally mono-substituted nitrogen atom, wherein p is 0, 1 or 2, s is 0 or 1 and R.sup.b is alkyl or alkoxy; provided that when X, X.sup.1 and X.sup.2 are oxygen, R.sup.1 is not pyridyl or pyrimidinyl. Processes for the preparation of these compounds and herbicidal compositions containing them are also described and claimed.
摘要:
A compound of formula (I): ##STR1## or a salt, enamine or the like, acylate, sulphonate, carbamate or ether derivative thereof; wherein X, X.sup.1 and X.sup.2 are independently oxygen or sulphur, R.sup.1 is an optionally substituted heterocyclic or cycloalkyl group, and Y is an optionally substituted C.sub.2 -C.sub.4 alkylene group which is optionally interposed by an oxygen atom, a group ##STR2## a group ##STR3## or an optionally mono-substituted nitrogen atom, wherein p is 0, 1 or 2, s is 0 or 1 and R.sup.b is alkyl or alkoxy; provided that when X, X.sup.1 and X.sup.2 are oxygen, R.sup.1 is not pyridyl or pyrimidinyl. Processes for the preparation of these compounds and herbicidal compositions containing them are also described and claimed.
摘要:
A compound of formula (I): ##STR1## in which the dotted lines indicate the presence of two double bonds arranged so as to form a fused hetero-aromatic ring system;Ar is an optionally substituted aryl or heterocyclic ring;W is O or NR.sup.1, where R.sup.1 is hydrogen or lower alkyl;X is (CH.sub.2).sub.n, CH.dbd.CH, CH(OR.sup.5)CH.sub.2, COCH.sub.2 ;where n is O, 1 or 2;R.sup.2 and R.sup.3 are independently selected from H, optionally substituted alkyl, alkenyl or alkynyl, halogen, NR.sup.6 R.sup.7 or R.sup.2 and R.sup.3 together with the carbon to which they are attached form an optionally substituted alkenyl or cycloalkyl group;R.sup.4 is CO.sub.2 R.sup.8, CN, COR.sup.8, CH.sub.2 OR.sup.8, CH(OH)R.sup.8, CH(OR.sup.8)R.sup.9, CSNH.sub.2, COSR.sup.8, CSOR.sup.8, CONHSO.sub.2 R.sup.8, CONR.sup.10 R.sup.11, CONHNR.sup.10 R.sup.11, CONHN.sup.+ R.sup.10 R.sup.11 R.sup.12 R.sup.13-, CO.sub.2.sup.- R.sup.14+ or COON.dbd.CR.sup.10 R.sup.11 ;R.sup.14+ is an agriculturally acceptable cation; and R.sup.13- is an agriculturally acceptable anion;R.sup.5, R.sup.8 and R.sup.9 are independently selected from H or an optionally substituted alkyl, aryl, alkenyl or alkynyl group; andR.sup.6, R.sup.7, R.sup.10, and R.sup.12 are independently selected from H or an optionally substituted alkyl, alkenyl, aryl or alkynyl group or any two of R.sup.6, R.sup.7, R.sup.10, R.sup.11 and R.sup.12 together with the atom to which they are attached form a cycloalkyl or heterocyclic ring. Compounds of formula (I) are herbicidal and composition containing them and methods of treatment using them are also described.
摘要:
A compound of formula (I): ##STR1## or a salt, enamine or the like, acylate, sulphonate, carbamate or ether derivative thereof; wherein X, X.sup.1 and X.sup.2 are independently oxygen or sulphur, R.sup.1 is an optionally substituted heterocyclic or cycloalkyl group, and Y is an optionally substituted C.sub.2 -C.sub.4 alkylene group which is optionally interposed by an oxygen atom, a group>S(O).sub.pa group ##STR2## or an optionally mono-substituted nitrogen atom, wherein p is O, 1 or 2, s is 0.sub.1 or 1 and R.sup.b is alkyl or alkoxy; provided that when X, X.sup.1 and X.sup.2 are oxygen, R.sup.1 is not pyridyl or pyrimidinyl. Processes for the preparation of these compounds and herbicidal compositions containing them are also described and claimed.
摘要:
A herbicidal compound of formula (I): ##STR1## in which the dotted line indicates the presence of two double bonds arranged so as to form a fused hetero-aromatic ring system;Py is an optionally substituted pyrazole ring;W is O or NR.sup.1 ; where R.sup.1 is hydrogen or lower alkyl;X is (CH.sub.2).sub.n, CH.dbd.CH, CH(OR.sup.5)CH.sub.2, COCH.sub.2 ;where n is 0, 1 or 2;R.sup.2 and R.sup.3 are independently selected from H, optionally substituted alkyl, alkenyl or alkynyl, halogen, NR.sup.6 R.sup.7, or R.sup.2 and R.sup.3 together with the carbon to which they are attached form an optionally substituted alkenyl or cycloalkyl group;R.sup.4 is CO.sub.2 R.sup.8, CN, COR.sup.8, CH.sub.2 OR.sup.8, CH(OH)R.sup.8, CH(OR.sup.8)R.sup.9, CSNH.sub.2, COSR.sup.8, CSOR.sup.8, CONHSO.sub.2 R.sup.8, CONR.sup.10 R.sup.11, CONHNR.sup.10 R.sup.11, CONHN.sup.+ R.sup.10 R.sup.11 R.sup.12 R.sup.14-, CO.sub.2.sup.- R.sup.15+ or COON.dbd.CR.sup.10 R.sup.11 ;R.sup.15+ is an agriculturally acceptable cation and R.sup.14- is an agriculturally acceptable anion.R.sup.5, R.sup.8 and R.sup.9 are independently selected from H or an optionally substituted alkyl, aryl, alkenyl or alkynyl group;R.sup.6, R.sup.7, R.sup.10, R.sup.11 and R.sup.12 are independently selected from H or an optionally substituted alkyl, alkenyl, aryl or alkynyl group; or any two of R.sup.6, R.sup.7, R.sup.10, R.sup.11 and R.sup.12 together with the atom to which they are attached form a cycloalkyl or heterocyclic ring.Processes for the preparation of these compounds and compositions containing them are also described.
摘要:
Diphenyl ethers of formula: ##STR1## wherein A is hydrogen or one of a specified range of substituents e.g. halogen, hydroxy, haloalkyl, B, C, E and F are hydrogen or specified substituents; D is CF.sub.3, halogen, or an other specified substituent; and R is a group --CONR.sup.4 SO.sub.2 R.sup.3 wherein R.sup.4 is hydrogen or C.sub.1 to C.sub.4 alkyl and R.sup.3 is an optionally substituted alkyl, alkenyl, alkynyl, or aryl radical; useful as selective herbicides.
摘要翻译:式:其中A是氢或特定范围的取代基之一的二苯醚。 卤素,羟基,卤代烷基,B,C,E和F是氢或特定的取代基; D是CF 3,卤素或其它指定的取代基; 并且R是基团-CONR 4 SO 2 R 3,其中R 4是氢或C 1至C 4烷基,R 3是任选取代的烷基,烯基,炔基或芳基; 用作选择性除草剂。
摘要:
Diphenyl ethers of formula: ##STR1## wherein A is hydrogen or one of a specified range of substituents e.g. halogen, hydroxy, haloalkyl, B, C, E and F are hydrogen or specified substituents; D is CF.sub.3, halogen, or another specified substituent; and R is a group --CONR.sup.4 SO.sub.2 R.sup.3 wherein R.sup.4 is hydrogen or C.sub.1 to C.sub.4 alkyl and R.sup.3 is an optionally substituted alkyl, alkenyl, alkynyl, or aryl radical; useful as selective herbicides.
摘要翻译:式:其中A是氢或特定范围的取代基之一的二苯醚。 卤素,羟基,卤代烷基,B,C,E和F是氢或特定的取代基; D是CF 3,卤素或另外指定的取代基; 并且R是基团-CONR 4 SO 2 R 3,其中R 4是氢或C 1至C 4烷基,R 3是任选取代的烷基,烯基,炔基或芳基; 用作选择性除草剂。
摘要:
A compound of formula (I): ##STR1## or a salt, enamine or the like, acylate, sulphonate, carbamate or ether derivative thereof; wherein X, X.sup.1 and X.sup.2 are independently oxygen or sulphur, R.sup.1 is an optionally substituted heterocyclic or cycloalkyl group, and Y is an optionally substituted C.sub.2 -C.sub.4 alkylene group which is optionally interposed by an oxygen atom, a group ##STR2## a group ##STR3## or an optionally mono-substituted nitrogen atom, wherein p is 0, 1 or 2, s is 0 or 1 and R.sup.b is alkyl or alkoxy; provided that when X, X.sup.1 and X.sup.2 are oxygen, R.sup.1 is not pyridyl or pyrimidinyl. Processes for the preparation of these compounds and herbicidal compositions containing them are also described and claimed.