公开(公告)号：US5043410A

公开(公告)日：1991-08-27

申请号：US407735

申请日：1989-09-15

申请人： Alberto Re ,  Francesco Giavarini ,  Cesare Cova

发明人： Alberto Re ,  Francesco Giavarini ,  Cesare Cova

IPC分类号： C08G18/10 ,  C08G18/50 ,  C08G18/67

CPC分类号： C08G18/675 ,  C08G18/10 ,  C08G18/5015

摘要： Fluorinated polyurethanes containing blocks having a perfluoropolyethereal structure, with rubber-like properties, alternated with stiff structural units are taught. The stiff units are at least partially provided with a double bond of the olefinic type, which is suitable for causing the cross-linking of the polymeric chains with a cross-linking system of the radicalic type.

公开(公告)号：US5026814A

公开(公告)日：1991-06-25

申请号：US407951

申请日：1989-09-15

申请人： Alberto Re ,  Francesco Giavarini

发明人： Alberto Re ,  Francesco Giavarini

IPC分类号： C08G18/10 ,  C08G18/50

CPC分类号： C08G18/5015 ,  C08G18/10

摘要： The invention relates to polyurethanes comprising polyoxyperfluoroalkylene blocks of rubber-like nature and rigid segments derived from short-chain aliphatic diols, optionally from aliphatic diamines, and from aliphatic or cycloaliphatic or aromatic diisocyanate. The number of the rigid-type segments is equal to or greater than the number of the polyoxyperfluoroalkylene blocks. The polyurethane are characterized by a glass transition temperature lower than -80.degree. C., a tensile strength greater than 30 kg/cm.sup.2, a hardness between 50 Shore A and 75 Shore D, and good thermoforming characteristics.

公开(公告)号：US4874842A

公开(公告)日：1989-10-17

申请号：US180892

申请日：1988-04-13

申请人： Ken Johns ,  Alberto Re ,  Gianangelo Bargigia

发明人： Ken Johns ,  Alberto Re ,  Gianangelo Bargigia

IPC分类号： C08J3/24

CPC分类号： C08J3/247

摘要： The present invention relates to a method for hot curing thermosetting resins and vulcanizable elastomers, based on the use of perfluoropolyethers in the liquid state as heat transfer media.

公开(公告)号：US4977222A

公开(公告)日：1990-12-11

申请号：US167125

申请日：1988-03-11

申请人： Gianangelo Bargigia ,  Alberto Re ,  Luigi Corbelli ,  Ken Johns ,  Luciano Flabbi ,  Padmanabhan Srinivasan

发明人： Gianangelo Bargigia ,  Alberto Re ,  Luigi Corbelli ,  Ken Johns ,  Luciano Flabbi ,  Padmanabhan Srinivasan

IPC分类号： C08J3/24 ,  C08J7/12

CPC分类号： C08J3/247

摘要： The cross-linking or curing of thermosetting resins and of hot curable elastomers is carried out by heating the material or the article comprising the resin (or the elastomer) by saturated vapor of the commercial perfluoropolyether having an average boiling point corresponding to the temperature necessary for the cross-linking and having a point range not exceeding 12.degree. C. (measured according to ASTM D 1078) in the presence of a chlorofluorohydrocarbon secondary vapor.

公开(公告)号：US4891417A

公开(公告)日：1990-01-02

申请号：US321300

申请日：1989-03-10

申请人： Alberto Re ,  Mario Alfieri

发明人： Alberto Re ,  Mario Alfieri

IPC分类号： C07D303/24 ,  C08G18/30 ,  C08G18/32 ,  C08G18/38 ,  C08G18/50 ,  C08G18/58 ,  C08G59/04 ,  C08G59/20 ,  C08G59/30 ,  C08G59/40 ,  C08G59/42 ,  C08G59/50

CPC分类号： C08G59/42 ,  C08G18/582 ,  C08G59/04 ,  C08G59/30 ,  C08G59/4028 ,  C08G59/50

摘要： Fluorinated polymers having epoxy resin structure, containing at least 10% by weight, preferably 20% by weight, of fluorine, prepared starting from epichlorohydrin and from one or more diols, at least one of which being a perfluoroalkylene diol, and by using conventional cross-linking agents for epoxy resins, such as anhydrides of dicarboxylic acids, di- or tri-isocyanates, polyfunctional amines.

公开(公告)号：US4849493A

公开(公告)日：1989-07-18

申请号：US191188

申请日：1988-05-06

申请人： Alberto Re ,  Marco De Giorgi

发明人： Alberto Re ,  Marco De Giorgi

IPC分类号： C08G65/22 ,  C08G18/38 ,  C08G18/50 ,  C08G18/65 ,  C08G18/66 ,  C08G18/80

CPC分类号： C08G18/6681 ,  C08G18/3876 ,  C08G18/5015 ,  C08G18/8054

摘要： Non-fluorinated tertiary aminic compounds, comprising two or more functional groups containing at least three active H, of the hydroxyl or aminic or thiol type, are utilized, in the form of a homogeneous mixture with perfluoropolyethers having hydroxy end groups, to prepare by means of polycondensation and cross-linking reaction with fluorinated or non-fluorinated polyisocyanates, carried out in the absence of catalysts, the corresponding polymers containing the perfluoropolyethereal chain deriving from the perfluoropolyether having hydroxy end groups.

公开(公告)号：US5109103A

公开(公告)日：1992-04-28

申请号：US667214

申请日：1991-01-22

申请人： Alberto Re ,  Marco De Giorgi ,  Gerardo Caporiccio

发明人： Alberto Re ,  Marco De Giorgi ,  Gerardo Caporiccio

IPC分类号： C08G63/68 ,  A61L27/00 ,  A61L27/18 ,  A61L33/00 ,  A61L33/06 ,  C08G63/66 ,  C08G63/682 ,  C08G63/78

CPC分类号： C08G63/6826 ,  A61L27/18 ,  A61L33/068

摘要： New polyesters comprising polyoxyfluoroalkylene blocks are prepared by polycondensation of diols with dicarboxylic acids or with derivatives thereof, said fluorinated polyesters being characterized by such improved surface properties that any subsequent treatments of the surface of the articles obtained therefrom are needless.

摘要翻译： PCT No.PCT / EP86 / 00712 Sec。 371日期1987年7月22日 102（e）日期1987年7月22日PCT提交1986年12月5日PCT公布。 公开号WO87 / 03608 日本6月18日，1987.通过二醇与二羧酸或其衍生物的缩聚来制备包含聚氧氟亚烷基嵌段的新聚酯。所述氟化聚酯的特征在于这种改进的表面性质，使得从其获得的制品的表面的任何后续处理是不必要的 。

公开(公告)号：US4851485A

公开(公告)日：1989-07-25

申请号：US201091

申请日：1988-06-01

申请人： Alberto Re ,  Claudio Tonelli ,  Vito Tortelli

发明人： Alberto Re ,  Claudio Tonelli ,  Vito Tortelli

IPC分类号： C08G18/58 ,  C08G18/80 ,  C08G59/40 ,  C08G59/42

CPC分类号： C07C265/10 ,  C07C265/12 ,  C08G18/58 ,  C08G18/8054 ,  C08G59/40 ,  C08G59/4028 ,  C08G59/42

摘要： Non-fluorinated epoxy resins of a known type are cross-linked by means of polyfunctional fluoroalkanes containing groups which are reactive with the epoxy groups and/or with the hydroxy groups present in the starting resin. The cross-linked products so obtained, having a fluorine content not higher than 15% by weight, and preferably ranging from 1% to 5%, exhibit a complex of properties which are typical of the corresponding fluorinated resins having a much higher fluorine content; in particular, oil- and water-repellency, resistance to hydrolysis and to solvents, and minimum absorption of water.

公开(公告)号：US4699969A

公开(公告)日：1987-10-13

申请号：US888160

申请日：1986-07-22

申请人： Alberto Re ,  Tiziano Terenghi

发明人： Alberto Re ,  Tiziano Terenghi

IPC分类号： C08G65/28 ,  C08G18/10 ,  C08G18/50 ,  C08G18/58 ,  C08G18/77 ,  C08G59/04 ,  C08G59/30 ,  C08G65/32 ,  C09D171/00 ,  C09D171/02 ,  C09J171/00 ,  C09J171/02 ,  G11B5/72 ,  G11B7/254 ,  G11B7/257

CPC分类号： C08G59/04 ,  C08G18/5015 ,  C08G18/582 ,  C08G59/30 ,  Y10S428/90 ,  Y10T428/31511 ,  Y10T428/31529 ,  Y10T428/31554

摘要： New resins containing urethane and/or epoxy bonds are prepared starting from fluorinated polymers having an epoxy structure and exhibiting structural characteristics predominantly typical of epoxides or of polyols, said polymers being prepared by synthesis from one or more diols, at least one of which being a perfluoropolyoxyalkylene diol, and from epichlorohydrin; said polymers are subsequently subjected to a treatment with isocyanated if their structural characteristics are predominantly those of polyols, or with polyamines or anhydrides if their structural characteristics are predominantly those of epoxides.

摘要翻译： 含有氨基甲酸乙酯和/或环氧键的新树脂从具有环氧结构的氟化聚合物开始制备，具有主要典型的环氧化物或多元醇的结构特征，所述聚合物通过从一种或多种二醇合成制备，其中至少一种是 全氟聚氧亚烷基二醇和表氯醇; 如果所述聚合物的结构特征主要是多元醇的结构特征，或者如果其结构特征主要是环氧化物的结构特征，则用聚胺或酸酐进行异氰酸酯处理。

公开(公告)号：US4782130A

公开(公告)日：1988-11-01

申请号：US828681

申请日：1986-02-12

申请人： Alberto Re ,  Ezio Strepparola ,  Piero Gavezzotti

发明人： Alberto Re ,  Ezio Strepparola ,  Piero Gavezzotti

IPC分类号： C08G18/00 ,  C06B45/10 ,  C08G18/10 ,  C08G18/50 ,  C08G18/65 ,  C08G18/66 ,  C08G18/77 ,  C09J175/08 ,  C08G18/32

CPC分类号： C09J175/08 ,  C06B45/10 ,  C08G18/10 ,  C08G18/5015 ,  C08G18/773

摘要： Fluorinated polyurethanes, having improved mechanical characteristics and a glass transition temperature lower than -80.degree. C., containing polyoxyperfluoroalkylene blocks deriving from perfluoropolyethers having hydroxylated end groups and/or from perfluoropolyethers having isocyanate end groups and furthermore units deriving from an aromatic or a cycloaliphatic diol.

摘要翻译： 氟化聚氨酯具有改善的机械特性和低于-80℃的玻璃化转变温度，其含有衍生自具有羟基端基的全氟聚醚和/或具有异氰酸酯端基的全氟聚醚的聚氧化全氟亚烷基嵌段以及衍生自芳族或脂环族二醇的单元 。