Polymerizable compositions containing ethylenically unsaturated monomers having episulfide functional groups and related methods
    7.
    发明授权
    Polymerizable compositions containing ethylenically unsaturated monomers having episulfide functional groups and related methods 有权
    含有具有环硫官能团的烯属不饱和单体和相关方法的可聚合组合物

    公开(公告)号:US09051426B2

    公开(公告)日:2015-06-09

    申请号:US13864785

    申请日:2013-04-17

    摘要: Provided is a polymerizable composition of (a) a monomer composition including ethylenically unsaturated monomer having a β-epithiopropyl functional group; (b) optionally, a compound having two or more β-epithiopropyl functional groups but no polymerizable ethylenically unsaturated groups; (c) an isourea functional polymerization initiator; and (d) a catalyst for reaction between the β-epithiopropyl functional groups. Also provided is a method of reducing the yellowness index of a sulfur-containing polymerizate prepared by addition polymerization, the method including reacting in the presence of an isourea functional polymerization initiator and a catalyst for reaction between β-epithiopropyl functional groups, a polymerizable composition of: (a) a monomer composition including ethylenically unsaturated monomer having a β-epithiopropyl functional group; and, optionally, (b) a compound having two or more β-epithiopropyl functional groups but no polymerizable ethylenically unsaturated groups.

    摘要翻译: 本发明提供(a)含有具有β-伯硫丙基官能团的烯属不饱和单体的单体组合物的聚合性组合物, (b)任选地,具有两个或更多个β-伯硫丙基官能团但不具有可聚合的烯属不饱和基团的化合物; (c)异脲官能聚合引发剂; 和(d)用于在反应中的反应的催化剂。 还提供了降低通过加成聚合制备的含硫聚合物的黄度指数的方法,该方法包括在异脲官能聚合引发剂和用于反应的催化剂之间进行反应, (a)单体组合物,其包含具有“ - 硫代丙基”官能团的烯属不饱和单体; 和任选地,(b)具有两个或更多个β-伯硫丙基官能团但不具有可聚合的烯属不饱和基团的化合物。

    Preparation of homopolymer and copolymers of (phosphonyl)aromatic diesters and acids
    9.
    发明授权
    Preparation of homopolymer and copolymers of (phosphonyl)aromatic diesters and acids 有权
    (膦酰基)芳族二酯和酸的均聚物和共聚物的制备

    公开(公告)号:US08722846B2

    公开(公告)日:2014-05-13

    申请号:US13314616

    申请日:2011-12-08

    IPC分类号: C08G63/68 C07C67/08

    CPC分类号: C08G63/6926

    摘要: The composition of a homopolymer of (phosphonyl) aromatic diester compound using a catalyst and a glycol is provided. Further, the composition of a copolymer of the (phosphonyl) aromatic diester compound using a catalyst, a glycol and a second diester is provided. These polymers find application as flame retardants during synthesis of various polymeric materials.

    摘要翻译: 提供使用催化剂和二醇的(膦酰基)芳族二酯化合物的均聚物的组成。 此外,提供了使用催化剂,二醇和第二二酯的(膦酰基)芳族二酯化合物的共聚物的组成。 这些聚合物在合成各种聚合材料期间被用作阻燃剂。