公开(公告)号：US09433936B2

公开(公告)日：2016-09-06

申请号：US14196019

申请日：2014-03-04

申请人： Scott J. Weigel ,  Joseph Emmanuel Gatt ,  Darryl Donald Lacy ,  Randall D. Partidge ,  Kun Wang ,  Lei Zhang ,  Christine Nicole Elia

发明人： Scott J. Weigel ,  Joseph Emmanuel Gatt ,  Darryl Donald Lacy ,  Randall D. Partidge ,  Kun Wang ,  Lei Zhang ,  Christine Nicole Elia

IPC分类号： B01J29/06 ,  B01J29/76 ,  B01J29/12 ,  B01J29/74 ,  B01J29/14 ,  B01J29/44 ,  B01J29/46 ,  B01J29/78 ,  C10G45/64 ,  C10G45/02 ,  C10G45/06 ,  C10G45/10 ,  C10G45/12 ,  C10G45/62 ,  C10G3/00 ,  B01J37/00

CPC分类号： B01J29/7661 ,  B01J29/12 ,  B01J29/126 ,  B01J29/14 ,  B01J29/44 ,  B01J29/46 ,  B01J29/7415 ,  B01J29/7461 ,  B01J29/7492 ,  B01J29/7615 ,  B01J29/7815 ,  B01J29/7861 ,  B01J37/0009 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  C10G3/44 ,  C10G3/47 ,  C10G3/48 ,  C10G3/50 ,  C10G45/02 ,  C10G45/06 ,  C10G45/10 ,  C10G45/12 ,  C10G45/62 ,  C10G45/64 ,  C10G2300/1014 ,  C10G2400/02 ,  C10G2400/04 ,  Y02P30/20

摘要： Provided are catalysts including: a zeolite component selected from zeolites having 10-member ring pores, zeolites having 12-member ring pores and a combination thereof, 0.1 to 5 weight % of a hydrogenation component selected from Pt, Pd, Ag, Ni, Co, Mo, W, Rh, Re, Ru, Ir and a mixture thereof, and a hydrothermally stable binder component selected from tantalum oxide, tungsten oxide, molybdenum oxide, vanadium oxide, magnesium oxide, calcium oxide, yttrium oxide, lanthanum oxide, cerium oxide, niobium oxide, tungstated zirconia, cobalt molybdenum oxide, cobalt molybdenum sulfide, nickel molybdenum oxide, nickel molybdenum sulfide, nickel tungsten oxide, nickel tungsten sulfide, cobalt tungsten oxide, cobalt tungsten sulfide, nickel molybdenum tungsten oxide and nickel molybdenum tungsten sulfide, cobalt molybdenum tungsten oxide and cobalt molybdenum tungsten sulfide, wherein the weight ratio of the zeolite to the hydrothermally stable binder is 85:15 to 25:75.

摘要翻译： 提供的催化剂包括：选自具有10元环孔的沸石的沸石组分，具有12元环孔的沸石及其组合，0.1〜5重量％的选自Pt，Pd，Ag，Ni，Co的氢化组分 ，Mo，W，Rh，Re，Ru，Ir及其混合物，以及选自氧化钽，氧化钨，氧化钼，氧化钒，氧化镁，氧化钙，氧化钇，氧化镧，铈的水热稳定的粘合剂成分 氧化物，氧化铌，钨酸氧化锆，钴钼氧化物，钴硫化钼，镍钼氧化物，镍钼硫化物，镍钨氧化物，镍硫化钨，钴钨氧化物，硫化钴硫化物，镍钼钨氧化物和镍钼硫化钨， 钴钼氧化钨和钴钼硫化钨，其中沸石与水热稳定粘合剂的重量比为85:15至25:75。

公开(公告)号：US20150152343A1

公开(公告)日：2015-06-04

申请号：US14541393

申请日：2014-11-14

申请人： Rohit VIJAY ,  Ajit Bhaskar DANDEKAR ,  Michel DAAGE ,  Christopher G. OLIVERI ,  Christine Nicole ELIA ,  Darryl Donald LACY ,  Scott J. WEIGEL ,  Bradley R. FINGLAND

发明人： Rohit VIJAY ,  Ajit Bhaskar DANDEKAR ,  Michel DAAGE ,  Christopher G. OLIVERI ,  Christine Nicole ELIA ,  Darryl Donald LACY ,  Scott J. WEIGEL ,  Bradley R. FINGLAND

IPC分类号： C10G67/14 ,  C10G69/08 ,  C10G67/02

CPC分类号： C10G67/14 ,  C10G65/12 ,  C10G67/02 ,  C10G69/08 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/301 ,  C10G2300/4025 ,  C10G2400/04 ,  C10G2400/10

摘要： Methods are provided for improving the yield of distillate products from hydroprocessing of gas oil feedstocks, such as vacuum gas oils. It has been unexpectedly found that stripping of gases or fractionation to separate out a distillate fraction during initial hydrotreatment of a feed can provide a substantial increase in distillate yield at a desired amount of feedstock conversion. The improvement in yield of distillate products can allow a desired level of conversion to be performed on a feedstock for generating lubricating base oil products while reducing or minimizing the amount of naphtha (or lower) boiling range products. Alternatively, the improvement in yield of distillate products can correspond to an improved yield during a single pass through a reaction system, so that distillate yield is increased even though a lubricant boiling range product is not generated.

摘要翻译： 提供了用于提高瓦斯油原料如真空瓦斯油加氢处理的馏出物产率的方法。 已经意外地发现，在进料的初始加氢处理期间汽提汽提或分馏以分离出馏出物馏分可以在所需量的原料转化率下提供馏出物产率的显着增加。 馏出物产品的产率的提高可以使得在用于产生润滑基础油产品的原料上进行所需水平的转化，同时减少或最小化石脑油（或更低）沸点产物的量。 或者，馏出物产物的产率的提高可以对应于在单次通过反应体系期间提高的产率，使得即使不产生润滑剂沸程产物，馏出物产率也增加。

公开(公告)号：US08778171B2

公开(公告)日：2014-07-15

申请号：US13412945

申请日：2012-03-06

申请人： Christopher G. Oliveri ,  Wenyih Frank Lai ,  Ajit B. Dandekar ,  Scott J. Weigel ,  Jason Wu ,  Robert E. Kay

发明人： Christopher G. Oliveri ,  Wenyih Frank Lai ,  Ajit B. Dandekar ,  Scott J. Weigel ,  Jason Wu ,  Robert E. Kay

IPC分类号： B01J29/08 ,  B01J29/06 ,  B01J29/10 ,  B01J29/12 ,  C10G47/10 ,  C10G47/12 ,  C10G47/14 ,  C10G47/18

CPC分类号： B01J35/002 ,  B01J29/084 ,  B01J29/126 ,  B01J29/146 ,  B01J29/166 ,  B01J29/80 ,  B01J35/023 ,  B01J35/04 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/1085 ,  B01J35/109 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/42 ,  C01B39/24 ,  C10G47/18 ,  C10G47/20

摘要： This invention relates to hydrocracking catalysts utilizing stabilized aggregates of small primary crystallites of zeolite Y that are clustered into larger secondary particles. At least 80% of the secondary particles may comprise at least 5 primary crystallites. The size of the primary crystallites may be at most about 0.5 micron, or at most about 0.3 micron, and the size of the secondary particles may be at least about 0.8 micron, or at least about 1.0 μm. The silica to alumina ratio of the resulting stabilized aggregated Y zeolite may be 4:1 or more. This invention also relates to the use of such catalysts in hydrocracking processes for the conversion of heavy oils into lighter fuel products. The invention is particularly suited for the selective production of diesel range products from gas oil range feedstock materials under hydrocracking conditions.

摘要翻译： 本发明涉及使用聚集成更大二次粒子的沸石Y的小初级晶体的稳定聚集体的加氢裂化催化剂。 至少80％的二次粒子可以包含至少5个初级微晶。 初级微晶的尺寸可以为至多约0.5微米，或至多约0.3微米，并且二次颗粒的尺寸可以为至少约0.8微米，或至少约1.0微米。 得到的稳定的聚集Y型沸石的二氧化硅与氧化铝的比例可以为4:1以上。 本发明还涉及这种催化剂在加氢裂化方法中用于将重油转化成较轻燃料产物的用途。 本发明特别适用于在加氢裂化条件下从瓦斯油原料中选择性生产柴油产品。

公开(公告)号：US20130333391A1

公开(公告)日：2013-12-19

申请号：US13917101

申请日：2013-06-13

申请人： NARASIMHAN SUNDARAM ,  RAMESH GUPTA ,  HANS THOMANN ,  HUGO S. CARAM ,  LOREN K. STARCHER ,  FRANKLIN F. Mittricker ,  SIMON C. WESTON ,  SCOTT J. WEIGEL

发明人： NARASIMHAN SUNDARAM ,  RAMESH GUPTA ,  HANS THOMANN ,  HUGO S. CARAM ,  LOREN K. STARCHER ,  FRANKLIN F. Mittricker ,  SIMON C. WESTON ,  SCOTT J. WEIGEL

IPC分类号： F02C3/34 ,  B01D53/047 ,  F02C6/04

CPC分类号： F02C3/34 ,  B01D53/047 ,  B01D2253/1124 ,  B01D2256/10 ,  B01D2257/504 ,  B01D2258/0283 ,  B01D2259/40056 ,  F01K17/04 ,  F02C6/04 ,  F02C9/16 ,  F05D2220/31 ,  F05D2220/32 ,  F05D2260/61 ,  F23J2215/50 ,  Y02C10/04 ,  Y02C10/08 ,  Y02E20/14 ,  Y02E20/16

摘要： Systems and methods are provided for combined cycle power generation while reducing or mitigating emissions during power generation. Recycled exhaust gas from a power generation combustion reaction can be separated using a swing adsorption process so as to generate a high purity CO2 stream while reducing/minimizing the energy required for the separation and without having to reduce the temperature of the exhaust gas. This can allow for improved energy recovery while also generating high purity streams of carbon dioxide and nitrogen.

摘要翻译： 提供系统和方法用于联合循环发电，同时减少或减少发电过程中的排放。 来自发电燃烧反应的回收废气可以使用回转吸附法分离，以产生高纯度CO 2流，同时减少/最小化分离所需的能量，而不必降低废气的温度。 这可以改善能量回收同时产生高纯度的二氧化碳和氮气流。

公开(公告)号：US5354360A

公开(公告)日：1994-10-11

申请号：US3191

申请日：1993-01-11

申请人： Charles G. Coe ,  James E. MacDougall ,  Scott J. Weigel

发明人： Charles G. Coe ,  James E. MacDougall ,  Scott J. Weigel

IPC分类号： B01D53/04 ,  B01J20/18

CPC分类号： B01D53/02 ,  B01D53/04 ,  B01J20/186 ,  B01D2253/108 ,  B01D2256/12 ,  B01D2257/102 ,  Y10S95/902

摘要： The present invention is directed to a process for separating nitrogen from gas mixtures containing nitrogen and less strongly adsorbed components such as oxygen, hydrogen, argon or helium at ambient temperatures or above by use of a magnesium exchanged, sodium A-zeolite in a preferred level of magnesium exchange and an appropriate pressure range for adsorption and desorption of bulk gases which provides improved recovery and reduced bed size factor.

摘要翻译： 本发明涉及一种通过使用镁交换的α-沸石在优选水平中从氮气和气体混合物中分离氮气的方法，所述气体混合物包含氮气和较弱吸附组分如氧气，氢气，氩气或氦气。 的镁交换和用于散装气体的吸附和解吸的适当压力范围，其提供改进的回收率和减小的床尺寸因子。

公开(公告)号：US09504995B2

公开(公告)日：2016-11-29

申请号：US14054038

申请日：2013-10-15

申请人： Allen W. Burton ,  Scott J. Weigel

发明人： Allen W. Burton ,  Scott J. Weigel

IPC分类号： C01B39/04 ,  C01B39/48 ,  B01J29/70

CPC分类号： B01J29/70 ,  C01B39/04 ,  C01B39/48

摘要： An aspect of the invention relates to a method of synthesizing a crystalline molecular sieve having an MSE framework type, the method comprising crystallizing a reaction mixture comprising a source of water, a source of an oxide of a tetravalent element, Y, selected from at least one of silicon, tin, titanium, vanadium, and germanium, optionally but preferably a source of a trivalent element, X, a source of an alkali or alkaline earth metal, M, a source of a tetraethylammonium cation, Q1, and optionally a source of a second organic cation, Q2, which can include a cyclic nitrogen-containing ammonium cation.

摘要翻译： 本发明的一个方面涉及一种合成具有MSE骨架类型的结晶分子筛的方法，所述方法包括使包含水源的反应混合物，四价元素的氧化物源Y至少结晶，所述Y选自至少 硅，锡，钛，钒和锗中的一种，任选但优选为三价元素的源X，碱金属或碱土金属的源，M，四乙基铵阳离子源，Q1和任选的源 的第二有机阳离子Q2可以包括环状含氮铵阳离子。

公开(公告)号：US09476356B2

公开(公告)日：2016-10-25

申请号：US13917101

申请日：2013-06-13

申请人： Narasimhan Sundaram ,  Ramesh Gupta ,  Hans Thomann ,  Hugo S. Caram ,  Loren K. Starcher ,  Franklin F. Mittricker ,  Simon C. Weston ,  Scott J. Weigel

发明人： Narasimhan Sundaram ,  Ramesh Gupta ,  Hans Thomann ,  Hugo S. Caram ,  Loren K. Starcher ,  Franklin F. Mittricker ,  Simon C. Weston ,  Scott J. Weigel

IPC分类号： F02C6/04 ,  F02C3/34 ,  B01D53/047

CPC分类号： F02C3/34 ,  B01D53/047 ,  B01D2253/1124 ,  B01D2256/10 ,  B01D2257/504 ,  B01D2258/0283 ,  B01D2259/40056 ,  F01K17/04 ,  F02C6/04 ,  F02C9/16 ,  F05D2220/31 ,  F05D2220/32 ,  F05D2260/61 ,  F23J2215/50 ,  Y02C10/04 ,  Y02C10/08 ,  Y02E20/14 ,  Y02E20/16

摘要： Systems and methods are provided for combined cycle power generation while reducing or mitigating emissions during power generation. Recycled exhaust gas from a power generation combustion reaction can be separated using a swing adsorption process so as to generate a high purity CO2 stream while reducing/minimizing the energy required for the separation and without having to reduce the temperature of the exhaust gas. This can allow for improved energy recovery while also generating high purity streams of carbon dioxide and nitrogen.

摘要翻译： 提供系统和方法用于联合循环发电，同时减少或减少发电过程中的排放。 来自发电燃烧反应的回收废气可以使用回转吸附法分离，以产生高纯度CO 2流，同时减少/最小化分离所需的能量，而不必降低废气的温度。 这可以改善能量回收同时产生高纯度的二氧化碳和氮气流。

公开(公告)号：US20140275688A1

公开(公告)日：2014-09-18

申请号：US14196035

申请日：2014-03-04

申请人： Scott J. Weigel ,  Joseph Emmanuel Gatt ,  Darryl Donald Lacy ,  Randall D. Partridge ,  Kun Wang ,  Lei Zhang ,  Christine Nicole Elia ,  Jenna Lynn Walp

发明人： Scott J. Weigel ,  Joseph Emmanuel Gatt ,  Darryl Donald Lacy ,  Randall D. Partridge ,  Kun Wang ,  Lei Zhang ,  Christine Nicole Elia ,  Jenna Lynn Walp

IPC分类号： C10G3/00

CPC分类号： C10G3/50 ,  C10G3/45 ,  C10G3/46 ,  C10G3/47 ,  C10G3/49 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/70 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10G2400/10 ,  Y02P30/20

摘要： Provided are methods for producing a lube base stock and/or a fuel from a feedstock of biological origin, the method including: contacting the feedstock in the presence of a catalyst to produce a lube base stock and/or a fuel, wherein the catalyst comprises: a zeolite component selected from a zeolite having 10-member ring pores, a zeolite having 12-member ring pores and a combination thereof, 0.1 to 5 weight % of a hydrogenation component selected from Pt, Pd, Ag, Ni, Co, Mo, W, Rh, Re, Ru, Ir and a mixture thereof, and a hydrothermally stable binder component.

摘要翻译： 提供了从生物来源的原料生产润滑油基础油料和/或燃料的方法，该方法包括：在催化剂存在下使原料接触以制备润滑油基础油料和/或燃料，其中催化剂包含 ：选自具有10元环孔的沸石的沸石成分，具有12元环孔的沸石及其组合，0.1〜5重量％的选自Pt，Pd，Ag，Ni，Co，Mo的氢化成分 ，W，Rh，Re，Ru，Ir及其混合物，以及水热稳定的粘合剂组分。

公开(公告)号：US20130026070A1

公开(公告)日：2013-01-31

申请号：US13412945

申请日：2012-03-06

申请人： Christopher G. Oliveri ,  Wenyih Frank Lai ,  Ajit B. Dandekar ,  Scott J. Weigel ,  Jason Wu ,  Robert E. Kay

发明人： Christopher G. Oliveri ,  Wenyih Frank Lai ,  Ajit B. Dandekar ,  Scott J. Weigel ,  Jason Wu ,  Robert E. Kay

IPC分类号： C10G47/20 ,  B01J29/08 ,  B01J29/80 ,  B01J29/65 ,  B01J29/60 ,  B01J29/18 ,  B01J29/14 ,  C10G47/18 ,  B01J29/40 ,  B82Y30/00

CPC分类号： B01J35/002 ,  B01J29/084 ,  B01J29/126 ,  B01J29/146 ,  B01J29/166 ,  B01J29/80 ,  B01J35/023 ,  B01J35/04 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/1085 ,  B01J35/109 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/42 ,  C01B39/24 ,  C10G47/18 ,  C10G47/20

摘要： This invention relates to hydrocracking catalysts utilizing stabilized aggregates of small primary crystallites of zeolite Y that are clustered into larger secondary particles. At least 80% of the secondary particles may comprise at least 5 primary crystallites. The size of the primary crystallites may be at most about 0.5 micron, or at most about 0.3 micron, and the size of the secondary particles may be at least about 0.8 micron, or at least about 1.0 μm. The silica to alumina ratio of the resulting stabilized aggregated Y zeolite may be 4:1 or more. This invention also relates to the use of such catalysts in hydrocracking processes for the conversion of heavy oils into lighter fuel products. The invention is particularly suited for the selective production of diesel range products from gas oil range feedstock materials under hydrocracking conditions.

摘要翻译： 本发明涉及使用聚集成更大二次粒子的沸石Y的小初级晶体的稳定聚集体的加氢裂化催化剂。 至少80％的二次粒子可以包含至少5个初级微晶。 初级微晶的尺寸可以为至多约0.5微米，或至多约0.3微米，并且二次颗粒的尺寸可以为至少约0.8微米，或至少约1.0微米。 得到的稳定的聚集Y型沸石的二氧化硅与氧化铝的比例可以为4:1以上。 本发明还涉及这种催化剂在加氢裂化方法中用于将重油转化成较轻燃料产物的用途。 本发明特别适用于在加氢裂化条件下从瓦斯油原料中选择性生产柴油产品。

公开(公告)号：US10001091B2

公开(公告)日：2018-06-19

申请号：US15345715

申请日：2016-11-08

申请人： Brian M. Weiss ,  Walter Weissman ,  Tilman W. Beutel ,  John F. Brody ,  Eugine Choi ,  Wenjun Li ,  Paul D. Madiara ,  Chris E. Esther Kliewer ,  Karl G. Strohmaier ,  Scott J. Weigel ,  Brett Loveless ,  Makoto Kioke ,  Hiroshi Miyagawa

发明人： Brian M. Weiss ,  Walter Weissman ,  Tilman W. Beutel ,  John F. Brody ,  Eugine Choi ,  Wenjun Li ,  Paul D. Madiara ,  Chris E. Esther Kliewer ,  Karl G. Strohmaier ,  Scott J. Weigel ,  Brett Loveless ,  Makoto Kioke ,  Hiroshi Miyagawa

IPC分类号： F01N3/20 ,  F02M27/02 ,  C10L3/10 ,  F02B43/12 ,  F02B51/02 ,  F02M21/02 ,  B01J29/44 ,  B01J29/74 ,  B01J29/80 ,  C10L3/00 ,  C01B3/40 ,  B01J23/63 ,  B01J29/068 ,  F02M26/35 ,  F02M26/36 ,  F02M26/20 ,  B01J21/04 ,  B01J21/08 ,  B01J23/10 ,  B01J23/46 ,  B01J29/00 ,  B01J29/70 ,  B01J29/85 ,  C10L3/08 ,  F02B37/013 ,  F02B43/10 ,  F02M26/05

CPC分类号： F02M27/02 ,  B01J21/04 ,  B01J21/08 ,  B01J23/10 ,  B01J23/464 ,  B01J23/63 ,  B01J29/005 ,  B01J29/068 ,  B01J29/44 ,  B01J29/70 ,  B01J29/743 ,  B01J29/80 ,  B01J29/85 ,  B01J2523/00 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/1047 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/1247 ,  C01B2203/84 ,  C10L3/00 ,  C10L3/08 ,  C10L3/10 ,  C10L2230/22 ,  C10L2270/02 ,  C10L2290/02 ,  C10L2290/06 ,  C10L2290/24 ,  F01N3/20 ,  F02B37/013 ,  F02B43/12 ,  F02B51/02 ,  F02B61/02 ,  F02B2043/103 ,  F02M21/0227 ,  F02M26/05 ,  F02M26/20 ,  F02M26/35 ,  F02M26/36 ,  Y02P20/142 ,  Y02P20/52 ,  Y02T10/126 ,  Y02T10/32 ,  B01J2523/31 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/822

摘要： Catalyst compositions suitable for use in the exhaust gas recycle stream of an internal combustion engine are provided. Such catalyst compositions typically provide significant amounts of methane in addition to syngas. A reformer incorporating such a catalyst for use in an exhaust gas recycle portion of an internal combustion engine powertrain is described. A powertrain incorporating such a reformer, a method of increasing the octane rating of an exhaust gas recycle stream, and a method of operating an internal combustion engine using methane-assisted combustion are also described.