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1.发明授权公开(公告)号：US12173240B2
公开(公告)日：2024-12-24
申请号：US18042713
申请日：2021-08-20
Applicant: Petróleo Brasileiro S.A. - Petrobras
Inventor： Jefferson Roberto Gomes , Jose Luiz Zotin , Rodrigo Caetano Chistone , Anilza De Almeida Lyra Correa , Marcelo Edral Pacheco
Abstract: The present invention relates to a process for converting vegetable oils, animal fats, residual edible oils and carboxylic acids into renewable liquid fuels, such as bionaphtha, bioJET-A1 and renewable diesel, for use in a mixture with fossil fuels. The process consists of two steps: hydrotreating and hydrocracking. The effluent from the hydrotreatment step presents aromatics, olefins and compounds resulting from the polymerization of esters and acids in its composition. This fact occurs due to the use of partially reduced catalysts and without injection of sulfide agent and allows obtaining a bioJET-A1 with adequate quality for use in a mixture with fossil kerosene. At the same time, the process generates, in addition to products in the distillation range of naphtha, kerosene and diesel, high molecular weight linear paraffins (with up to 40 carbon atoms).
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2.发明公开公开(公告)号：US20230332057A1
公开(公告)日：2023-10-19
申请号：US18042713
申请日：2021-08-20
Applicant: Petróleo Brasileiro S.A. - Petrobras
Inventor： Jefferson Roberto Gomes , Jose Luiz Zotin , Rodrigo Caetano Chistone , Anilza De Almeida Lyra Correa , Marcelo Edral Pacheco
CPC classification number: C10G47/18 , B01J23/44 , B01J29/7415 , B01J29/7484 , B01J29/7492 , B01J35/026 , C10G3/50 , C10G69/126 , C10G2300/1014 , C10G2300/1018 , C10G2300/1088 , C10G2300/1096 , C10G2400/08
Abstract: The present invention relates to a process for converting vegetable oils, animal fats, residual edible oils and carboxylic acids into renewable liquid fuels, such as bionaphtha, bioJET-A1 and renewable diesel, for use in a mixture with fossil fuels. The process consists of two steps: hydrotreating and hydrocracking. The effluent from the hydrotreatment step presents aromatics, olefins and compounds resulting from the polymerization of esters and acids in its composition. This fact occurs due to the use of partially reduced catalysts and without injection of sulfide agent and allows obtaining a bioJET-A1 with adequate quality for use in a mixture with fossil kerosene. At the same time, the process generates, in addition to products in the distillation range of naphtha, kerosene and diesel, high molecular weight linear paraffins (with up to 40 carbon atoms).
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公开(公告)号：US11420192B2
公开(公告)日：2022-08-23
申请号：US16940711
申请日：2020-07-28
Applicant: Saudi Arabian Oil Company , JGC Catalysts and Chemicals, Ltd. , Japan Cooperation Center Petroleum
Inventor： Omer Refa Koseoglu , Robert Peter Hodgkins , Mitsunori Watabe , Koji Uchida
Abstract: In accordance with one or more embodiments of the present disclosure, a catalyst composition includes a catalyst support and at least one hydrogenative component disposed on the catalyst support. The catalyst support includes at least one USY zeolite having a framework substituted with titanium and zirconium. The framework-substituted USY zeolite comprises at least one rare earth element. Methods of making and using such a catalyst in a hydrocracking process are also disclosed.
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公开(公告)号：US11186787B2
公开(公告)日：2021-11-30
申请号：US16527861
申请日：2019-07-31
Applicant: ExxonMobil Research and Engineering Company
Inventor： Rugved P. Pathare , Lisa I-Ching Yeh , Yogi V. Shukla , Charles L. Baker, Jr. , Bryan E. Hagee , Debra A. Sysyn , Kendall S. Fruchey
IPC: C10G65/12 , C10G47/18 , C10M101/02 , C10G69/02 , C10N20/00 , C10N20/02 , C10N30/02 , C10N30/08 , C10N30/10 , C10N40/12 , C10N40/25
Abstract: A base stock having at least 90 wt. % saturates, an amount and distribution of aromatics, as determined by ultra violet (UV) spectroscopy, including an absorptivity between 280 and 320 nm of less than 0.015 l/gm-cm, a viscosity index (VI) from 80 to 120, and having a cycloparaffin performance ratio greater than 1.05 and a kinematic viscosity at 100° C. between 4 and 6 cSt. A base stock having at least 90 wt. % saturates, an amount and distribution of aromatics, as determined by UV spectroscopy, including an absorptivity between 280 and 320 nm of less than 0.020 l/gm-cm, a viscosity index (VI) from 80 to 120, and having a cycloparaffin performance ratio greater than 1.05 and a kinematic viscosity at 100° C. between 10 and 14 cSt. A lubricating oil having the base stock as a major component, and one or more additives as a minor component. Methods for improving oxidation performance and low temperature performance of formulated lubricant compositions through the compositionally advantaged base stock.
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公开(公告)号：US11180704B2
公开(公告)日：2021-11-23
申请号：US16079789
申请日：2017-02-21
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Maikel van Iersel , Luis Aramburo , Andrew Davies , Emiel van Kimmenade
Abstract: The present invention relates to a process for producing LPG and BTX from a mixed feedstream comprising C5-C12 hydrocarbons by contacting said feedstream in the presence of hydrogen with a first hydrocracking catalyst and contacting the thus obtained first hydrocracked product in the presence of hydrogen with a second hydrocracking catalyst to produce a second hydrocracked product stream comprising LPG and BTX.
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Patent Agency Ranking
公开(公告)号：US11072751B1
公开(公告)日：2021-07-27
申请号：US16851536
申请日：2020-04-17
Applicant: Saudi Arabian Oil Company
Inventor： Omer Refa Koseoglu
Abstract: An integrated process is provided herein having a first reaction zone to lower sulfur and nitrogen content of the initial feedstock to a target level to facilitate processing in a second reaction zone for deep hydrogenation. With the very low heteroatom content, noble metal catalyst materials used in the second reaction zone are protected and maximum saturation of aromatics is achieved. The processes and systems herein are suitable for converting certain heavy fractions, typically considered “low value” feedstocks, into higher value products including gasoline and diesel, and a hydrogen-rich, aromatic-lean heavy fraction suitable as feed for olefin production processes, or as a lubricant base oil.
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公开(公告)号：US10920159B2
公开(公告)日：2021-02-16
申请号：US16527718
申请日：2019-07-31
Applicant: ExxonMobil Research and Engineering Company
Inventor： Rugved P. Pathare , Lisa I-Ching Yeh , Yogi V. Shukla , Charles L. Baker, Jr. , Bryan E. Hagee , Debra A. Sysyn , Kendall S. Fruchey
IPC: C10G65/12 , C10G47/18 , C10M101/02 , C10G69/02 , C10N20/00 , C10N20/02 , C10N30/02 , C10N30/08 , C10N30/10 , C10N40/12 , C10N40/25
Abstract: A base stock having at least 90 wt. % saturates, an amount and distribution of aromatics, as determined by ultra violet (UV) spectroscopy, including an absorptivity between 280 and 320 nm of less than 0.015 l/gm-cm, a viscosity index (VI) from 80 to 120, and having a cycloparaffin performance ratio greater than 1.05 and a kinematic viscosity at 100° C. between 4 and 6 cSt. A base stock having at least 90 wt. % saturates, an amount and distribution of aromatics, as determined by UV spectroscopy, including an absorptivity between 280 and 320 nm of less than 0.020 l/gm-cm, a viscosity index (VI) from 80 to 120, and having a cycloparaffin performance ratio greater than 1.05 and a kinematic viscosity at 100° C. between 10 and 14 cSt. A lubricating oil having the base stock as a major component, and one or more additives as a minor component. Methods for improving oxidation performance and low temperature performance of formulated lubricant compositions through the compositionally advantaged base stock.
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公开(公告)号：US10793491B2
公开(公告)日：2020-10-06
申请号：US15318154
申请日：2015-06-01
Applicant: SABIC Global Technologies B.V.
Inventor： Dustin Fickel , Stephen Hall , Kumar Prashant , Maikel van Iersel , Sonia Farrokhpanah
IPC: C07C4/06 , C10G65/14 , C10G65/10 , B01J29/44 , C10G45/00 , C07C4/18 , C07C6/12 , C10G47/18 , C10G45/62 , C10G65/18 , C07C7/04 , B01J29/42
Abstract: A process for producing benzene comprising the steps of:(a) separating a source feedstream comprising C5-C12 hydrocarbons including benzene and alkylbenzenes into a first feedstream comprising a higher proportion of benzene than the source feedstream and a second feedstream comprising a lower proportion of benzene than the source feedstream and subsequently, (b) contacting the first feedstream in the presence of hydrogen with a first hydrocracking catalyst, and (c) contacting the second feedstream with hydrogen under second process conditions to produce a second product stream comprising benzene, wherein i) the second process conditions are suitable for hydrocracking and step (c) involves contacting the second feedstream in the presence of hydrogen with a second hydrocracking catalyst, ii) the second process conditions are suitable for toluene disproportionation and involve contacting the second feedstream with a toluene disproportionation catalyst or iii) the second process conditions are suitable for hydrodealkylation.
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公开(公告)号：US10533140B2
公开(公告)日：2020-01-14
申请号：US16306441
申请日：2017-01-31
Applicant: REVO INTERNATIONAL INC.
Inventor： Keiichi Tsuto , Yuichiro Azuma , Daisaku Shojo
IPC: B01J37/00 , C10G3/00 , B01J37/16 , B01J37/04 , B01J37/10 , B01J37/20 , C10G47/18 , B01J29/068 , B01J29/072
Abstract: A method for producing a hydrocarbon liquid fuel including hydrocracking a raw material oil in the presence of a hydrocracking catalyst, at a supplying pressure of hydrogen of from 0.1 to 1.0 MPa, a liquid space velocity of liquid volume of the raw material oil of from 0.05 to 10.0 hr−1, and a flow rate of the hydrogen from 50 to 3,000 NL per 1 L of the raw material oil, wherein the hydrocracking catalyst is produced by a method including stirring a sulfur compound and a cracking catalyst in an aqueous medium to allow liquid-solid separation (step 1); stirring a solid product obtained in the step 1 and a metal component in an aqueous medium to allow liquid-solid separation (step 2); baking a solid product obtained in the step 2 (step 3); and reducing a solid product obtained in the step 3, or reducing a solid product obtained in the step 3, and then subjecting a reduced product to sulfurization treatment (step 4). According to the present invention, the hydrocracking of a raw material oil such as fats and oils and biomass retort oils, or a hydrocarbon or the like in petroleum oils, in a given composition can be accomplished by supplying a low-pressure hydrogen of a normal pressure or so.
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公开(公告)号：US20200010772A1
公开(公告)日：2020-01-09
申请号：US16572946
申请日：2019-09-17
Applicant: ExxonMobil Research and Engineering Company
Inventor： Ajit B. Dandekar , Bradley R. Fingland , Kendall S. Fruchey , Scott J. Weigel
IPC: C10M101/02 , C10G47/18 , C10G65/12 , C10G69/02
Abstract: Systems and methods are provided for producing lubricant basestocks having a reduced or minimized aromatics content. A first processing stage can perform an initial amount of hydrotreating and/or hydrocracking. A first separation stage can then be used to remove fuels boiling range (and lower boiling range) compounds. The remaining lubricant boiling range fraction can then be exposed under hydrocracking conditions to a USY catalyst including a supported noble metal, such as Pt and/or Pd. The USY catalyst can have a desirable combination of catalyst properties, such as a unit cell size of 24.30 or less (or 24.24 or less), a silica to alumina ratio of at least 50 (or at least 80), and an alpha value of 20 or less (or 10 or less). In some aspects, the effluent from the second (hydrocracking) stage can be dewaxed without further separation. In such aspects, a portion of the dewaxed effluent can be used as a recycle quench stream to cool the hydrocracking effluent prior to entering the dewaxing reactor.
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