Abstract:
For producing synthesis gas, SG, from a hydrocarbon feed and optionally from recycled compounds, F, a first feed F1 supplemented with steam undergoes steam reforming in a multi-tube reactor-exchanger R comprising a plurality of reaction tubes (38) containing a steam reforming catalyst and a shell containing said tubes, to produce a first synthesis gas SG1; reaction tubes (38) are heated principally by convection by circulating a fluid HF in the shell external to said tubes, in which HF is a staged partial oxidation stream with oxygen of a second feed F2 at a pressure in the range 0.5 to 12 MPa, to produce a second synthesis gas SG2; and the synthesis gas SG is produced by mixing SG1 and SG2.
Abstract:
To facilitate operation of a facility for chemical conversion of a feed that comprises a reactor (2) containing a slurry constituted by at least one suspension of at least one solid in a liquid, a gas supply, and a circuit that is external of the reactor, for continuous movement of a slurry stream, wherein the external circuit withdraws slurry from the reactor from at least one point (A) and re-introduces at least a portion of the slurry at at least one other point (B), the facility is further provided with means for stopping circulation of the slurry in the circuit; means for pressurized introduction of at least one fluid for draining the slurry contained in the circuit; and means for circulating the slurry in the external circuit under conditions such that the Reynolds number is more than 2500.
Abstract:
To facilitate operation of a facility for chemical conversion of a feed that comprises a reactor (2) containing a slurry constituted by at least one suspension of at least one solid in a liquid, a gas supply, and a circuit that is external of the reactor, for continuous movement of a slurry stream, wherein the external circuit withdraws slurry from the reactor from at least one point (A) and re-introduces at least a portion of the slurry at at least one other point (B), the facility is further provided with means for stopping circulation of the slurry in the circuit; means for pressurized introduction of at least one fluid for draining the slurry contained in the circuit; and means for circulating the slurry in the external circuit under conditions such that the Reynolds number is more than 2500.
Abstract:
An elongate reaction vessel and process includes at least two stages in the vertical direction in which an endothermic or exothermic catalytic reaction is carried out and comprises: a catalytic reaction zone (12a, 12b) per stage (6, 7); introducing (2) a reaction fluid to a stage adapted for transverse motion of the fluid across the whole vertical extent of the reaction zone; introducing and extracting the catalyst; a heat exchanger (5a) for reaction fluids located inside the vessel between two successive reaction zones; means (6) for transporting reaction fluids from one stage to another preferably connected to the exchanger of the stage under consideration and to the inlet for reaction fluids of the subsequent stage; and means for recovering reaction fluids downstream of the last stage. The temperature variation in each zone and the temperature level are respectively adjusted by the thickness of each zone and by heat exchange.
Abstract:
A steam-cracking process with a very high degree of severity of a feedstock that comprises at least 20% by weight of hydrocarbons of the group that is formed by ethane and propane in which the feedstock that is diluted with water vapor is circulated in the radiation zone of a furnace, in at least one pipe with a length L≧14 m and a hydraulic diameter that is greater than or equal to 34 mm in the end portion of the pipe at least, is described under the following conditions of dwell time &tgr; and furnace output temperature COT: 120 ms≦&tgr;≦2800 ms and 858° C.≦COT≦1025° C. to obtain a conversion of at least 77% of ethane of the feedstock if the feedstock contains ethane and/or a conversion of at least 96% of the propane of the feedstock if the feedstock contains propane, and to maintain this conversion for a cycle time that is greater than or equal to about 8 days.
Abstract:
A steam cracking process and facility is described which comprises injection of erosive powder to effect at least partial decoking of transfer line exchangers without interrupting the steam cracking stream. The powder, preferably injected just upstream of the transfer line exchangers (TLE) (4), is separated from the cracked gases in primary gas/solid separators (5), temporarily stored in receiving drums at a controlled temperature and evacuated to a common powder storage and/or treatment module by pneumatic transfer by means of a relatively low flow of uncondensable gas. The process and facility can be used to collect solid fragments generated by injection of chemical compounds which are catalysts for the gasification of coke by steam.
Abstract:
The invention concerns a process for converting a stream of natural or associated gas into liquid fractions, comprising: a) a step for converting said stream of gas into a synthesis gas SG; b) a step FT for Fischer-Tropsch synthesis to convert the SG into liquid fractions; c) a step for fractionating the effluents from the Fischer-Tropsch synthesis into at least one relatively heavy fraction comprising waxes with a boiling point of 565° C. or more and at least one relatively light fraction; d) a step HCKI for isomerization hydrocracking of the relatively heavy fraction, in which at least 75% by weight of the fraction of the feed with a boiling point of more than 565° C. is converted into compounds boiling below 565° C.; e) at least one step for mixing at least the effluents from step HCKI (step d)), the light fraction from step c) and a crude oil P, to thereby produce an oil P*.
Abstract:
A process for pre-refining a crude oil P is described in which P is fractionated into several fractions, some of which are typically hydrotreated, hydrocracked or hydroconverted, then said fractions are re-composed and at least three pre-refined oils Pa, Pb, Pc are produced, Pc being a residual asphaltenic oil and Pa and Pb being two non asphaltenic oils having different ratios R wherein: R=(0.9N+0.5VGO+)/(MD+0.1VGO+), in which: N=naphtha [30° C./170° C.]; MD=middle distillates: [170° C./260° C.] and VGO+=fraction boiling above 360° C.R translates as the relative potential of a non residual oil to be converted into gasoline with respect to middle distillates during its subsequent refining.
Abstract:
Use, in a gas production region, of a purified field gas in which:a) said gas is converted into hydrogen;b) a conventional sulphur-containing transportable fluid crude P1 is supplied;c) P1 is treated without discharging carbon, comprisinga desulphurizing treatment step by hydrotreatment, hydroconversion or hydrocracking of a fraction boiling above 343° C., consuming hydrogen;a step for reducing the quantity of vacuum residue by segregation and/or conversion of a portion of said vacuum residue;so as to produce a pre-refined asphaltenes-free oil refinery feedstock PA, and a residual easily transportable liquid oil refinery feedstock;d) evacuating said prerefined oil PA to an oil port.
Abstract translation:在气体生产区域中使用纯化的场气,其中:a)将所述气体转化为氢气; b)提供常规的含硫可运输流体原油P1; c)P1处理而不排出碳,其包括通过加氢处理,加氢转化或加氢裂化沸点高于343℃的馏分进行脱硫处理步骤,消耗氢气; 通过分离和/或转化所述减压渣油的一部分来减少真空残渣量的步骤; 以便生产预精制无沥青的炼油原料P A A和残留的容易运输的液体炼油原料; d)将所述预精炼油P A A A抽空到油口。
Abstract:
A chemical conversion reactor contains a substantially vertical catalytic bed between an upper end and a lower end and comprises, in combination: close to its upper end, at least one means for introducing a solid catalyst, means for introducing and evacuating said feed allowing its flow in a substantially horizontal direction through the catalytic bed, means for heating said feed integrated into said reactor, said reactor comprising, close to its lower end, at least one means for extraction of the catalyst, which extraction is differentiated between an upstream portion and a downstream portion of said catalytic bed, with respect to the direction of flow of said feed.