公开(公告)号：US20090035621A1

公开(公告)日：2009-02-05

申请号：US12174740

申请日：2008-07-17

Applicant: Dominique Casanave ,  Fabrice Giroudiere ,  Nicolas Boudet

Inventor： Dominique Casanave ,  Fabrice Giroudiere ,  Nicolas Boudet

IPC: H01M8/06

CPC classification number: C01B3/382 ,  C01B3/38 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/066 ,  C01B2203/1229 ,  C01B2203/84 ,  H01M8/0618 ,  H01M8/0631 ,  H01M2008/1095 ,  Y02P70/56

Abstract: The invention relates to a process for co-generating electricity and hydrogen that comprises a stage a for steam reforming in the presence of water and oxygen of a hydrocarbon feedstock in which the O2/C molar ratio is to be between 0.003 and 0.2, and the H2O/C molar ratio is to be between 2 and 5, followed by a stage b for the production of electricity in a fuel cell that uses the hydrogen-rich gas that is obtained from stage a as a power source.

Abstract translation: 本发明涉及一种用于共同产生电和氢的方法，其包括在O 2 / C摩尔比在0.003和0.2之间的烃原料的水和氧存在下进行蒸汽重整的阶段a， H 2 O / C摩尔比为2〜5，接着是使用从阶段a获得的富氢气体作为动力源的燃料电池的电力生产阶段b。

公开(公告)号：US20090012188A1

公开(公告)日：2009-01-08

申请号：US11890525

申请日：2007-08-07

Applicant: Alexandre Rojey ,  Reynald Bonneau ,  Nicolas Boudet

Inventor： Alexandre Rojey ,  Reynald Bonneau ,  Nicolas Boudet

IPC: C07C27/00

CPC classification number: C01B3/36 ,  C01B2203/0233 ,  C01B2203/0255 ,  C01B2203/062 ,  C10J3/00 ,  C10J3/82 ,  C10J2300/0916 ,  C10J2300/092 ,  C10J2300/093 ,  C10J2300/1659 ,  C10J2300/1665 ,  C10J2300/1838 ,  C10J2300/1846 ,  C10J2300/1853 ,  C10K3/026 ,  Y02E50/18 ,  Y02P20/129 ,  Y02P20/145 ,  Y02P20/146

Abstract: Process for the production of liquid hydrocarbons from a feedstock that comprises at least one elementary feedstock from the group of biomass, coal, lignite, petroleum residues, methane, and natural gas, comprising: at least one stage a) for gasification of the feedstock by partial oxidation and/or steam reforming to produce a synthesis gas SG; a stage b) for separating CO2 from SG and a portion of the effluent of the subsequent stage c); the mixing of a portion of the CO2 that is separated with a gas of an H2/CO ratio of more than 3; a stage c) for partial conversion with hydrogen, thermal or thermocatalytic, of the CO2 that is present in said first mixture according to the reaction: CO2+H2→CO+H2O in a specific reaction zone that is separated from said gasification zone or zones; a stage d) for Fisher-Tropsch synthesis on a synthesis gas that comprises at least a portion of SG and at least a portion of the CO that is produced by the conversion of CO2 into hydrogen.

Abstract translation: 用于从原料生产液体烃的方法，所述原料包含来自生物质，煤，褐煤，石油残渣，甲烷和天然气组的至少一种基本原料，包括：至少一个阶段a）用于通过 部分氧化和/或蒸汽重整以产生合成气SG; 一个阶段b）从SG和后续阶段c）的一部分流出物分离CO 2; 将一部分与H2 / CO比大于3的气体分离的CO 2混合; 根据CO 2 + H 2→CO + H 2 O在与所述气化区分离的特定反应区中，存在于所述第一混合物中的CO 2部分转化为氢，热或热催化的阶段c） 区域 合成气中的Fisher-Tropsch合成阶段d），其包含至少一部分SG和通过CO 2转化为氢而产生的至少一部分CO。

公开(公告)号：US20050244329A1

公开(公告)日：2005-11-03

申请号：US11075965

申请日：2005-03-10

Applicant: Dominique Casanave ,  Nicolas Boudet

Inventor： Dominique Casanave ,  Nicolas Boudet

IPC: C01B3/26 ,  C01B3/32 ,  C01B3/48 ,  C01B3/50 ,  C01B3/54

CPC classification number: C01B3/323 ,  C01B3/326 ,  C01B3/48 ,  C01B3/501 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/0405 ,  C01B2203/0475 ,  C01B2203/048 ,  C01B2203/0811 ,  C01B2203/1047 ,  C01B2203/1217 ,  C01B2203/1229 ,  C01B2203/148 ,  C01B2203/1604 ,  C01B2203/1619 ,  C01B2203/1628 ,  C01B2203/1671 ,  C01B2203/1695 ,  Y02P20/129 ,  Y02P20/52

Abstract: Process for the production of high-purity hydrogen from an ethanol or higher-alcohol feedstock, employing a vapor reforming unit, a carbon monoxide conversion unit and a membrane separation unit and comprising intense thermal integration that is obtained by combustion under the control of an effluent of the process so as to provide the calories that are necessary to the vapor reforming reaction.

Abstract translation: 用于从乙醇或高级醇原料生产高纯度氢气的方法，采用气相重整装置，一氧化碳转化装置和膜分离装置，并且包括通过在流出物的控制下燃烧而获得的强烈热积分 以提供气相重整反应所必需的热量。

公开(公告)号：US08460406B2

公开(公告)日：2013-06-11

申请号：US11878624

申请日：2007-07-25

Applicant: Eric Lemaire ,  Nicolas Boudet

Inventor： Eric Lemaire ,  Nicolas Boudet

IPC: C10L8/00 ,  C10L5/44

CPC classification number: F23G5/02 ,  C10J3/50 ,  C10J2300/0903 ,  C10J2300/0923 ,  C10J2300/0983 ,  C10J2300/0989 ,  C10L5/44 ,  C10L9/083 ,  F23G5/027 ,  F23G5/04 ,  F23G5/20 ,  F23G5/30 ,  F23G7/02 ,  F23G7/105 ,  F23G2201/702 ,  F23G2201/80 ,  Y02E50/10 ,  Y02E50/14 ,  Y02E50/15 ,  Y02E50/30 ,  Y02P20/145

Abstract: The process of the invention describes a set of steps for preparing a solid lignocellulosic biomass type feed, alone or mixed with a liquid hydrocarbon phase with a view to supplying a unit for gasification of said feed. The various steps include drying, torrefaction, milling and constituting a suspension of particles of biomass in a hydrocarbon cut.

Abstract translation: 本发明的方法描述了用于制备单独或与液体烃相混合的固体木质纤维素生物质型进料的一组步骤，以供应用于气化所述进料的单元。 各种步骤包括干燥，烘焙，研磨和构成烃切割中生物质颗粒的悬浮液。

公开(公告)号：US08409545B2

公开(公告)日：2013-04-02

申请号：US12524510

申请日：2007-12-17

Applicant: Matthieu Rolland ,  Eric Lemarie ,  Nicolas Boudet ,  Jean-Marie Seiler ,  Sylvie Rouge

Inventor： Matthieu Rolland ,  Eric Lemarie ,  Nicolas Boudet ,  Jean-Marie Seiler ,  Sylvie Rouge

IPC: C01B3/24

CPC classification number: C10J3/64 ,  B01D2253/112 ,  B01D2258/05 ,  B01D2259/40 ,  C10G2/32 ,  C10G11/05 ,  C10G29/205 ,  C10J2300/0916 ,  C10J2300/0959 ,  C10J2300/0989 ,  C10J2300/1618 ,  C10J2300/1637 ,  C10J2300/1659 ,  C10J2300/1665 ,  C10J2300/1671 ,  C10J2300/1846 ,  C10J2300/1884 ,  C10K1/004 ,  Y02E50/18 ,  Y02E50/32 ,  Y02P20/145

Abstract: The process that is the object of the invention describes a process whose purpose is to produce a purified synthesis gas from lignocellulosic biomass that includes a pyrolysis stage, a purification stage placed upstream from the partial oxidation stage, and a cooling stage.

Abstract translation: 作为本发明的目的的方法描述了一种方法，其目的是从木质纤维素生物质产生纯化的合成气，其包括热分解阶段，位于部分氧化阶段上游的净化阶段和冷却阶段。

公开(公告)号：US08100994B2

公开(公告)日：2012-01-24

申请号：US12174740

申请日：2008-07-17

Applicant: Dominique Casanave ,  Fabrice Giroudiere ,  Nicolas Boudet

Inventor： Dominique Casanave ,  Fabrice Giroudiere ,  Nicolas Boudet

IPC: C01B3/36 ,  C10J3/46

CPC classification number: C01B3/382 ,  C01B3/38 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/066 ,  C01B2203/1229 ,  C01B2203/84 ,  H01M8/0618 ,  H01M8/0631 ,  H01M2008/1095 ,  Y02P70/56

Abstract: The invention relates to a process for co-generating electricity and hydrogen that comprises a stage a for steam reforming in the presence of water and oxygen of a hydrocarbon feedstock in which the O2/C molar ratio is to be between 0.003 and 0.2, and the H2O/C molar ratio is to be between 2 and 5, followed by a stage b for the production of electricity in a fuel cell that uses the hydrogen-rich gas that is obtained from stage a as a power source.

Abstract translation: 本发明涉及一种用于共同产生电和氢的方法，其包括在O 2 / C摩尔比在0.003和0.2之间的烃原料的水和氧存在下进行蒸汽重整的阶段a， H 2 O / C摩尔比为2〜5，接着是使用从阶段a获得的富氢气体作为动力源的燃料电池的电力生产阶段b。

公开(公告)号：US07357855B2

公开(公告)日：2008-04-15

申请号：US11442328

申请日：2006-05-30

Applicant: Eric Lenglet ,  Nicolas Boudet ,  Frédéric Hoffman

Inventor： Eric Lenglet ,  Nicolas Boudet ,  Frédéric Hoffman

IPC: C10G35/00 ,  B01J8/00

CPC classification number: B01J8/0496 ,  B01J8/0438 ,  B01J8/12

Abstract: Described are a reactor for carrying out a chemical conversion process in a catalytic bed with mechanism for supplying heat integrated into the reactor, and with a very compact reaction zone, combined with efficient use of the catalyst, and a process for converting a feed, such as a hydrocarbon feed, undergoing an endothermic reaction using the disclosed reactor.

Abstract translation: 描述了一种用于在催化床中进行化学转化过程的反应器，其具有用于提供集成到反应器中的热的机构，并且具有非常紧凑的反应区，结合有效使用催化剂，以及用于转化进料的方法 作为烃进料，使用所公开的反应器进行吸热反应。

公开(公告)号：US07070742B2

公开(公告)日：2006-07-04

申请号：US10432774

申请日：2001-11-07

Applicant: Eric Lenglet ,  Nicolas Boudet ,  Frédéric Hoffmann

Inventor： Eric Lenglet ,  Nicolas Boudet ,  Frédéric Hoffmann

IPC: B01J8/08 ,  B01J8/12 ,  F28D13/00 ,  F28D21/00

CPC classification number: B01J8/0496 ,  B01J8/003 ,  B01J8/0035 ,  B01J8/0438 ,  B01J8/087 ,  B01J8/12 ,  B01J2208/00115 ,  B01J2208/00707

Abstract: A reactor with integrated heat for carrying out a chemical conversion process in the presence of a gaseous diluent supplied through one or more ports at the upper and/or lower ends of a catalytic bed through which a feed moves substantially horizontally, and a process for converting a feed, such as a hydrocarbon feed in the reactor.

Abstract translation: 一种具有集成热量的反应器，用于在存在气态稀释剂的情况下进行化学转化过程，所述气体稀释剂通过一个或多个端口在催化床的上端和/或下端通过基本上水平地移动而进入其中; 进料，如反应器中的烃进料。

公开(公告)号：US08460633B2

公开(公告)日：2013-06-11

申请号：US11075965

申请日：2005-03-10

Applicant: Dominique Casanave ,  Nicolas Boudet

Inventor： Dominique Casanave ,  Nicolas Boudet

IPC: C01B3/26

CPC classification number: C01B3/323 ,  C01B3/326 ,  C01B3/48 ,  C01B3/501 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/0405 ,  C01B2203/0475 ,  C01B2203/048 ,  C01B2203/0811 ,  C01B2203/1047 ,  C01B2203/1217 ,  C01B2203/1229 ,  C01B2203/148 ,  C01B2203/1604 ,  C01B2203/1619 ,  C01B2203/1628 ,  C01B2203/1671 ,  C01B2203/1695 ,  Y02P20/129 ,  Y02P20/52

Abstract: Process for the production of high-purity hydrogen from an ethanol or higher-alcohol feedstock, employing a steam reforming unit, a carbon monoxide conversion unit and a membrane separation unit and comprising intense thermal integration that is obtained by combustion under the control of an effluent of the process so as to provide the calories that are necessary to the steam reforming reaction.

Abstract translation: 使用蒸汽重整单元，一氧化碳转化单元和膜分离单元从乙醇或高级醇原料生产高纯度氢的方法，包括通过在流出物的控制下燃烧而获得的强烈热积分 以提供蒸汽重整反应所必需的热量。

公开(公告)号：US20120010306A1

公开(公告)日：2012-01-12

申请号：US13144138

申请日：2009-12-03

Applicant: David Chiche ,  Nicolas Boudet ,  Jean Christophe Viguie ,  Marc Antoine Lelias ,  Olivier Ducreux

Inventor： David Chiche ,  Nicolas Boudet ,  Jean Christophe Viguie ,  Marc Antoine Lelias ,  Olivier Ducreux

IPC: C07C27/06 ,  C01B3/02

CPC classification number: B01D53/685 ,  B01D53/52 ,  B01D53/75 ,  B01D53/8606 ,  B01D53/8621 ,  B01D2253/112 ,  B01D2255/20707 ,  B01D2256/16 ,  B01D2256/20 ,  B01D2257/2042 ,  B01D2257/2045 ,  B01D2257/2047 ,  B01D2257/304 ,  B01D2257/308 ,  B01D2257/406 ,  B01D2257/408 ,  C10K1/101 ,  C10K1/16 ,  C10K1/32 ,  C10K1/34

Abstract: The invention relates to a process for finally removing sulphur-containing, nitrogen-containing and halogen-containing impurities contained in a synthesis gas, said process including: a) a joint step for hydrolysing COS and HCN contained in the gas and for collecting the halogen-containing compounds, using a TiO2-based catalyst, b) a washing step using a solvent, c) a step for desulphurisation on a collecting or adsorbing mass. The synthesis gas purified in accordance with the process of the invention contains less than 10 ppb by weight, less than 10 ppb by weight of nitrogen-containing impurities and less than 10 ppb by weight of halogen-containing impurities.

Abstract translation: 本发明涉及一种最终去除合成气中所含的含硫，含氮和含卤杂质的方法，所述方法包括：a）水解包含在气体中并用于收集卤素的COS和HCN的接合步骤 使用TiO 2类催化剂，b）使用溶剂的洗涤步骤，c）在收集或吸附质量物质上脱硫的步骤。 根据本发明方法纯化的合成气含有小于10ppb（重量），少于10ppb（重量）的含氮杂质和小于10ppb（重量）的含卤杂质。