Liquid phase oxidation of aromatic feedstocks with manganate recycling to produce carboxylic acids
    10.
    发明授权
    Liquid phase oxidation of aromatic feedstocks with manganate recycling to produce carboxylic acids 有权
    芳烃原料的液相氧化与锰酸盐再循环以产生羧酸

    公开(公告)号:US09388110B2

    公开(公告)日:2016-07-12

    申请号:US14104571

    申请日:2013-12-12

    摘要: Systems and methods for liquid-phase oxidation of an aromatic feedstock containing at least one oxidizable aromatic compound may incorporate an oxidation reactor, a separation apparatus in fluidic communication with the oxidation reactor, a solids treatment unit, and a product recovery unit in fluidic communication with the separation apparatus. The oxidation reactor may conduct liquid-phase oxidation of the oxidizable aromatic compound in the aromatic feedstock in the presence of a manganate salt to form a slurry containing liquid product and solid manganese dioxide. The separation apparatus may accept the slurry from the oxidation reactor and separate the liquid component from the solid component. The solids treatment unit accepts the solid component from the separation apparatus, treats the solid component with a basic liquid to oxidize the manganese dioxide in the solid component and form a regenerated manganate salt, which may be recycled back to the oxidation reactor.

    摘要翻译: 含有至少一种可氧化芳族化合物的芳族原料的液相氧化的系统和方法可以包括氧化反应器,与氧化反应器流体连通的分离装置,固体处理单元和与 分离装置。 氧化反应器可以在锰酸盐存在下在芳族原料中进行可氧化芳族化合物的液相氧化,形成含有液体产物和固体二氧化锰的浆料。 分离装置可以接受来自氧化反应器的浆料并将液体组分与固体组分分离。 固体处理单元接受来自分离装置的固体组分,用碱性液体处理固体组分以氧化固体组分中的二氧化锰,并形成可再循环回氧化反应器的再生锰酸盐。