SYSTEMS AND METHODS FOR PRODUCING FUEL FROM A RENEWABLE FEEDSTOCK
    73.
    发明申请
    SYSTEMS AND METHODS FOR PRODUCING FUEL FROM A RENEWABLE FEEDSTOCK 审中-公开
    从可再生饲料生产燃料的系统和方法

    公开(公告)号:US20150057477A1

    公开(公告)日:2015-02-26

    申请号:US13975096

    申请日:2013-08-23

    Applicant: UOP LLC

    Abstract: Methods and systems are provided for producing a fuel from a renewable feedstock. The method includes deoxygenating the renewable feedstock with a hydrogenation catalyst in a deoxygenation reaction zone to produce normal paraffins. The normal paraffins are isomerized to form isomerized paraffins using an isomerization catalyst in an isomerization reaction zone. Aromatic compounds are formed from non-aromatic compounds with an aromatic catalyst in an aromatic production zone downstream from the deoxygenation reaction zone.

    Abstract translation: 提供了用于从可再生原料生产燃料的方法和系统。 该方法包括在脱氧反应区中用氢化催化剂对可再生原料进行脱氧以产生正构烷烃。 使用异构化反应区中的异构化催化剂使正构链烷烃异构化形成异构烷烃。 在脱氧反应区下游的芳族生产区中,芳族化合物由芳族化合物与芳族化合物形成。

    CATALYST FOR PRODUCING MONOCYCLIC AROMATIC HYDROCARBONS, AND METHOD FOR PRODUCING MONOCYCLIC AROMATIC HYDROCARBONS
    74.
    发明申请
    CATALYST FOR PRODUCING MONOCYCLIC AROMATIC HYDROCARBONS, AND METHOD FOR PRODUCING MONOCYCLIC AROMATIC HYDROCARBONS 审中-公开
    用于生产单环芳香烃的催化剂,以及生产单环芳香烃的方法

    公开(公告)号:US20140364667A1

    公开(公告)日:2014-12-11

    申请号:US14467707

    申请日:2014-08-25

    Abstract: A catalyst for producing monocyclic aromatic hydrocarbons of 6 to 8 carbon number from a feedstock oil having a 10 volume % distillation temperature of at least 140° C. and an end point temperature of not more than 400° C., or a feedstock oil having a 10 volume % distillation temperature of at least 140° C. and a 90 volume % distillation temperature of not more than 360° C., wherein the catalyst contains a crystalline aluminosilicate, gallium and/or zinc, and phosphorus, and the amount of phosphorus supported on the crystalline aluminosilicate is within a range from 0.1 to 1.9% by mass based on the mass of the crystalline aluminosilicate; and a method for producing monocyclic aromatic hydrocarbons, the method involving bringing a feedstock oil having a 10 volume % distillation temperature of at least 140° C. and an end point temperature of not more than 400° C., or a feedstock oil having a 10 volume % distillation temperature of at least 140° C. and a 90 volume % distillation temperature of not more than 360° C., into contact with the above-mentioned catalyst for producing monocyclic aromatic hydrocarbons.

    Abstract translation: 一种催化剂,用于从具有10体积%蒸馏温度至少为140℃,终点温度不高于400℃的原料油生产6至8个碳原子的单环芳族烃,或具有 至少140℃的10体积%蒸馏温度和不高于360℃的90体积%蒸馏温度,其中所述催化剂含有结晶硅铝酸盐,镓和/或锌和磷,以及 在结晶硅铝酸盐上负载的磷的含量相对于结晶性铝硅酸盐的质量为0.1〜1.9质量% 和单环芳烃的制造方法,其特征在于,使具有10体积%馏出温度的原料油为至少140℃,终点温度为400℃以下的方法, 10体积%的蒸馏温度为至少140℃,90体积%蒸馏温度为不高于360℃,与上述用于制备单环芳烃的催化剂接触。

    Method of making a molecular sieve of MFS framework type with controllable average size
    76.
    发明授权
    Method of making a molecular sieve of MFS framework type with controllable average size 有权
    制作具有可控平均尺寸的MFS框架型分子筛的方法

    公开(公告)号:US08853117B2

    公开(公告)日:2014-10-07

    申请号:US13388331

    申请日:2010-08-18

    Abstract: A method of making a crystalline molecular sieve of MFS framework type, preferably ZSM-57, from a synthesis mixture comprising at least one source of tetravalent element (Y), at least one source of trivalent element (X), at least one source of alkali metal hydroxide (MOH), at least one structure-directing-agent (R) and water, said alkali metal (M) comprising potassium, and having the following mole composition (expressed in terms of oxide): YO2:(p)X2O3:(q)OH−:(r)R:(s)H2O, wherein (p) is in the range from 0.005 to 0.05, (q) is in the range from 0.01 to 3, (r) is in the range from 0.03 to 2 and (s) is in the range from 10 to 75 (based on total weight of said synthesis mixture); wherein the crystals of molecular sieve formed having an average diameter (D) of less than or equal to 1.5 micron and an average thickness (T) of less than or equal to 300 nanometers.

    Abstract translation: 从包含至少一种四价元素(Y)源,至少一种三价元素(X)源的合成混合物制备MFS骨架型结晶分子筛(优选ZSM-57)的方法,至少一种源 碱金属氢氧化物(MOH),至少一种结构导向剂(R)和水,所述碱金属(M)包含钾,并具有以下摩尔组成(以氧化物表示):YO 2:(p)X 2 O 3 :(q)OH - (r)R:(s)H 2 O,其中(p)在0.005至0.05的范围内,(q)在0.01至3的范围内,(r) 0.03至2和(s)在10至75(基于所述合成混合物的总重量)的范围内; 其中形成的平均直径(D)小于或等于1.5微米且平均厚度(T)小于或等于300纳米的分子筛晶体。

    Methods of reactivating an aromatization catalyst
    78.
    发明授权
    Methods of reactivating an aromatization catalyst 有权
    还原芳构化催化剂的方法

    公开(公告)号:US08664144B2

    公开(公告)日:2014-03-04

    申请号:US12617440

    申请日:2009-11-12

    Applicant: An-Hsiang Wu

    Inventor: An-Hsiang Wu

    Abstract: A method of reactivating a spent catalyst comprising a metal and a catalyst support, the method comprising redispersing the metal in the spent catalyst to produce a redispersed spent catalyst, contacting the redispersed spent catalyst with a reactivating composition to produce a redispersed, reactivated spent catalyst, and thermally treating the redispersed, reactivated spent catalyst to produce a reactivated catalyst. A method comprising employing a fresh aromatization catalyst in one or more reaction zones for a time period sufficient to produce a spent catalyst, reducing the amount of carbonaceous material associated with the spent catalyst to produce a decoked spent catalyst, contacting the decoked spent catalyst with a redispersing composition to produce a decoked redispersed spent, contacting the decoked redispersed spent catalyst with a reactivating composition to produce a decoked redispersed reactivated spent catalyst, and thermally treating the decoked, reactivated spent catalyst to produce a reactivated catalyst.

    Abstract translation: 一种重新激活包含金属和催化剂载体的废催化剂的方法,所述方法包括将废金属重新分散在废催化剂中以产生再分散的废催化剂,使再分散的废催化剂与再活化组合物接触以产生再分散的再活化的废催化剂, 并对再分散的再活化的废催化剂进行热处理以产生再活化的催化剂。 一种方法,包括在一个或多个反应区中使用新鲜的芳构化催化剂足以产生废催化剂的时间段,减少与废催化剂相关的碳质材料的量以产生经过处理的废催化剂,将经过处理的废催化剂与 再分散组合物以产生经过重新分配的再分散的废料,使经过重新分离的废催化剂与再活化组合物接触,以产生经过重新分离的再分解的再生废催化剂,并热处理所述经切割的再活化的废催化剂以产生再活化的催化剂。

    Method for producing ultra-clean gasoline
    80.
    发明授权
    Method for producing ultra-clean gasoline 有权
    超清洁汽油的生产方法

    公开(公告)号:US08597494B2

    公开(公告)日:2013-12-03

    申请号:US12726151

    申请日:2010-03-17

    Abstract: The present invention relates to a method for producing ultra-clean gasoline. The invention provides a method of hydro-upgrading inferior gasoline through deep desulfurization and octane number recovery, which comprises the following steps: cutting inferior full-range gasoline into the light and heavy fraction gasolines; contacting the light fraction gasoline successively with a catalyst for selective diene removal and a catalyst for desulfurization and hydrocarbon aromatization/single-branched-chain hydroisomerization; contacting the heavy fraction gasoline with a catalyst for selective hydrodesulfurization, and contacting the reaction effluent with a catalyst for supplemental desulfurization and hydrocarbon multi-branched-chain hydroisomerization; and blending the treated light and heavy fraction gasolines to obtain the ultra-clean gasoline product. The method of the invention is suitable for hydro-upgrading inferior gasoline, especially for hydro-upgrading inferior FCC gasoline with ultra-high sulfur content and high olefin content to obtain excellent hydro-upgrading effects.

    Abstract translation: 本发明涉及一种生产超清洁汽油的方法。 本发明提供了一种通过深度脱硫和辛烷值回收来升级劣质汽油的方法,包括以下步骤:将低级全程汽油切割成轻重汽油; 将轻馏分汽油依次与用于选择性二烯除去的催化剂和用于脱硫和烃芳构化/单支链加氢异构化的催化剂接触; 使重馏分汽油与催化剂接触以进行选择性加氢脱硫,并将反应流出物与用于补充脱硫和烃多支链加氢异构化的催化剂接触; 并混合经处理的轻质和重馏分汽油,得到超清洁汽油产品。 本发明的方法适用于升级劣质汽油,特别是用于加氢改造具有超高硫含量和高烯烃含量的劣质FCC汽油,以获得优异的水力升级效果。

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