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    Hydrocarbon processing using fullerene catalysts
    71.
    发明授权
    Hydrocarbon processing using fullerene catalysts 失效
    使用富勒烯催化剂的烃加工

    公开(公告)号：US5420371A

    公开(公告)日：1995-05-30

    申请号：US210884

    申请日：1994-03-18

    Applicant: Ripudaman Malhotra ,  Doris S. Tse ,  Donald F. McMillen

    Inventor： Ripudaman Malhotra ,  Doris S. Tse ,  Donald F. McMillen

    IPC: B01J21/18 ,  C07C4/00 ,  C07C5/11 ,  C07C5/32 ,  C07C5/367 ,  C10G45/60 ,  C10G45/68 ,  C10G47/02 ,  C10G49/02 ,  C07C5/03 ,  C07C5/10

    CPC classification number: C07C5/11 ,  C07C4/00 ,  C07C5/321 ,  C07C5/367 ,  C07C2103/26 ,  C07C2521/18

    Abstract: A process is described for carrying out the dehydrogenation or hydrogenation, including hydrogenolysis, of a hydrocarbon in the presence of one or more soluble fullerene catalysts which have been dissolved in the hydrocarbon (when the hydrocarbon is a liquid capable of dissolving the fullerene catalyst) or dissolved in a solvent which is also a solvent for the hydrocarbon (when the hydrocarbon either is not a liquid or is not a liquid which is a solvent for the fullerene catalyst). The use of a liquid catalyst, i.e., a dissolved fullerene catalyst, inhibits coking reactions to thereby inhibit formation of coke on a solid catalyst or catalyst support by elimination of nucleation points or growth regions for such coke formation.

    Abstract translation: 描述了一种在已经溶解在烃中的一种或多种可溶性富勒烯催化剂存在下（当烃是能够溶解富勒烯催化剂的液体）的情况下进行烃的脱氢或氢化（包括氢解）的方法或 溶解在溶剂中，该溶剂也是烃的溶剂（当烃不是液体或不是作为富勒烯催化剂的溶剂的液体时）。 使用液体催化剂，即溶解的富勒烯催化剂，抑制焦化反应，从而通过消除这种焦炭形成的成核点或生长区域来抑制在固体催化剂或催化剂载体上形成焦炭。

    Production of gem-disubstituted cyclohexadienones
    79.
    发明授权
    Production of gem-disubstituted cyclohexadienones 失效
    偕二取代的环己二烯酮的生产

    公开(公告)号：US4804774A

    公开(公告)日：1989-02-14

    申请号：US177151

    申请日：1988-04-04

    Applicant: G. Patrick Stahly

    Inventor： G. Patrick Stahly

    IPC: C07C39/24 ,  C07C39/38 ,  C07C45/62 ,  C07C45/67 ,  C07C49/497 ,  C07C49/713 ,  C07C49/747 ,  C07F7/08 ,  C07F7/18 ,  C07F7/10

    CPC classification number: C07F7/188 ,  C07C39/24 ,  C07C39/38 ,  C07C45/62 ,  C07C45/673 ,  C07C49/497 ,  C07C49/713 ,  C07C49/747 ,  C07F7/0818 ,  C07C2103/26

    Abstract: Quinones may be perfluoroalkylated by means of perfluoroalkyltrihydrocarbyl silane using trialkylphosphites or hexahydrocarbylphosphorous triamides, or both as catalysts. The reaction --which is conducted under essentially anhydrous conditions, preferably in a suitable liquid phase reaction medium, most preferably a dipolar aprotic solvent--results in the formation of gem-disubstituted cyclohexadienones in which the gem substituents are a perfluoroalkyl group and a trihydrocarbylsiloxy group. These gem-disubstituted compounds in turn can be readily converted to perfluoroalkyl substituted aromatics, thus circumventing the traditional need for photochlorination followed by halogen exchange using hydrogen fluoride as a means of preparing perfluoroalkyl aromatic compounds.

    Abstract translation: 醌类可以使用三烷基亚磷酸酯或六烃基磷酸三酰胺或全部作为催化剂通过全氟烷基三烃基硅烷全氟烷基化。 在基本上无水条件下，优选在合适的液相反应介质，最优选偶极非质子溶剂中进行的反应导致形成偕二取代的环己二烯酮，其中偕基取代基是全氟烷基和三烃基甲硅烷氧基。 甲基二取代的化合物又可以容易地转化为全氟烷基取代的芳族化合物，从而避免了光氯化的传统需要，随后使用氟化氢进行卤素交换作为制备全氟烷基芳族化合物的手段。

    [3,4-dichloro-6,7,8,8a,9,10-hexahydro-6-oxo-8a-substituted-2-phenanthreny l)oxy]-alkanoic acids and -ethanimidamides
    80.
    发明授权
    [3,4-dichloro-6,7,8,8a,9,10-hexahydro-6-oxo-8a-substituted-2-phenanthreny l)oxy]-alkanoic acids and -ethanimidamides 失效
    [3,4-二氯-6,7,8,8a，9,10-六氢-6-氧代-8a-取代-2-菲基]氧基] - 烷酸和 - 乙酰胺

    公开(公告)号：US4777281A

    公开(公告)日：1988-10-11

    申请号：US835599

    申请日：1986-03-03

    Applicant: Otto W. Woltersdorf, Jr. ,  Edward J. Cragoe, Jr.

    Inventor： Otto W. Woltersdorf, Jr. ,  Edward J. Cragoe, Jr.

    IPC: C07C59/90 ,  C07C69/76

    CPC classification number: C07C59/90 ,  C07C2103/26

    Abstract: The invention relates to novel [(3,4-dichloro-6,7,8,8a,9,10-hexahydro-6-oxo-8a-substituted-2-phenanthrenyl)ox yl]-alkanoic acids and -ethanimidamides and their salts. The compounds are useful for the treatment and prevention of injury to the brain and of edema due to head trauma, stroke (particularly ischemic), arrested breathing, cardiac arrest, Reye's syndrome, cerebral thrombosis, cerebral embolism, cerebral hemorrhage, cerebral tumors, encephalomyelitis, spinal cord injury, hydrocephalus, post-operative brain injury trauma, edema due to cerebral infections and various brain concussions.

    Abstract translation: 本发明涉及新的[（3,4-二氯-6,7,8,8a，9,10-六氢-6-氧代-8a-取代-2-菲基）羰基] - 烷酸和 - 乙酰亚胺酰胺和 他们的盐 该化合物可用于治疗和预防脑部损伤以及头部创伤，中风（特别是缺血性），呼吸暂停，心跳骤停，雷叶综合征，脑血栓形成，脑栓塞，脑出血，脑肿瘤，脑脊髓炎 ，脊髓损伤，脑积水，术后脑损伤创伤，由于脑部感染引起的水肿和各种脑震荡。

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