公开(公告)号：US08546629B2

公开(公告)日：2013-10-01

申请号：US13242833

申请日：2011-09-23

Applicant: Andrea G. Bozzano ,  Matthew James Griffiths ,  Amarendra Anumakonda

Inventor： Andrea G. Bozzano ,  Matthew James Griffiths ,  Amarendra Anumakonda

IPC: C07C2/64 ,  C07C5/22

CPC classification number: C07C2/66 ,  C01B3/26 ,  C10G3/00 ,  C10G3/50 ,  C10G9/00 ,  C10G29/205 ,  C10G45/32 ,  C10G57/005 ,  C10G69/00 ,  C10G69/123 ,  C10G69/126 ,  C10G69/14 ,  C10G2300/1014 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/08 ,  Y02E50/13 ,  Y02P30/20 ,  C07C15/107

Abstract: Embodiments of methods for co-production of linear alkylbenzene and biofuel from a natural oil are provided. A method comprises the step of deoxygenating the natural oils to form a stream comprising paraffins. A first portion of the paraffins are dehydrogenated to provide mono-olefins. Then, benzene is alkylated with the mono-olefins under alkylation conditions to provide an alkylation effluent comprising alkylbenzenes and benzene. Thereafter, the alkylbenzenes are isolated to provide the alkylbenzene product. A second portion of the paraffins is processed to form biofuel.

Abstract translation: 提供了从天然油共生产直链烷基苯和生物燃料的方法的实施方案。 一种方法包括使天然油脱氧以形成包含石蜡的物流的步骤。 将第一部分链烷烃脱氢以提供单烯烃。 然后，在烷基化条件下用单烯烃烷基化苯以提供包含烷基苯和苯的烷基化流出物。 此后，分离烷基苯以提供烷基苯产物。 处理第二部分石蜡以形成生物燃料。

公开(公告)号：US20130253239A1

公开(公告)日：2013-09-26

申请号：US13428559

申请日：2012-03-23

Applicant: Andrea G. Bozzano ,  Jeffery C. Bricker ,  Bryan K. Glover

Inventor： Andrea G. Bozzano ,  Jeffery C. Bricker ,  Bryan K. Glover

IPC: C07C7/00 ,  C07C7/10

CPC classification number: C07C7/167 ,  C07C2/06 ,  C07C2/64 ,  C07C5/327 ,  C07C7/163 ,  C10G9/00 ,  C10G29/205 ,  C10G45/32 ,  C10G50/00 ,  C10G57/005 ,  C10G57/02 ,  C10G69/00 ,  C10G2300/1011 ,  C10G2300/1022 ,  C10G2300/4081 ,  C10G2400/22 ,  C10G2400/30 ,  C07C11/02 ,  C07C15/107

Abstract: A process for producing heavy alkyl aromatics is presented. The process utilizes low molecular weight hydrocarbons for generating larger alkyl groups. The hydrocarbons can be generated from a variety of sources including Fischer-Tropsch liquids. The process includes oligomerization of low molecular weight olefins to larger olefins. The larger olefins are passed to an alkylation reactor to alkylate aromatic compounds.

Abstract translation: 提出了一种生产重质烷基芳烃的方法。 该方法利用低分子量烃来产生较大的烷基。 烃可以从各种来源产生，包括费 - 托液体。 该方法包括将低分子量烯烃低聚成较大的烯烃。 较大的烯烃通入烷基化反应器以烷基化芳族化合物。

公开(公告)号：US08518351B2

公开(公告)日：2013-08-27

申请号：US13076631

申请日：2011-03-31

Applicant: Andrew P. Wieber ,  Paul R. Zimmerman

Inventor： Andrew P. Wieber ,  Paul R. Zimmerman

IPC: B01J8/04 ,  B01J8/00 ,  B01J19/00 ,  C07C1/00 ,  C07C2/00 ,  C07C4/00 ,  C07C5/00 ,  C07C6/00 ,  C10G69/00 ,  C10G47/00

CPC classification number: B01D3/009 ,  B01J8/00 ,  C10G7/08 ,  C10G45/02 ,  C10G45/32 ,  C10G45/44 ,  C10G47/00 ,  C10G47/04 ,  C10G47/14 ,  C10G47/16 ,  C10G65/12 ,  C10G69/02 ,  C10G2400/04 ,  C10G2400/30

Abstract: An apparatus is disclosed for hydrocracking hydrocarbon feed in a hydrocracking unit and hydrotreating a diesel product from the hydrocracking unit in a hydrotreating unit. The hydrocracking unit and the hydrotreating unit shares the same recycle gas compressor. A warm separator separates recycle gas and hydrocarbons from diesel in the hydrotreating effluent, so fraction of the diesel is relatively simple. The warm separator also keeps the diesel product separate from the more sulfurous diesel in the hydrocracking effluent, and still retains heat needed for fractionation of lighter components from the low sulfur diesel product.

Abstract translation: 公开了一种用于在加氢裂化装置中加氢裂化烃进料并在加氢处理装置中从加氢裂化装置加氢处理柴油产品的装置。 加氢裂化装置和加氢处理装置共享相同的循环气体压缩机。 热分离器在加氢处理流出物中将循环气体和碳氢化合物与柴油分离，因此柴油馏分比较简单。 暖型分离器还使柴油机与加氢裂化废液中的更多的亚硫酸柴油分离，并且仍然保留了从低硫柴油产品中分馏较轻组分所需的热量。

公开(公告)号：US20130087481A1

公开(公告)日：2013-04-11

申请号：US13640856

申请日：2011-03-22

Applicant: Jean-Philippe Heraud ,  Frédéric Morel ,  Alain Quignard

Inventor： Jean-Philippe Heraud ,  Frédéric Morel ,  Alain Quignard

IPC: C10G65/12 ,  C10G47/00 ,  C10G45/32 ,  C10G45/02 ,  C10G45/44 ,  C10G65/10 ,  C10G65/04

CPC classification number: C10G65/12 ,  B01J23/883 ,  C10G45/02 ,  C10G45/32 ,  C10G45/44 ,  C10G47/00 ,  C10G49/12 ,  C10G65/04 ,  C10G65/10 ,  C10G67/0454 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/205 ,  C10G2300/206 ,  C10G2300/301 ,  C10G2300/44 ,  C10G2300/701 ,  C10G2300/805 ,  C22B7/009 ,  Y02P10/214

Abstract: A process for the hydroconversion of heavy oil feedstocks comprises a step for hydroconversion of the feedstock in at least one reactor containing a catalyst in slurry mode used to recover metals from the residual unconverted fraction, especially those used as catalysts. The process comprises a hydroconversion step, a gas/liquid separation step, a liquid/liquid extraction step, a grinding step, a leaching step, a combustion step, a metals extraction step and a step for the preparation of catalytic solutions which are recycled to the hydroconversion step.

Abstract translation: 用于加氢转化重油原料的方法包括在至少一个反应器中加氢转化原料的步骤，所述反应器含有浆料模式的催化剂，用于从残余的未转化馏分，特别是用作催化剂的馏分中回收金属。 该方法包括加氢转化步骤，气/液分离步骤，液/液萃取步骤，研磨步骤，浸出步骤，燃烧步骤，金属萃取步骤和用于制备催化溶液的步骤，其被再循环至 加氢转化步骤。

公开(公告)号：US20130079573A1

公开(公告)日：2013-03-28

申请号：US13242833

申请日：2011-09-23

Applicant: Andrea G. Bozzano ,  Matthew James Griffiths ,  Amarendra Anumakonda

Inventor： Andrea G. Bozzano ,  Matthew James Griffiths ,  Amarendra Anumakonda

IPC: C07C1/207

CPC classification number: C07C2/66 ,  C01B3/26 ,  C10G3/00 ,  C10G3/50 ,  C10G9/00 ,  C10G29/205 ,  C10G45/32 ,  C10G57/005 ,  C10G69/00 ,  C10G69/123 ,  C10G69/126 ,  C10G69/14 ,  C10G2300/1014 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/08 ,  Y02E50/13 ,  Y02P30/20 ,  C07C15/107

Abstract: Embodiments of methods for co-production of linear alkylbenzene and biofuel from a natural oil are provided. A method comprises the step of deoxygenating the natural oils to form a stream comprising paraffins. A first portion of the paraffins are dehydrogenated to provide mono-olefins. Then, benzene is alkylated with the mono-olefins under alkylation conditions to provide an alkylation effluent comprising alkylbenzenes and benzene. Thereafter, the alkylbenzenes are isolated to provide the alkylbenzene product. A second portion of the paraffins is processed to form biofuel.

Abstract translation: 提供了从天然油共生产直链烷基苯和生物燃料的方法的实施方案。 一种方法包括使天然油脱氧以形成包含石蜡的流的步骤。 将第一部分链烷烃脱氢以提供单烯烃。 然后，在烷基化条件下用单烯烃烷基化苯以提供包含烷基苯和苯的烷基化流出物。 此后，分离烷基苯以提供烷基苯产物。 处理第二部分石蜡以形成生物燃料。

公开(公告)号：US08323590B2

公开(公告)日：2012-12-04

申请号：US12917821

申请日：2010-11-02

Applicant: David A. Wegerer ,  Kurt M. Vanden Bussche

Inventor： David A. Wegerer ,  Kurt M. Vanden Bussche

IPC: B01J8/04 ,  B01J10/00 ,  C07C5/03

CPC classification number: C10G45/32 ,  C01B3/16 ,  C10G2300/1092 ,  C10G2300/207 ,  C10G2400/20 ,  C10K1/08 ,  C10K3/04 ,  Y02P30/40

Abstract: A process and apparatus are presented for the removal of carbon monoxide from ethylene streams. The removal of carbon monoxide before selective hydrogenation protects the catalyst in the selective hydrogenation reactor. Carbon monoxide levels are controlled with the water gas shift process to convert the carbon monoxide to carbon dioxide, with the carbon dioxide removed in an acid gas removal process.

公开(公告)号：US20120203042A1

公开(公告)日：2012-08-09

申请号：US13394559

申请日：2010-09-09

Applicant: George W. Huber ,  Anne Mae Gaffney ,  Jungho Jae ,  Yu-Ting Cheng

Inventor： George W. Huber ,  Anne Mae Gaffney ,  Jungho Jae ,  Yu-Ting Cheng

IPC: C07C1/20 ,  B82Y5/00

CPC classification number: C10G3/49 ,  B01J29/40 ,  B01J29/405 ,  B01J29/44 ,  B01J29/46 ,  B01J29/48 ,  B01J29/87 ,  C07C45/49 ,  C10B49/22 ,  C10B53/02 ,  C10B57/06 ,  C10G1/002 ,  C10G1/02 ,  C10G1/10 ,  C10G3/00 ,  C10G11/18 ,  C10G45/32 ,  C10G50/00 ,  C10G2300/1003 ,  C10G2300/1014 ,  C10G2300/4018 ,  C10G2300/4081 ,  C10G2300/70 ,  C10G2400/20 ,  C10G2400/30 ,  Y02E50/14 ,  Y02P20/52 ,  Y02P30/20 ,  Y02P30/42

Abstract: This invention relates to compositions and methods for fluid hydrocarbon product, and more specifically, to compositions and methods for fluid hydrocarbon product via catalytic pyrolysis. Some embodiments relate to methods for the production of specific aromatic products (e.g., benzene, toluene, naphthalene, xylene, etc.) via catalytic pyrolysis. Some such methods may involve the use of a composition comprising a mixture of a solid hydrocarbonaceous material and a heterogeneous pyrolytic catalyst component. In some embodiments, an olefin compound may be co-fed to the reactor and/or separated from a product stream and recycled to the reactor to improve yield and/or selectivity of certain products. The methods described herein may also involve the use of specialized catalysts. For example, in some cases, zeolite catalysts may be used. In some instances, the catalysts are characterized by particle sizes in certain identified ranges that can lead to improve yield and/or selectivity of certain products.

Abstract translation: 本发明涉及流体烃产物的组合物和方法，更具体地说，涉及通过催化裂解的流化烃产物的组合物和方法。 一些实施方案涉及通过催化热解生产特定芳族产物（例如苯，甲苯，萘，二甲苯等）的方法。 一些这样的方法可以涉及使用包含固体烃类材料和非均相热解催化剂组分的混合物的组合物。 在一些实施方案中，烯烃化合物可以共同进料至反应器和/或从产物流中分离并再循环至反应器以提高某些产物的产率和/或选择性。 本文所述的方法还可以涉及使用专门的催化剂。 例如，在一些情况下，可以使用沸石催化剂。 在一些情况下，催化剂的特征在于可以导致某些产物的产率和/或选择性的某些确定范围内的粒度。

公开(公告)号：US20110262308A1

公开(公告)日：2011-10-27

申请号：US13178729

申请日：2011-07-08

Applicant: Sven Ivar Hommeltoft ,  Howard S. Lacheen

Inventor： Sven Ivar Hommeltoft ,  Howard S. Lacheen

IPC: G05B99/00

CPC classification number: C10G29/205 ,  C10G45/32 ,  C10G2300/1081 ,  C10G2300/1088 ,  C10G2300/1096 ,  C10G2300/201 ,  C10G2300/305 ,  C10G2300/4025 ,  C10G2300/80 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10G2400/10

Abstract: An apparatus comprising: a) an alkylation reactor holding an ionic liquid catalyst and a reactant mixture, b) a means for measuring levels of a halide in an effluent from the alkylation reactor, and c) a control system that receives a signal in response to the measuring and communicates changes in an operating condition that influences the yield of products from the reactant mixture. The control system is responsive to deviations outside a predetermined range of halide level that has been selected to obtain a ratio of a yield of an alkylate gasoline and a yield of a middle distillate from 0.31 to 4.0 in the product from the alkylation reactor.

Abstract translation: 一种装置，包括：a）保持离子液体催化剂和反应物混合物的烷基化反应器，b）用于测量来自烷基化反应器的流出物中的卤化物的水平的装置，以及c）控制系统，其响应于 在影响反应物混合物的产物产量的操作条件下测量和通信变化。 控制系统响应于在烷基化反应器的产物中已经选择以获得烷基化汽油的产率与中间馏分的产率为0.31至4.0的预定卤化物范围之外的偏差。

公开(公告)号：US07947166B2

公开(公告)日：2011-05-24

申请号：US12047631

申请日：2008-03-13

Applicant: Florent Picard ,  Quentin Debuisschert ,  Annick Pucci

Inventor： Florent Picard ,  Quentin Debuisschert ,  Annick Pucci

IPC: C10G45/00

CPC classification number: C10G69/123 ,  C10G29/205 ,  C10G45/32 ,  C10G45/40 ,  C10G69/14 ,  C10G2400/02

Abstract: The present invention relates to a method for treating a feed corresponding to a pyrolysis gasoline, comprising: a) at least one stage of selective hydrogenation of the feed, referred to as HD1, b) fractionating in one or more distillation columns the effluent from stage a) in order to produce at least one light C5 cut, an intermediate C6 or C6-C7 or C6-C8 cut intended for aromatics production, a heavy C7+ or C8+ or C9+ cut intended for gasoline production, c) at least one stage of hydrodesulfurization and deep hydrogenation of the intermediate cut, referred to as HD2, d) at least one stage of alkylation of the heavy C7+, C8+ or C9+ cut consisting of a treatment on an acid catalyst allowing weighting of the sulfur compounds, e) at least one stage of distillation of the effluent from stage d), intended to produce a light fraction that can be directly used as a low-sulfur gasoline base, and a heavy C11+ or C12+ fraction rich in sulfur compounds, used as middle distillate or fuel oil.

Abstract translation: 本发明涉及用于处理对应于热解汽油的进料的方法，其包括：a）进料的至少一个阶段选择性氢化，称为HD1，b）在一个或多个蒸馏塔中分馏出来自阶段 a）为了产生至少一个轻C5切割，用于芳烃生产的中间体C6或C6-C7或C6-C8切割，用于汽油生产的重C 7 +或C 8 +或C 9 +切割，c）至少一个阶段 中间切片的加氢脱硫和深氢化，称为HD2，d）重酸C7 +，C8 +或C9 +切割的至少一个阶段的烷基化，由在酸催化剂上进行处理，允许加权硫化合物，e）至少 用于产生可以直接用作低硫汽油基质的轻馏分的一级阶段d）中的流出物的蒸馏，以及用作中间馏分或燃料油的富含硫化合物的重C11 +或C12 +馏分 。

公开(公告)号：US07517824B2

公开(公告)日：2009-04-14

申请号：US11295191

申请日：2005-12-06

Applicant: Stephen H. Brown ,  Khavinet Lourvanij

Inventor： Stephen H. Brown ,  Khavinet Lourvanij

IPC: B01J38/06 ,  B01J29/06

CPC classification number: B01J29/90 ,  B01J29/70 ,  B01J38/06 ,  B01J38/12 ,  C10G25/03 ,  C10G45/32

Abstract: The present invention relates to a process for stripping hydrocarbons from a catalyst, comprising the step of contacting the catalyst with steam at stripping conditions, wherein the catalyst comprises a molecular sieve having a structure type of MWW, the steam comprises at least 90 wt. % vapor phase H2O, the stripping conditions comprise a temperature range from about 100° C. to about 250° C., a pressure less than 310 kpa-a, and a WHSV range from about 0.01 to about 100 hr−1.

Abstract translation: 本发明涉及一种从催化剂中汽提烃的方法，包括在汽提条件下使催化剂与蒸汽接触的步骤，其中催化剂包含结构类型为MWW的分子筛，该蒸汽包含至少90wt。 ％汽相H 2 O，汽提条件包括约100℃至约250℃的温度范围，小于310kpa-a的压力和约0.01至约100小时-1的WHSV范围。