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公开(公告)号：US11286217B2
公开(公告)日：2022-03-29
申请号：US16942113
申请日：2020-07-29
申请人： UOP LLC
摘要： A dehydrogenation process and apparatus contact a paraffinic stream with dehydrogenation catalyst to product olefinic product gases. The olefinic product gases are separated from spent dehydrogenation catalyst and contained in a confined space that has a smaller volume than the reactor particularly at the same elevation. The containment of the olefinic product gases facilitates quenching the olefinic product gases to terminate reaction and improve selectivity to propylene.
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公开(公告)号：US11046625B1
公开(公告)日：2021-06-29
申请号：US16888066
申请日：2020-05-29
申请人： Bio2Electric, LLC
摘要： A system for oxidative conversion of a mixed hydrocarbon feed stream to a product stream containing at least one olefin is provided. The system includes a plurality of reactors each capable of oxidatively dehydrogenating at least a portion of a hydrocarbon in the mixed hydrocarbon feed, and each reactor able to operate at different set of reaction conditions from other reactors in the plurality of reactors. All of the reactors use the same oxygen transfer agent to produce at least one olefin. In some embodiments, at least one reactor is optimized to oxidatively couple methane to produce ethylene, while other reactors are optimized to oxidatively dehydrogenate ethane to ethylene or to oxidatively dehydrogenate propane to ethylene and/or propylene. All of the reactors feed into a single regeneration unit for the oxygen transfer agent. A method of oxidatively converting the mixed hydrocarbon feed to an olefin is also provided.
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公开(公告)号：US10730821B2
公开(公告)日：2020-08-04
申请号：US15778182
申请日：2016-09-09
申请人： Retrotope, Inc.
IPC分类号： C07C67/30 , C07C11/12 , C07C51/347 , C07C5/00 , C07C407/00 , C07C29/00 , C07C409/16 , C07B59/00 , B01J31/22
摘要： Methods for preparing isotopically modified 1,4-diene systems from non-isotopically modified 1,4-dienes involve selective oxidation of one or more bis-allylic position(s), or the preparation of isotopically modified 1,4-diene systems via trapping pi-allylic complexes with a source of deuterium or tritium. Such methods are useful for preparing isotopically modified polyunsaturated lipid including polyunsaturated fatty acids and polyunsaturated fatty acid derivatives.
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4.发明授权公开(公告)号：US09643167B2
公开(公告)日：2017-05-09
申请号：US14628179
申请日：2015-02-20
发明人： Kenji Akagishi , Hiroyuki Yano , Ryusuke Miyazaki
IPC分类号： B01J29/06 , C07C1/20 , C07C2/00 , C07C4/00 , C07C5/00 , B01J29/70 , B01J21/08 , B01J29/40 , B01J35/02 , B01J37/00 , C07C6/04
CPC分类号： B01J29/70 , B01J21/08 , B01J29/06 , B01J29/40 , B01J35/023 , B01J37/0045 , B01J2229/42 , C07C2/00 , C07C6/04 , C07C2521/08 , C07C2529/40 , C07C2529/70 , Y02P20/52 , C07C11/06
摘要： The present invention provides a zeolite-containing catalyst having excellent shape, fluidity and mechanical strength as a catalyst for a fluidized bed reaction. The present invention provides a zeolite-containing catalyst which is a particulate catalyst containing zeolite and silica, wherein the catalyst has an average particle diameter of 20 to 300 μm and the ratio of the void area in the cross-section of the particle is 30% or less relative to the cross-section area of the particle.
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5.发明授权公开(公告)号：US09181161B2
公开(公告)日：2015-11-10
申请号：US14396635
申请日：2013-04-05
申请人： MERCK PATENT GmbH
发明人： Thomas Rudolph , Tatjana Best
IPC分类号： A61K8/00 , A61K31/045 , C07C5/00 , C07C43/196 , A01N31/04 , A01N31/06 , A01N37/02 , A01N41/04 , A61K8/34 , A61K8/46 , A61Q5/00 , A61Q15/00 , A61Q17/00 , A61K31/047 , A61K31/08 , A61K31/185 , C07C29/20 , C07C35/21 , C07C41/20 , A61Q11/00
CPC分类号： C07C43/196 , A01N31/04 , A01N31/06 , A01N37/02 , A01N41/04 , A61K8/345 , A61K8/466 , A61K31/047 , A61K31/08 , A61K31/185 , A61K2800/10 , A61K2800/40 , A61Q5/006 , A61Q11/00 , A61Q15/00 , A61Q17/005 , C07C29/20 , C07C35/21 , C07C41/20
摘要： The present invention relates to the use of at least one dicyclohexylmethanol derivative of the formula (I) as antimicrobial active compound or as anti-acne, antidandruff, deodorant or antiperspirant active compound, to preparations comprising these compounds, and to specific dicyclohexylmethanol derivatives and to a process for the preparation thereof.
摘要翻译： 本发明涉及至少一种式（I）的二环己基甲醇衍生物作为抗微生物活性化合物或抗痤疮，去头皮屑，除臭或止汗活性化合物用于包含这些化合物的制剂，以及特定的二环己基甲醇衍生物，以及 其制备方法。
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公开(公告)号：US08912346B2
公开(公告)日：2014-12-16
申请号：US13263353
申请日：2009-05-14
CPC分类号： C07F9/65522
摘要： A phosphine ligand suitable for use in telomerizing butadiene comprises two phenyl groups and a xanthene moiety.
摘要翻译： 适用于调聚丁二烯的膦配体包括两个苯基和呫吨部分。
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7.发明授权公开(公告)号：US08859834B2
公开(公告)日：2014-10-14
申请号：US13808010
申请日：2011-06-09
申请人： Christian Boeing , Markus Winterberg , Tobias Laiblin , Gunnar Schilling , Wolfgang Garstka , Burkard Kreidler , Dietrich Maschmeyer , Reiner Bukohl
发明人： Christian Boeing , Markus Winterberg , Tobias Laiblin , Gunnar Schilling , Wolfgang Garstka , Burkard Kreidler , Dietrich Maschmeyer , Reiner Bukohl
摘要： The present invention describes a process for the parallel selective hydrogenation of branched and unbranched multiply unsaturated C4-C6-hydrocarbons in olefin-containing hydrocarbon mixtures with minimization of hydrogenation and isomerization of the olefins present in the stream.
摘要翻译： 本发明描述了一种在含烯烃的烃混合物中并行选择性氢化支链和非支链的多不饱和C4-C6-烃的方法，其中存在于物流中的烯烃的氢化和异构化最小化。
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公开(公告)号：US08680353B2
公开(公告)日：2014-03-25
申请号：US13680910
申请日：2012-11-19
申请人： Sven Crone , Oliver Ryll , Till Blum , Alexander Weck , Rainer Papp , Roland Krokoszinski , Heinrich-Josef Blankertz
发明人： Sven Crone , Oliver Ryll , Till Blum , Alexander Weck , Rainer Papp , Roland Krokoszinski , Heinrich-Josef Blankertz
CPC分类号： C07C2/06 , C07C2/10 , C07C2523/755 , C07C11/02
摘要： A process for preparing oligomers by continuous oligomerization of butenes is described, wherein a) a feed stream 1) comprising 1-butene and 2-butene in a total concentration of from 10 to 70% by weight and from 10 to 60% by weight of isobutane is reacted until more than 60% by weight of the 1-butene comprised in the feed stream 1 but less than 50% by weight of the 2-butene comprised in feed stream 1 have been converted into oligomers. b) The oligomers obtained in a) are separated off and optionally passed to a further work-up and the remaining residual stream is fed to work-up by distillation. c) Isobutane is separated off by distillation from the residual stream, and d) the isobutane-depleted stream obtained after the work-up by distillation c) is reacted to form oligomers.
摘要翻译： 描述了通过丁烯的连续低聚制备低聚物的方法，其中a）包含总重量为10-70重量％和10-60重量％的1-丁烯和2-丁烯的进料流1） 异丁烷反应直到进料流1中包含的重量百分比大于60重量％的1-丁烯，但是小于50重量％的进料流1中包含的2-丁烯已经被转化为低聚物。 b）将a）中得到的低聚物分离出来并任选地进一步处理，剩余的剩余物流通过蒸馏进料后处理。 c）通过蒸馏从残余物流分离异丁烷，和d）通过蒸馏处理后获得的异丁烷贫化物流c）反应形成低聚物。
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公开(公告)号：US08680351B2
公开(公告)日：2014-03-25
申请号：US13416604
申请日：2012-03-09
CPC分类号： C10G35/06 , C10G35/04 , C10G35/065 , C10G35/085 , C10G59/06 , C10G2300/1044 , C10G2400/30
摘要： A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and passing each feedstream to separation reformers. The reformers are operated under different conditions to utilize the differences in the reaction properties of the different hydrocarbon components. The process utilizes a common catalyst, and common downstream processes for recovering the desired aromatic compounds generated.
摘要翻译： 提出了一种重整烃流的方法。 该方法包括将石脑油进料流分成至少两个进料流并将每个进料流通过分离重整器。 改性剂在不同条件下运行，以利用不同烃组分的反应性质的差异。 该方法利用普通的催化剂和用于回收生成的所需芳族化合物的常见的下游方法。
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公开(公告)号：US20140066676A1
公开(公告)日：2014-03-06
申请号：US13601281
申请日：2012-08-31
CPC分类号： B01J19/0006 , B01J19/24 , B01J2219/00166 , B01J2219/24 , C10G35/04 , C10G35/24 , C10G45/68 , C10G45/72 , G06F17/10 , G06F17/5009
摘要： Methods and systems for improved catalytic reforming are disclosed. A method of catalytic reforming includes feeding a feedstream comprising C6-convertibles to one or more reactors; contacting the feedstream with a reforming catalyst; selecting values for a LHSV, a H2/HC ratio, and a conversion of C6-convertibles from a deactivation kinetic model so as to maximize a net present amount of benzene produced over a run-length of the reforming catalyst; operating the one or more reactors at the selected LHSV, the selected H2/HC ratio, and the selected conversion of C6-convertibles; and recovering an effluent from the reactor, wherein the effluent comprises at least about 40 wt % benzene.
摘要翻译： 公开了用于改进催化重整的方法和系统。 一种催化重整的方法包括将包含C6-可转变物的进料流进料到一个或多个反应器; 使原料流与重整催化剂接触; 从失活动力学模型中选择LHSV值，H2 / HC比值和C6-可转化物的转化率，以便最大化在重整催化剂的游程长度上产生的苯的净存在量; 在所选择的LHSV，所选择的H 2 / HC比率和所选择的C6-可转换的转化物中操作所述一个或多个反应器; 以及从所述反应器回收流出物，其中所述流出物包含至少约40重量％的苯。
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