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公开(公告)号：US09957211B2
公开(公告)日：2018-05-01
申请号：US15308884
申请日：2015-05-07
CPC分类号： C07C41/06 , C07C7/005 , C07C7/04 , C07C7/13 , C07C7/163 , C07C7/167 , C07C43/046 , C07C11/08 , C07C11/09
摘要： The present invention provides, among other things, new processes for separating and purifying C4 fractions from a crude C4 stream. Compared to prior methods, the processes of the present invention simplify the C4 separation processes, afford more possible configurations for separation and purification, and are more cost effective. The processes and systems provided herein can be used as part of a cost-effective and efficient method for synthesizing methyl tertiary-butyl ether.
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公开(公告)号：US20170349506A1
公开(公告)日：2017-12-07
申请号：US15523910
申请日：2016-01-21
发明人： Akihiro KUWANA , Junichi KAWAKAMI , Shuji TSUNO
摘要： A propane production method includes a hydrogenation reaction step of hydrogenation-reacting crude propylene and hydrogen in a presence of a catalyst to obtain gaseous crude propane containing impurities; and an impurity removal step of removing the impurities contained in the gaseous crude propane obtained in the hydrogenation reaction step to obtain purified propane. The impurity removal step includes an adsorptive removal stage of adsorbing and removing water, ethane and propylene contained as impurities in the gaseous crude propane by adsorption treatment in which the gaseous crude propane is brought into contact with an adsorbent, and a separation removal stage of separating and removing hydrogen, oxygen, nitrogen and methane contained as impurities in the crude propane after the adsorption treatment by partial condensation or distillation of crude propane after the adsorption treatment in the adsorptive removal stage.
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公开(公告)号：US09834494B2
公开(公告)日：2017-12-05
申请号：US14499663
申请日：2014-09-29
申请人： UOP LLC
发明人： Charles P. Luebke , Bart Dziabala , Belma Demirel
CPC分类号： C07C5/05 , B01J8/0457 , B01J2219/00038 , B01J2219/0004 , B01J2219/00105 , C07C7/163 , C07C2521/04 , C07C2523/44 , C07C2523/755 , C07C11/02 , C07C15/00
摘要： Methods and apparatuses are provided for producing hydrocarbons. A method for producing hydrocarbons may include two or more reactors having a distributed aromatic rich feed and hydrogen system. Using this configuration, the aromatic rich feed and hydrogen streams are split equally to all reactors wherein each reactor contains a catalyst. The outlet from the last reactor may include a recycle that may be injected into the inlet of the first reactor.
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公开(公告)号：US09695096B2
公开(公告)日：2017-07-04
申请号：US13547164
申请日：2012-07-12
申请人： Yongqiang Xu , Gary G. Podrebarac
发明人： Yongqiang Xu , Gary G. Podrebarac
CPC分类号： C07C7/167 , C07C6/04 , C07C7/163 , Y02P20/127 , Y02P20/142 , C07C11/10 , C07C11/06
摘要： A process for the conversion of linear pentenes to propylene is disclosed. The process may include feeding hydrogen and a C5-olefin containing stream comprising linear pentenes, dienes, acetylenes, and cyclopentene to a catalytic distillation reactor system. Concurrently in the catalytic distillation reactor system, the acetylenes and dienes may be hydrogenated and the C5-olefin containing stream may be fractionated, thereby recovering an overheads fraction comprising the linear pentenes, a side draw fraction comprising the cyclopentene, and a bottoms fraction. In some embodiments, at least a portion of the overheads fraction may then be fed to a metathesis reactor for converting the linear pentenes to propylene.
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公开(公告)号：US09321711B2
公开(公告)日：2016-04-26
申请号：US14763471
申请日：2014-02-21
IPC分类号： C07C45/53 , C07C37/08 , C07C2/66 , B01J19/00 , C07C409/14 , B01J19/24 , B01D3/14 , C07C37/74 , C07C45/82
CPC分类号： C07C37/08 , B01D3/143 , B01J19/245 , B01J2219/00006 , B01J2219/24 , C07C5/03 , C07C7/163 , C07C37/74 , C07C45/53 , C07C45/82 , C07C407/00 , C07C409/14 , C07C2601/14 , C07C39/04 , C07C49/403 , C07C13/28
摘要： A system for producing high-purity phenol and/or cyclohexanone from cyclohexylbenzene oxidation includes a cyclohexylbenzene feed hydrogenation reactor, a bubble column oxidation reactor, a cyclohexylbenzene hydroperoxide concentrator, a cleavage reactor, and a separation and purification sub-system. The components and the integrated system are designed such that high-purity phenol and/or cyclohexanone can be produced at high energy efficiency.
摘要翻译： 用于从环己基苯氧化生产高纯度苯酚和/或环己酮的体系包括环己基苯进料氢化反应器，泡罩塔氧化反应器，环己基苯氢过氧化物浓缩器，裂解反应器和分离和纯化子系统。 这些组件和集成系统被设计成能够以高能量效率生产高纯度苯酚和/或环己酮。
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公开(公告)号：US20150353459A1
公开(公告)日：2015-12-10
申请号：US14763471
申请日：2014-02-21
CPC分类号： C07C37/08 , B01D3/143 , B01J19/245 , B01J2219/00006 , B01J2219/24 , C07C5/03 , C07C7/163 , C07C37/74 , C07C45/53 , C07C45/82 , C07C407/00 , C07C409/14 , C07C2601/14 , C07C39/04 , C07C49/403 , C07C13/28
摘要： A system for producing high-purity phenol and/or cyclohexanone from cyclohexylbenzene oxidation includes a cyclohexylbenzene feed hydrogenation reactor, a bubble column oxidation reactor, a cyclohexylbenzene hydroperoxide concentrator, a cleavage reactor, and a separation and purification sub-system. The components and the integrated system are designed such that high-purity phenol and/or cyclohexanone can be produced at high energy efficiency.
摘要翻译： 用于从环己基苯氧化生产高纯度苯酚和/或环己酮的体系包括环己基苯进料氢化反应器，泡罩塔氧化反应器，环己基苯氢过氧化物浓缩器，裂解反应器和分离和纯化子系统。 这些组件和集成系统被设计成能够以高能量效率生产高纯度苯酚和/或环己酮。
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公开(公告)号：US09169172B2
公开(公告)日：2015-10-27
申请号：US14394524
申请日：2013-04-10
IPC分类号： C07C45/53 , C07C37/08 , C07C2/66 , C07C5/05 , C07C2/74 , C07C5/03 , C07C407/00 , C07C7/163 , B01J23/44 , B01J23/46 , B01J23/75 , B01J23/755 , B01J35/00 , B01J35/08 , B01J37/00 , C07C409/14 , B01J21/04
CPC分类号： C07C5/05 , B01J21/04 , B01J23/44 , B01J23/462 , B01J23/75 , B01J23/755 , B01J35/008 , B01J35/08 , B01J37/0009 , C07C2/74 , C07C5/03 , C07C7/163 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/14 , C07C2521/04 , C07C2523/44 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C49/403 , C07C39/04
摘要： The present invention relates to hydrogenation processes including: contacting a first composition with hydrogen under hydrogenation conditions, in the presence of an eggshell hydrogenation catalyst, wherein the first composition has: (i) greater than about 50 wt % of cyclohexylbenzene, the wt % based upon the total weight of the first composition; and (ii) greater than about 0.3 wt % of cyclohexenylbenzene, the wt % based upon the total weight of the first composition; and thereby obtaining a second composition having less cyclohexenylbenzene than the first composition. Other hydrogenation processes are also described.
摘要翻译： 本发明涉及氢化方法，包括：在加氢条件下，在蛋壳氢化催化剂存在下使第一组合物与氢接触，其中第一组合物具有：（i）大于约50重量％的环己基苯，基于重量％ 基于第一组合物的总重量; 和（ii）大于约0.3重量％的环己烯基苯，所述wt％基于第一组合物的总重量; 从而获得比第一组合物少的环己烯基苯的第二组合物。 还描述了其它氢化方法。
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公开(公告)号：US20150284662A1
公开(公告)日：2015-10-08
申请号：US14741542
申请日：2015-06-17
申请人： UOP LLC
IPC分类号： C11D1/14
CPC分类号： C11D1/143 , C07C1/2078 , C07C1/213 , C07C1/22 , C07C2/66 , C07C5/2729 , C07C5/277 , C07C5/333 , C07C7/00 , C07C7/163 , C07C303/02 , C07C303/04 , C07C309/29 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/28 , C07C2523/75 , C07C2523/755 , C07C2523/883 , C10G3/44 , C10G3/45 , C10G3/46 , C10G3/48 , C10G3/50 , C10G9/00 , C10G29/205 , C10G45/32 , C10G57/005 , C10G69/123 , C10G69/14 , C10G2300/1014 , C10G2400/30 , C11D1/22 , C11D3/3418 , C11D11/04 , C07C309/31 , C07C9/00 , C07C11/02 , C07C15/107
摘要： A linear alkyl benzene product and production of linear alkylbenzene from a natural oil are provided. A method comprises the step of deoxygenating the natural oils to form a stream comprising paraffins. The paraffins are dehydrogenated to provide mono-olefins. Then, benzene is alkylated with the mono-olefins under alkylation conditions to provide an alkylation effluent comprising alkylbenzenes and benzene. Thereafter, the alkylbenzenes are isolated to provide the alkylbenzene product.
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公开(公告)号：US09079814B2
公开(公告)日：2015-07-14
申请号：US14297833
申请日：2014-06-06
申请人： UOP LLC
IPC分类号： C07C2/64 , C07C5/22 , C07C1/24 , C07C1/207 , C07C5/05 , C07C5/27 , C07C5/327 , C07C15/107 , C07C309/31
CPC分类号： C07C1/24 , C07C1/2076 , C07C1/2078 , C07C1/213 , C07C2/66 , C07C5/05 , C07C5/27 , C07C5/277 , C07C5/327 , C07C5/333 , C07C7/163 , C07C15/107 , C07C303/04 , C07C309/31 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/28 , C07C2523/755 , C07C2523/883 , C10G3/48 , C10G29/205 , C10G69/123 , C11D1/22 , C07C9/00 , C07C11/02
摘要： A linear alkyl benzene product and production of linear alkylbenzene from a natural oil are provided. A method comprises the step of deoxygenating the natural oils to form a stream comprising paraffins. The paraffins are dehydrogenated to provide mono-olefins. Then, benzene is alkylated with the mono-olefins under alkylation conditions to provide an alkylation effluent comprising alkylbenzenes and benzene. Thereafter, the alkylbenzenes are isolated to provide the alkylbenzene product.
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10.发明授权Process for producing styrene-, methylstyrene- and ethylbenzene-free C6-C9 aromatic hydrocarbon blends 有权生产苯乙烯，甲基苯乙烯和乙基苯的C6-C9芳族烃共混物的方法公开(公告)号：US09067846B2
公开(公告)日：2015-06-30
申请号：US13986804
申请日：2013-06-07
CPC分类号： C07C5/03 , C07C7/04 , C07C7/14891 , C07C7/163 , C07C41/06 , C07C15/02 , C07C15/067 , C07C43/164
摘要： Various substantially styrene-, methylstyrene- and ethylbenzene-free C6-C9 aromatic hydrocarbon blends are produced from a hydrocarbon feed stream containing C5-C9 aromatic hydrocarbons including styrene, methylstyrene and sulphur compounds by first separating the stream into a distillate containing C5-C7 hydrocarbons, and a bottoms fraction containing C8 and C9 hydrocarbons; and converting the styrene and methylstyrene to their corresponding ethers by reacting with a C1-C3 lower alcohol in the presence of a selective acidic etherification catalyst. The effluent may be sent to a gasoline pool for blending or the effluent is separated by distillation into an ether stream and either a C8 or a C8-C9 aromatic hydrocarbon rich stream. The C5-C7 distillate is hydrogenated.
摘要翻译： 各种基本上苯乙烯，甲基苯乙烯和乙基苯的C 6 -C 9芳族烃共混物是由包含苯乙烯，甲基苯乙烯和硫化合物的C 5 -C 9芳烃的烃进料流产生的，首先将料流分离成含有C5-C7烃的馏出物 和含有C8和C9烃的塔底馏分; 并通过在选择性酸性醚化催化剂存在下与C1-C3低级醇反应，将苯乙烯和甲基苯乙烯转化为相应的醚。 流出物可以被送到用于混合的汽油池中，或者通过蒸馏将流出物分离成醚流和C8或C8-C9富含芳烃的料流。 C5-C7馏出物被氢化。
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