摘要:
New sulfided metal catalysts are described, containing a metal X selected from Ni, Co and mixtures thereof, a metal Y selected from Mo, W and mixtures thereof, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by the sulfidation of mixed oxide precursors, also new, having general formula (A) XaYbZcOd.pC (A) possibly shaped without a binder, or by sulfidation of mixed oxides having formula (A), in shaped form with a binder, wherein X is selected from Ni, Co and mixtures thereof, Y is selected from Mo, W and mixtures thereof, Z is selected from Si, Al and mixtures thereof, 0 is oxygen, C is selected from: a nitrogenated compound N, an organic residue deriving from the partial calcination of the nitrogenated compound N, said nitrogenated compound N, when present, being selected from: a) an alkyl ammonium hydroxide having formula (I) RIRIIRIIIRIVNOH (I) wherein the groups RI-RIV, the same or different, are aliphatic groups containing from 1 to 7 carbon atoms, b) an amine having formula (II) R1R2R3N (II) wherein R1 is a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, and R2 and R3, the same or different, are selected from H and a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, said alkyl being equal to or different from R1, a, b, c, d are the number of moles of the elements X, Y, Z, O, respectively, p is the weight percentage of C with respect to the total weight of the precursor having formula (A), a, b, c, d are higher than 0 a/b is higher than or equal to 0.3 and lower than or equal to 2, (a+b)/c is higher than or equal to 0.3 and lower than or equal to 10, preferably varying from 0.8 to 10 d=(2a+6b+Hc)/2 wherein H=4 when Z=Si H=3 when Z=Al and p is higher than or equal to 0 and lower than or equal to 40%. Said catalysts can be used as hydrotreating catalysts.
摘要:
The present invention relates to a process for the removal of organic acids, particularly naphthenic acids, from crude oils and crude oil distillates by use of a supported basic ionic liquid in a mass ratio of crude oil and/or crude oil distillate and ionic liquid of from greater than 40:1, the basic ionic liquid comprises a basic anion selected from serinate, prolinate, histidinate, threoninate, valinate, asparaginate, taurinate and lysinate.
摘要:
The present invention is related to a process oil using as a raw material a deasphalted oil obtained by deasphalting a vacuum residual oil of a crude oil and a manufacturing method of the process oil, the process oil having properties of: (a) a polycyclic aromatics (PCA) content of less than 3 mass %; (b) a viscosity (100° C.) of 40 to 70 mm2/s; (c) an aniline point of 85 to 100° C.; (d) a flash point of 250° C. or higher; (e) an aromatic hydrocarbon content of 40 to 55 mass %; and (f) a polar substance content of 10 to 15 mass %. The present invention is also related to a process oil and a manufacturing method of the process oil, the process oil obtained by mixing: an extract obtained by deasphalting and solvent-extracting a vacuum residual oil of a crude oil; and a lubricant base oil having a polycyclic aromatics (PCA) content of less than 3 mass %, and having properties of: (a) a polycyclic aromatics (PCA) content of less than 3 mass %; (i) a viscosity (100° C.) of 30 to 80 mm2/s; (j) an aniline point of 90° C. or lower; (k) a flash point of 240° C. or higher; (l) a benzo(a)pyrene content of 1 mass ppm or less; (m) a specified aromatic compound content of 10 mass ppm or less; and (n) a polar substance content of 10 to 30 mass %.
摘要:
A hydrocarbon synthesizer system for the production of petroleum fractions from a feedstock. Methods of synthesizing hydrocarbons from a feedstock.
摘要:
A method for purifying a fluid from contaminating particles in a centrifugal separator by means of a separation aid which is of higher density than the fluid and which binds said particles, the centrifugal separator having a rotor body that rotates about an axis of rotation. The fluid to be purified is led via an inlet into a separation chamber delimited by the rotor body. Separated particles are discharged via a first outlet and clarified fluid cleared is discharged via a second outlet. The fluid being mixed with an amount of separation aid, supplied to the separation chamber. The pollutant particles are bound to the separation aid, which is forced out by the rotation of the rotor body to the periphery thereof. A small flow of separation aid and particles bound thereto are discharged from the separation chamber via the first outlet, and a flow of purified fluid is discharged from the separation chamber via the second outlet.
摘要:
A selective adsorbent by means of which halogenated aromatic compounds contained in organic media in small amounts can be selectively adsorbed and either removed or concentrated from the organic media to facilitate decomposition of the halogenated aromatic compounds. The selective adsorbent comprises a composition comprising a compound that interacts with the halogenated aromatic compound attractively and which is selected from the group consisting of a cyclic compound selected from the group consisting of a modified cyclodextrin compound represented by the following formula 1: (where R1 is an amino group, an alkyl group, an alkenyl group, an alkynyl group, a halogen atom, a haloalkyl group, an aryl group, an aralkyl group, an alkoxyalkyl group, a nitro group, an alkanoyl group, an aroyl group, an alkoxycarbonyl group, an arylalkoxycarbonyl group, an alkoxy group, a haloalkoxy group, an aryloxy group, an aralkyloxy group, an alkoxyalkyloxy group, an alkanoyloxy group, an alkoxycarbonyloxy group, an aralkyloxycarbonyloxy group, an alkylsilyl group, or an alkylsilyloxy group; n is 6, 7, or 8), other cyclic oligosaccharides, a supermolecular assembly of cyclodextrin, a crown compound, cyclophane, azacyclophane, thiocyclophane, cryptand, cyclotriveratrylene, cavitand, calixarene, spherand, and cyclic oligopeptides; dimers of these cyclic compounds; an acyclic compound selected from the group consisting of acyclic oligosaccharides and acyclic oligopeptides; and mixtures of two or more species of these cyclic compounds and/or these acyclic compounds.
摘要:
A method for improving the lubricating properties of a distillate base oil characterized by a pour point of 0 degrees C. or less and a boiling range having the 10 percent point falling between about 625 degrees F. and about 790 degrees F. and the 90 percent point falling between about 725 degrees F. and about 950 degrees F., the method comprises blending with said distillate base oil a sufficient amount of a pour point depressing base oil blending component to reduce the pour point of the resulting base oil blend at least 3 degrees C. below the pour point of the distillate base oil, wherein the pour point depressing base oil blending component is an isomerized Fischer-Tropsch derived bottoms product having a pour point that is at least 3 degrees C. higher than the pour point of the distillate base oil.
摘要:
An improved aromatics saturation process for use with lube oil boiling range feedstreams utilizing a catalyst comprising a hydrogenation-dehydrogenation component selected from the Group VIII noble metals and mixtures thereof on a mesoporous support having aluminum incorporated into its framework and an average pore diameter of about 15 to less than about 40 Å.
摘要:
An new class of oil-soluble, sulfur scavengers or converts are disclosed where the scavengers include substantially monomeric aldehyde-amine adducts from the reaction of at least one sterically hindered primary or secondary amine and a molar excess of at least one aldehyde. Methods are also disclosed for reducing, reducing below a given level or eliminating noxious sulfur species from fluids using the inventive scavengers and for making the inventive scavengers.
摘要:
A stacked bed catalyst system comprising at least one first catalyst selected from conventional hydrotreating catalyst having an average pore diameter of greater than about 10 nm and at least one second catalyst comprising a bulk metal hydrotreating catalyst.