摘要:
A method for coating of a metallic coil or of metallic sheets with an aqueous coating composition comprising at least one compound selected from the group consisting of zirconium compounds, titanium compounds and hafnium compounds whereby the such treated metallic coil or metallic sheets is/are shaped by cold extruding, by deep-drawing, by drawing, by necking, by punching, by wall ironing or by any combination of such process steps to a hollow article like a container or a casing and is then cleaned and optionally further coated either by chemical pre-treatment and then by coating with ink or paint or both or by chemical treatment.
摘要:
The invention relates to a functionalized phenol-aldehyde resin which comprises a phenol-aldehyde condensation product, having a phenol component with no carboxyl group, and an aromatic hydroxycarboxylic acid and imidazole as constituents which is useful for corrosion-inhibiting treatment of bare or conversion-coated metal surfaces is provided. Methods of making the functionalized phenol-aldehyde resin, processes for coating metal surfaces using compositions according to the invention and products coated thereby are also included in the invention.
摘要:
A universal aqueous composition and a process for using such a composition for pretreating metal substrates is provided. The aqueous composition includes a hydroxy functional cyclic compound, such as a tannin, in an amount of at least about 500 ppm, phosphate ions, an oxidizer-accelerator, and at least one Group IVB metal compound capable of converting to a metal oxide upon application to the metal substrate, such as a fluorozirconate or fluorotitanate. The composition may further contain fluoride ions and/or iron. The composition is particularly useful for corrosion resistance with a variety of metals such as iron, steel, zinc-coated surfaces, aluminum, and alloys thereof. A disaccharide may further be provided to prolong the useful life of the composition, particularly when used in spray applications.
摘要:
The present invention provides a method of coating aluminum and aluminum alloy substrates by which not only a corrosion resistance comparable or even superior to that afforded by chromate treatment can be imparted but also the adhesion to the coating film can be improved, while the luster of aluminum is fully retained, notwithstanding the use of a chromium-free treating solution, as well as a coated article with the coated surface according to the above method having a metallic luster. The present invention provides a method of coating aluminum and aluminum alloy substrates which comprises treating an aluminum or aluminum alloy substrate with an acidic solution containing sulfuric acid and 0.2 to 0.4 g/L of a ferric ion and having a pH value of 0.6 to 2.0, subjecting the same to chemical conversion treatment with an acidic coat-forming agent containing 0.01 to 0.125 g/L of a zirconium or titanium ion, 0.01 to 1.0 g/L of a phosphate ion, and 0.01 to 0.5 g/L of a fluoride ion and having a pH value of 1.5 to 4.0, followed by coating.
摘要:
A lubricant and surface conditioner for formed metal surfaces, particularly aluminum and tin beverage containers, reduces the coefficient of static friction of said metal surfaces and enables drying said metal surfaces at a lower temperature. The conditioner includes a water-soluble organic material selected from amine oxides and quaternary ammonium salts, fluozirconate, fluohafnate, or fluotitanate ion, and preferably also phosphate and nitrate ions. Good resistance to damaging the friction reducing effect by overheating and to staining of the domes of treated containers during pasteurization can be achieved.
摘要:
A surface treatment chemicals for aluminum or its alloy consisting essentially of 10-1000 parts by weight of niobium ion and/or tantalum ion, and 1-50 parts by weight of effective fluorine ion, and optionally 10-500 parts by weight of zirconium ion and/or titanium ion and 10-500 parts by weight of phosphate ion. A surface treatment bath is produced by diluting the surface treatment chemicals so as to have a pH of 1.5-4.0. Excellent resistance to blackening by boiling water and adhesion to an overlying polymer coating film can be obtained by a surface treatment using this bath.
摘要:
The invention is in a composition and process for the chromium free passivating postrinsing of conversion layers on metals before the application of a paint or adhesive. The conversion layers can be on the bases of phosphate layers, at least two polyvalent metal ions with complex formers, titanium, zirconium and/or hafnium. The postrinsing agent is an aqueous solution which has been adjusted to a pH value of up to 5 and which contains an aluminum fluorozirconate having an Al:Zr:F mole ratio of (0.15 to 8.0):1:(5 to 52), and in which solutions the total concentration of Al+Zr+F is 0.1 to 8.0 g/l. The postrinsing solutions may additionally contain at least one of the anions benzoate, caprylate, ethyl hexoate, salicylate in a total concentration of 0.05 to 0.5 g/1 and may preferably be adjusted to the required pH value with cations of volatile bases, such as ammonium, ethanolammonium and di- and triethanolammonium. The paint is subsequently applied suitably by cathodic electrocoating or powder coating or from a low-solvent high-solids paint.The rinsing treatment is over a period of 1 to 120 seconds at temperatures of 20.degree. to 80.degree. C. The invention is used as a pretreatment to the application of a paint coating, film coating or adhesive coating.
摘要:
A surface treatment chemical for aluminum or its alloy comprising 10-1000 parts by weight of vanadium or cerium ion, 10-500 parts by weight of zirconium ion, 10-500 parts by weight of phosphate ion and 1-50 parts by weight of effective fluorine ion. A surface treatment bath for aluminum or its alloy comprising 10-1000 ppm of vanadium or cerium ion, 10-500 ppm of zirconium ion, 10-500 ppm of phosphate ion and 1-50 ppm of effective fluorine ion, and having pH of 2.0-4.0.
摘要:
A metal article is improved on its surface for the purpose of plating thereon by treatment with an additive of an anionic, cationic or amphoteric and water-soluble or water-self-dispersible organic polymer J, K or L. J is a polymer having an aromatic ring and OH group and a polar group. K is a polymer of hydroxystyrene having a polar group. L is a copolymer of hydroxystyrene having a polar group and a vinyl compound. The article this way plated is improved in corrosion resistance.
摘要:
A composition and process are useful for imparting corrosion resistance and paint receptivity to metal surfaces. The process involves application of an aqueous wet film which is dried in place and thus avoids effluent problems from conventional processes involving rinsing. The composition contains a water soluble titanium zirconium compound, an inositol 2-6 phosphate ester and silica.