Corrosion inhibitor formulations with improved performance, lower toxicity and reduced manufacturing hazards
    2.
    发明授权
    Corrosion inhibitor formulations with improved performance, lower toxicity and reduced manufacturing hazards 有权
    具有改进性能,降低毒性和降低制造危害的防腐剂配方

    公开(公告)号:US07981314B2

    公开(公告)日:2011-07-19

    申请号:US11431780

    申请日:2006-05-10

    IPC分类号: C09K5/00

    摘要: Aqueous corrosion inhibitor compositions, preferably storage-stable, useful in acidic cleaning solutions for cleaning the surfaces of metal, comprising reaction products of at least one rosin amine component, at least one non-flammable liquid ketone component, at least one carboxylic acid component, at least one paraformaldehyde component and water; aqueous acidic cleaners prepared therefrom; and methods of their use. The inventive corrosion inhibitor compositions are made by a simple process which reduces the presence of toxic and/or flammable raw materials, co-products, residual reactants and chloride ion while providing acid inhibition in aqueous acidic cleaners.

    摘要翻译: 水性缓蚀剂组合物,优选储存稳定的,可用于清洁金属表面的酸性清洁溶液,其包含至少一种松香胺组分,至少一种不可燃液体酮组分,至少一种羧酸组分的反应产物, 至少一种多聚甲醛组分和水; 由其制备的含水酸性清洁剂; 及其使用方法。 本发明的腐蚀抑制剂组合物通过简单的方法制备,该方法减少有毒和/或可燃的原料,副产物,残余反应物和氯离子的存在,同时在含水酸性清洁剂中提供酸抑制。

    Aminated hydroxylated polyester polyol resin and molding compositions
comprised thereof
    5.
    发明授权
    Aminated hydroxylated polyester polyol resin and molding compositions comprised thereof 失效
    氨基羟基化聚酯多元醇树脂及其成型组合物

    公开(公告)号:US4874837A

    公开(公告)日:1989-10-17

    申请号:US141808

    申请日:1988-01-11

    摘要: An aminated, hydroxylated, polyester polyol resin comprised of the product of a reaction of an acid anhydride selected from the group including maleic acid anhydride or a mixture of maleic acid anhydride and a polyfunctional acid anhydride, a low molecular weight polyether polyol having an average molecular weight of about 100 to about 600, selected from the group including diethylene glycol or a mixture of diethylene glycol and another low molecular weight polyether polyol, a lower alkylene oxide and having from 2 to 4 carbon atoms, and a mono- or di-functional amino compound selected from the group including diethanolamine or a mixture of diethanolamine and at least one mono- or di-functional amino compounds containing at least one isocyanate reactive group attached to the nitrogen of the mono- or di- functional amino compound. The aminated, hydroxylated, polyester polyol resins are particularly useful forming a thermosetting composition comprising the aminated, hydroxylated, polyester polyol resin and polyisocyanate in reaction injection molding process to prepare molded articles.

    摘要翻译: 由选自马来酸酐或马来酸酐与多官能酸酐的混合物的酸酐反应的产物构成的胺化羟基化聚酯多元醇树脂,具有平均分子量 约100至约600的重量,选自包括二甘醇或二甘醇和另一低分子量聚醚多元醇的混合物,低级环氧烷和具有2至4个碳原子的单体或二官能团 选自包括二乙醇胺或二乙醇胺和至少一种含有至少一个与单官能或二官能氨基化合物的氮连接的异氰酸酯反应性基团的单官能或二官能氨基化合物的氨基化合物。 胺化的羟基化聚酯多元醇树脂在反应注射成型工艺中形成包含胺化的,羟基化的聚酯多元醇树脂和多异氰酸酯的热固性组合物是特别有用的,以制备模塑制品。

    Aminated hydroxylated polyester polyol resin and molding compositions
comprised thereof
    6.
    发明授权
    Aminated hydroxylated polyester polyol resin and molding compositions comprised thereof 失效
    氨基羟基化聚酯多元醇树脂及其成型组合物

    公开(公告)号:US4868267A

    公开(公告)日:1989-09-19

    申请号:US141809

    申请日:1988-01-11

    摘要: A thermosetting resin composition comprising the product of an unsaturated polyester intermediate resin which is derived from the reaction of (a) an acid anhydride selected from the group including maleic acid anhydride or a mixture of maleic anhydride and a polyfunctional acid anhydride, a low molecular weight polyether polyol having a molecular weight of about 100 to about 600 selected from the group including diethylene glycol or a mixture of diethylene glycol and at least one other low molecular weight polyether polyol having a molecular weight of about 100 to about 600, and a lower alkylene oxide having from 2-4 carbon atoms; and, (b) a mono- or di-functional amino compound selected from the group including diethanolamine or a mixture of diethanolamine and at least one other mono- or di-functional amino compounds selected from the group including a primary or secondary amino alcohol or a primary or secondary diamine which contain isocyanate reactive groups attached to the nitrogen of the amino alcohol or diamine, the equivalent ratio of mono- or di-functional amino compound to unsaturated polyester intermediate resin being in the range from about 0.125 to about 0.5, such that a corresponding proportion of the unsaturated polyester intermediate resin remains unreacted and has a maleate functionality; (c) a morpholine compound; (d) a vinyl crosslinking compound; and (e) an isocyanate. The thermosetting resin compositions are especially useful in a reaction injection molding (RIM) process to prepare molded articles.

    摘要翻译: 一种热固性树脂组合物,其包含不饱和聚酯中间体树脂的产物,其衍生自(a)选自马来酸酐或马来酸酐与多官能酸酐的混合物的酸酐,低分子量 分子量为约100至约600的聚醚多元醇,其选自包括二甘醇或二甘醇与分子量为约100至约600的至少一种其它低分子量聚醚多元醇的混合物,以及低级亚烷基 具有2-4个碳原子的氧化物; 和(b)选自包括二乙醇胺或二乙醇胺和至少一种其它选自伯或仲氨基醇的其它单 - 或二官能氨基化合物的混合物的单官能或二官能氨基化合物或 包含与氨基醇或二胺的氮连接的异氰酸酯反应性基团的伯或仲二胺,单官能或二官能氨基化合物与不饱和聚酯中间体树脂的当量比在约0.125至约0.5的范围内, 相应比例的不饱和聚酯中间体树脂保持未反应并具有马来酸酯官能度; (c)吗啉化合物; (d)乙烯基交联化合物; 和(e)异氰酸酯。 热固性树脂组合物特别可用于制备模塑制品的反应注射成型(RIM)方法。

    Method of determining inhibitor concentrations in inhibited acidic pickling solutions
    9.
    发明授权
    Method of determining inhibitor concentrations in inhibited acidic pickling solutions 失效
    抑制酸性酸洗液中抑制剂浓度的测定方法

    公开(公告)号:US06329206B1

    公开(公告)日:2001-12-11

    申请号:US09338007

    申请日:1999-06-22

    申请人: James P. Bershas

    发明人: James P. Bershas

    IPC分类号: G01N3102

    摘要: The concentration of a hexamethylenetetramine-containing inhibitor in an acid pickling solution that has accumulated dissolved iron from use of the solution in pickling ferriferous material can be estimated with sufficient accuracy for practical control of the pickling process by alkalinizing a sample of the pickling solution to a pH of at least 10.8, so that any iron content of the solution precipitates from the solution, separating the precipitate from the liquid remainder of the alkalinized sample, and determining by colorimetry the concentration in the liquid remainder of formaldehyde produced by acid catalyzed hydrolysis of the hexamethylenetetramine to formaldehyde and ammonia.

    摘要翻译: 通过使用酸洗液中的溶液将酸中浸渍溶液中的含六亚甲基四胺的抑制剂的浓度估计可以足够的精度来实际控制酸洗方法,将酸洗液样品碱化为 pH至少为10.8,使得溶液中的任何铁含量从溶液中沉淀出来,将沉淀物与碱性样品的液体剩余物分离,并通过比色法测定由酸催化水解产生的甲醛液体剩余物中的浓度 六亚甲基四胺与甲醛和氨。