摘要:
This disclosure provides corrosion-resistant coatings that significantly improve corrosion resistance compared to the prior art. The corrosion protection system senses gradients in electrical potential, pH, and metal ion concentration, and then automatically halts corrosion. Some variations provide a gradient-responsive corrosion-resistant coating comprising: a first layer comprising a transition metal oxide and mobile cations; a second layer comprising a biphasic polymer, wherein the biphasic polymer contains ionic groups, wherein the biphasic polymer comprises a discrete phase and a continuous transport phase, wherein the continuous transport phase is capable of delivering oligomers in response to corrosion byproducts, and wherein the oligomers are ionically crosslinkable with metal cations from a base metal substrate. Other variations provide a corrosion protection system comprising: a base metallic layer; a metal oxide layer comprising a transition metal oxide and mobile cations; a polymer layer comprising a biphasic polymer; and a sealing layer disposed on the polymer layer.
摘要:
The present disclosure provides an aqueous binder composition for forming a sacrificial corrosion-protective coating, said composition being free of chromates and also preferably free of borates and molybdates. Said binder composition advantageously has a pH of less than 6 and comprises a binder, particles of at least one metal oxide and at least one metallic phosphate, said binder comprising a hydrolyzed organosilane oligomer. In addition, the proportion by weight of said particles of at least one metal oxide relative to the total dry weight of said binder composition is greater than or equal to 75%.
摘要:
The present invention relates to a method for producing an anticorrosion coating, wherein (1) an anticorrosion primer comprising (A) at least one organic resin as binder and (B) at least one synthetic layered double hydroxide comprising organic anions is applied directly to a metallic substrate and (2) a polymer film is formed from the anticorrosion primer applied in stage (1), the method being characterized in that the at least one synthetic layered double hydroxide (B) comprises at least one organic anion of the following formula (I): where R1═COO−, SO3−, R2/R3═NH2, OH, H. The present invention relates, furthermore, to coated metallic substrates coated by the method of the invention. The present invention relates not least to the use of the anticorrosion primer for use in the method of the invention for improving the corrosion resistance of metallic substrates.
摘要:
A coating composition includes a conductive polymer including at least one of the following: a single conductive polymer, a dual strand conductive polymer, a combination of a single conductive polymer and a dual strand conductive polymer or an organic-inorganic hybrid composite.
摘要:
The invention discloses thermosetting water-based paint comprising water-dispersible acrylic polymer particles which are obtained through multi-stage emulsion polymerization of radical polymerizable unsaturated monomers using a specific reactive emulsifying agent, said monomers comprising amido-containing radical polymerizable unsaturated monomer having at least 2 radical polymerizable unsaturated groups per molecule, methacrylic acid and hydroxyl-containing radical polymerizable unsaturated monomer; and coating film-forming methods which use the thermosetting water-based paint.
摘要:
A process is described for treating metal surfaces printed wiring boards and similar substrates to provide improved creep corrosion resistance on such surfaces. A modified organic solderability preservative composition is used in combination with an emulsion polymer to provide a modified polymer coating on the metal surface finish via a chemical reaction to provide enhanced corrosion protection of the surface.
摘要:
An aqueous mixture AB comprising, in its solids, a mass fraction of from 5 % to 40 % of a polyvinyl butyral B, and a mass fraction of from 60 % to 95 % of a Mannich base A which is made by a two-step reaction wherein an epoxy amine adduct A1 prepared in the first step from an epoxy resin A11 with a mixture A12 of a primary linear or branched aliphatic amine A121 having from 2 to 30 carbon atoms and a further aliphatic linear, branched or cyclic amine A122 having from 4 to 16 carbon atoms and having one primary and at least one tertiary amino group, which epoxy amine adduct A1 is reacted in die second step with formaldehyde and a phenolic compound A2 to form a Mannich base, and a method of use thereof as a binder in wash primers.
摘要:
A coating composition includes a conductive polymer including at least one of the following: a single conductive polymer, a dual strand conductive polymer, a combination of a single conductive polymer and a dual strand conductive polymer or an organic-inorganic hybrid composite.
摘要:
Perfluoropolyether benzotriazole compounds and compositions containing perfluoropolyether benzotriazole compounds are provided. The perfluoropolyether benzotriazole compounds can be attached to a substrate having a metal or metal oxide-containing surface to provide at least one of the following characteristics: anti-soiling, anti-staining, ease of cleaning, repellency, hydrophobicity, or oleophobicity.
摘要:
The invention relates to a functionalized phenol-aldehyde resin which comprises a phenol-aldehyde condensation product, having a phenol component with no carboxyl group, and an aromatic hydroxycarboxylic acid and imidazole as constituents which is useful for corrosion-inhibiting treatment of bare or conversion-coated metal surfaces is provided. Methods of making the functionalized phenol-aldehyde resin, processes for coating metal surfaces using compositions according to the invention and products coated thereby are also included in the invention.