Gradient-responsive corrosion-resistant coatings

    公开(公告)号:US11891538B1

    公开(公告)日:2024-02-06

    申请号:US17864945

    申请日:2022-07-14

    摘要: This disclosure provides corrosion-resistant coatings that significantly improve corrosion resistance compared to the prior art. The corrosion protection system senses gradients in electrical potential, pH, and metal ion concentration, and then automatically halts corrosion. Some variations provide a gradient-responsive corrosion-resistant coating comprising: a first layer comprising a transition metal oxide and mobile cations; a second layer comprising a biphasic polymer, wherein the biphasic polymer contains ionic groups, wherein the biphasic polymer comprises a discrete phase and a continuous transport phase, wherein the continuous transport phase is capable of delivering oligomers in response to corrosion byproducts, and wherein the oligomers are ionically crosslinkable with metal cations from a base metal substrate. Other variations provide a corrosion protection system comprising: a base metallic layer; a metal oxide layer comprising a transition metal oxide and mobile cations; a polymer layer comprising a biphasic polymer; and a sealing layer disposed on the polymer layer.

    Method For Producing An Anticorrosion Coating
    3.
    发明申请
    Method For Producing An Anticorrosion Coating 有权
    生产防腐涂料的方法

    公开(公告)号:US20140302334A1

    公开(公告)日:2014-10-09

    申请号:US14351475

    申请日:2012-10-19

    IPC分类号: C09D5/08 C23F11/00

    摘要: The present invention relates to a method for producing an anticorrosion coating, wherein (1) an anticorrosion primer comprising (A) at least one organic resin as binder and (B) at least one synthetic layered double hydroxide comprising organic anions is applied directly to a metallic substrate and (2) a polymer film is formed from the anticorrosion primer applied in stage (1), the method being characterized in that the at least one synthetic layered double hydroxide (B) comprises at least one organic anion of the following formula (I): where R1═COO−, SO3−, R2/R3═NH2, OH, H. The present invention relates, furthermore, to coated metallic substrates coated by the method of the invention. The present invention relates not least to the use of the anticorrosion primer for use in the method of the invention for improving the corrosion resistance of metallic substrates.

    摘要翻译: 本发明涉及一种防腐涂层的制造方法,其中(1)防腐底漆,其包含(A)至少一种作为粘合剂的有机树脂和(B)至少一种包含有机阴离子的合成层状双氢氧化物直接施加到 金属基材和(2)聚合物膜由在阶段(1)中应用的防腐底漆形成,其特征在于至少一种合成层状双氢氧化物(B)包含至少一种下式的有机阴离子( I):其中R1 = COO-,SO3-,R2 / R3 = NH2,OH,H。此外,本发明还涉及通过本发明的方法涂覆的涂覆的金属基材。 本发明不仅在于本发明的用于提高金属基材的耐腐蚀性的防腐底漆的用途。

    Organic polymer coating for protection against creep corrosion
    6.
    发明申请
    Organic polymer coating for protection against creep corrosion 有权
    有机聚合物涂层,用于防止蠕变腐蚀

    公开(公告)号:US20100243301A1

    公开(公告)日:2010-09-30

    申请号:US12383650

    申请日:2009-03-27

    IPC分类号: H05K1/09 H05K3/28

    摘要: A process is described for treating metal surfaces printed wiring boards and similar substrates to provide improved creep corrosion resistance on such surfaces. A modified organic solderability preservative composition is used in combination with an emulsion polymer to provide a modified polymer coating on the metal surface finish via a chemical reaction to provide enhanced corrosion protection of the surface.

    摘要翻译: 描述了一种用于处理金属表面印刷线路板和类似基底的方法,以在这些表面上提供改善的耐蠕变腐蚀性。 改性有机可焊性防腐剂组合物与乳液聚合物组合使用,以通过化学反应在金属表面光洁度上提供改性聚合物涂层,以提供增强的表面腐蚀保护。

    WATER-BORNE CATIONIC BINDERS FOR WASH PRIMERS
    7.
    发明申请
    WATER-BORNE CATIONIC BINDERS FOR WASH PRIMERS 审中-公开
    WATER-BORNE洗衣机的阳离子粘合剂

    公开(公告)号:US20090221465A1

    公开(公告)日:2009-09-03

    申请号:US12280732

    申请日:2007-03-01

    IPC分类号: C11D3/37 C23G1/06

    摘要: An aqueous mixture AB comprising, in its solids, a mass fraction of from 5 % to 40 % of a polyvinyl butyral B, and a mass fraction of from 60 % to 95 % of a Mannich base A which is made by a two-step reaction wherein an epoxy amine adduct A1 prepared in the first step from an epoxy resin A11 with a mixture A12 of a primary linear or branched aliphatic amine A121 having from 2 to 30 carbon atoms and a further aliphatic linear, branched or cyclic amine A122 having from 4 to 16 carbon atoms and having one primary and at least one tertiary amino group, which epoxy amine adduct A1 is reacted in die second step with formaldehyde and a phenolic compound A2 to form a Mannich base, and a method of use thereof as a binder in wash primers.

    摘要翻译: 一种含水混合物AB,其包含固体中的聚乙烯醇缩丁醛B的5%至40%的质量分数,以及通过两步制备的曼尼希碱A的60%至95%的质量分数 反应,其中在第一步中由环氧树脂A11制备的环氧胺加合物A1与具有2-30个碳原子的伯直链或支链脂族胺A121的混合物A12和另外的脂族直链,支链或环状胺A122 4至16个碳原子并且具有一个伯和至少一个叔氨基,该环氧胺加合物A1在第二步中与甲醛和酚化合物A2反应以形成曼尼希碱,以及其用作粘合剂的方法 在洗涤底漆。

    Perfluoropolyether benzotriazole compounds
    9.
    发明授权
    Perfluoropolyether benzotriazole compounds 失效
    全氟聚醚苯并三唑化合物

    公开(公告)号:US07449266B2

    公开(公告)日:2008-11-11

    申请号:US11553853

    申请日:2006-10-27

    IPC分类号: G03G13/00 C07D249/12

    摘要: Perfluoropolyether benzotriazole compounds and compositions containing perfluoropolyether benzotriazole compounds are provided. The perfluoropolyether benzotriazole compounds can be attached to a substrate having a metal or metal oxide-containing surface to provide at least one of the following characteristics: anti-soiling, anti-staining, ease of cleaning, repellency, hydrophobicity, or oleophobicity.

    摘要翻译: 提供全氟聚醚苯并三唑化合物和含有全氟聚醚苯并三唑化合物的组合物。 全氟聚醚苯并三唑化合物可以连接到具有金属或含金属氧化物的表面的基材上,以提供以下特征中的至少一种:抗污染,抗污染,易于清洁,排斥性,疏水性或疏油性。