CHROMIUM (III)-CONTAINING AQUEOUS SOLUTION AND PROCESS FOR PRODUCING THE SAME
    2.
    发明申请
    CHROMIUM (III)-CONTAINING AQUEOUS SOLUTION AND PROCESS FOR PRODUCING THE SAME 审中-公开
    铬(III) - 水溶液及其生产方法

    公开(公告)号:US20110162556A1

    公开(公告)日:2011-07-07

    申请号:US13062486

    申请日:2009-08-27

    Abstract: It is intended to provide a chromium (III)-containing aqueous solution which has widely adjustable molar ratios of various acid radicals to Cr and is useful as a source of trivalent chromium or a supplementary source of trivalent chromium for the bath in the surface treatment of various metals. Specifically, the chromium (III)-containing aqueous solution is characterized by containing a complex chromium (III) salt which is produced by performing chromic acid reduction reaction in the simultaneous or sequential presence of two or more acids selected from an inorganic acid other than chromic acid and an organic acid. Furthermore, it is intended to provide a process for producing a chromium (III)-containing aqueous solution by performing chromic acid reduction reaction by the contact of chromic acid with an acid other than chromic acid and/or an organic reducing agent in a water solvent, characterized in that the chromic acid reduction reaction is performed in the simultaneous or sequential presence of at least two or more acids selected as the acid other than chromic acid from an inorganic acid and an organic acid.

    Abstract translation: 旨在提供一种含铬(III)的水溶液,其具有广泛可调的各种酸基与Cr的摩尔比,并且可用作三价铬的来源或用于在表面处理中的浴中的三价铬的补充来源 各种金属。 具体地说,含铬(III)的水溶液的特征在于,含有复合铬(III)盐,它是通过在两种或更多种选自铬酸盐以外的无机酸的同时或相继存在下进行铬酸还原反应 酸和有机酸。 此外,本发明旨在提供一种通过在水溶剂中使铬酸与铬酸和/或有机还原剂之间的酸接触进行铬酸还原反应来制备含铬(III)的水溶液的方法 其特征在于,所述铬酸还原反应是在无机酸和有机酸中选择为不同于铬酸的酸的至少两种或多种酸的同时或相继存在下进行的。

    Use of substituted hydroxylamines in metal phosphating processes
    4.
    发明授权
    Use of substituted hydroxylamines in metal phosphating processes 有权
    在金属磷化工艺中使用取代的羟胺

    公开(公告)号:US07294210B2

    公开(公告)日:2007-11-13

    申请号:US10319115

    申请日:2002-12-13

    Applicant: Richard Church

    Inventor: Richard Church

    CPC classification number: C23C22/08 C23C22/10 C23C22/12 C23C22/13 C23C22/18

    Abstract: Alkyl-substituted hydroxylamines are useful as aids in the phosphating of metal substrates. In particular, the rate of phosphating and the rate at which manganese compounds are dissolved into aqueous phosphoric acid solutions may be accelerated by alkyl-substituted hydroxylamines.

    Abstract translation: 烷基取代的羟胺可用作金属底物磷酸化的辅助剂。 特别地,磷酸化速率和锰化合物溶解在磷酸水溶液中的速率可以通过烷基取代的羟胺加速。

    Process and solution for providing a thin corrosion inhibiting coating on a metallic surface
    5.
    发明申请
    Process and solution for providing a thin corrosion inhibiting coating on a metallic surface 审中-公开
    在金属表面提供薄的腐蚀抑制涂层的工艺和解决方案

    公开(公告)号:US20040118483A1

    公开(公告)日:2004-06-24

    申请号:US10328924

    申请日:2002-12-24

    CPC classification number: C23C22/73 C23C22/08 C23C22/10 C23C22/36

    Abstract: The invention relates to a process for coating metallic surfaces with a phosphating coating by contacting metallic surfaces at a temperature not above 45null C. and at a pH value less than 3.5 with an aqueous acidic alkali metal phosphating solution or dispersion containing: At least one compound of at least one phosphorus containing acid and/or at least one of their derivates like esters and salts in a total content of all kinds of acids and all their derivates like esters and salts together of less than 20 g/L calculated on mole base as orthophosphate, whereby the content of such phosphorus containing compounds/ions is at least 50% by weight in comparison to all such compounds/ions and at least one ion selected from the group consisting of at least one alkali metal ion and ammonium ion, whereby the phosphating coating has a coating composition with a phosphorus content of not more than 8 atomic % as measured by Secondary Neutral Mass Spectroscopy (SNMS) and whereby the phosphating coating has a coating weight in the range from 0.01 to 0.5 g/m2.

    Abstract translation: 本发明涉及一种通过磷酸盐涂层涂覆金属表面的方法,该方法是在酸性碱金属磷酸盐水溶液或分散体的水溶液或分散体水溶液中,使金属表面在不高于45℃,pH值小于3.5的温度下接触,至少含有一种 至少一种含磷酸和/或其衍生物中的至少一种衍生物的化合物,其总酸含量和所有其衍生物如酯和盐的总酸含量低于20g / L,基于摩尔数 作为正磷酸盐,由此与所有这样的化合物/离子和选自至少一种碱金属离子和铵离子的至少一种离子相比,含磷化合物/离子的含量为至少50重量%,由此 磷化涂层具有通过次级中性质谱(SNMS)测量的磷含量不超过8原子%的涂料组合物,由此磷化涂层 涂层重量在0.01至0.5g / m 2的范围内。

    Use of substituted hydroxylamines in metal phosphating processes
    6.
    发明申请
    Use of substituted hydroxylamines in metal phosphating processes 有权
    在金属磷化工艺中使用取代的羟胺

    公开(公告)号:US20030155042A1

    公开(公告)日:2003-08-21

    申请号:US10319115

    申请日:2002-12-13

    Inventor: Richard Church

    CPC classification number: C23C22/08 C23C22/10 C23C22/12 C23C22/13 C23C22/18

    Abstract: Alkyl-substituted hydroxylamines are useful as aids in the phosphating of metal substrates. In particular, the rate of phosphating and the rate at which manganese compounds are dissolved into aqueous phosphoric acid solutions may be accelerated by alkyl-substituted hydroxylamines.

    Abstract translation: 烷基取代的羟胺可用作金属底物磷酸化的辅助剂。 特别地,磷酸化速率和锰化合物溶解在磷酸水溶液中的速率可以通过烷基取代的羟胺加速。

    Method and composition for depositing heavy iron phosphate coatings
    8.
    发明授权
    Method and composition for depositing heavy iron phosphate coatings 失效
    沉积重金属磷酸盐涂层的方法和组成

    公开(公告)号:US5258078A

    公开(公告)日:1993-11-02

    申请号:US898413

    申请日:1992-06-15

    CPC classification number: C23C22/10 C23C22/08

    Abstract: An immersion bath composition and a method for applying a heavy, non-powdery coating of iron phosphate on a ferrous substance which is characterized by the addition of an effective amount of gluconic acid to a solution containing phosphoric acid, a soda ash, a chlorate or organic accelerator and water. Using conventional phosphating bath parameters, immersion of a ferrous substrate into the bath produces a heavy, strongly adherent, iron phosphate coating which is non-powdery or dust free and highly satisfactory for paint pre-treatment of the substrate surface.

    Abstract translation: 浸渍浴组合物和将铁磷酸盐重的非粉末涂层施用于铁质物质的方法,其特征在于向含有磷酸,苏打灰,氯酸盐的溶液中加入有效量的葡萄糖酸 有机促进剂和水。 使用常规磷化浴参数,将铁基底浸入浴中产生重的,强粘附的磷酸铁镀层,其非粉末或无粉尘,并且对于基材表面的油漆预处理非常满意。

    Copper-based metallic member having a chemical conversion film and
method for producing same
    9.
    发明授权
    Copper-based metallic member having a chemical conversion film and method for producing same 失效
    具有化学转化膜的铜基金属构件及其制造方法

    公开(公告)号:US4788086A

    公开(公告)日:1988-11-29

    申请号:US754231

    申请日:1985-07-12

    Inventor: Shigeki Matsuda

    CPC classification number: C23C22/10 C23C22/08 Y10T428/13 Y10T428/2958

    Abstract: Copper can be directly chemically converted by the disclosed method and a novel copper-based metallic member is proposed. The chemical conversion film formed on the copper-based metallic member comprises phosphate and copper halide. The chemical conversion bath contains metal ions, phosphoric acid ions, halogen ions, and oxidizer.

    Abstract translation: 铜可以通过公开的方法直接化学转化,并提出了一种新的铜基金属构件。 形成在铜基金属构件上的化学转化膜包括磷酸盐和卤化铜。 化学转化浴含有金属离子,磷酸离子,卤素离子和氧化剂。

    Conversion coating solutions for treating metallic surfaces
    10.
    发明授权
    Conversion coating solutions for treating metallic surfaces 失效
    用于处理金属表面的转化涂层溶液

    公开(公告)号:US4306917A

    公开(公告)日:1981-12-22

    申请号:US217233

    申请日:1980-12-17

    CPC classification number: C23C22/10

    Abstract: A conversion coating solution for treating metallic surfaces has a pH value in the range of 3 to 6 and contains 1 g/l to 50 g/l of an acid alkali phosphate as phosphate ions, 0.2 g/l to 20 g/l of one or more of chlorates and bromates, and 0.01 g/l to 0.5 g/l of tin ions, with a weight ratio of chlorine ions to tin ions being between 0.6 and 6. The solution provides a continuous and uniform conversion coating having high anti-corrosion performance.

    Abstract translation: 用于处理金属表面的转化涂层溶液的pH值在3至6的范围内,并且含有1g / l至50g / l的酸式磷酸碱式磷酸盐作为磷酸根离子,0.2g / l至20g / l的一种 或更多的氯酸盐和溴酸盐,以及0.01g / l至0.5g / l的锡离子,氯离子与锡离子的重量比为0.6至6.该溶液提供了连续且均匀的转化涂层, 腐蚀性能。

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