METHODS FOR REMOVING ETCH STOP LAYERS

    公开(公告)号:US20230035288A1

    公开(公告)日:2023-02-02

    申请号:US17858371

    申请日:2022-07-06

    Abstract: Methods open etch stop layers in an integrated environment along with metallization processes. In some embodiments, a method for opening an etch stop layer (ESL) prior to metallization may include etching the ESL with an anisotropic process using direct plasma to form helium ions that are configured to roughen the ESL for a first duration of approximately 10 seconds to approximately 30 seconds, forming aluminum fluoride on the ESL using remote plasma and nitrogen trifluoride gas for a second duration of approximately 10 seconds to approximately 30 seconds, and exposing the ESL to a gas mixture of boron trichloride, trimethylaluminum, and/or dimethylaluminum chloride at a temperature of approximately 100 degrees Celsius to approximately 350 degrees Celsius to remove aluminum fluoride from the ESL and a portion of a material of the ESL for a third duration of approximately 30 seconds to approximately 60 seconds.

    APPARATUS FOR REMOVING ETCH STOP LAYERS

    公开(公告)号:US20230031381A1

    公开(公告)日:2023-02-02

    申请号:US17858390

    申请日:2022-07-06

    Abstract: In some embodiments, an integrated tool for opening an etch stop layer and performing metallization comprises a first chamber with a remote plasma source, a direct plasma source, and a thermal source configured to open the etch stop layer on a substrate, a second chamber of the integrated tool with dry etch processing configured to pre-clean surfaces exposed by opening the etch stop layer, a third chamber of the integrated tool configured to deposit a barrier layer on the substrate, a fourth chamber of the integrated tool configured to deposit a liner layer on the substrate, and at least one fifth chamber of the integrated tool configured to deposit metallization material on the substrate. The integrated tool may also include a vacuum transfer chamber.

    3D NAND HIGH ASPECT RATIO STRUCTURE ETCH
    15.
    发明申请

    公开(公告)号:US20180182777A1

    公开(公告)日:2018-06-28

    申请号:US15855465

    申请日:2017-12-27

    Abstract: Embodiments of the present disclosure provide methods for forming features in a film stack. The film stack may be utilized to form stair-like structures with accurate profiles control in manufacturing three dimensional (3D) stacking of semiconductor chips. In one example, a method includes exposing a substrate having a multi-material layer formed thereon to radicals of a remote plasma to form one or more features through the multi-material layer, the one or more features exposing a portion of a top surface of the substrate, and the multi-material layer comprising alternating layers of a first layer and a second layer, wherein the remote plasma is formed from an etching gas mixture comprising a fluorine-containing chemistry, and wherein the process chamber is maintained at a pressure of about 2 Torr to about 20 Torr and a temperature of about −100° C. to about 100° C.

    LOW TEMPERATURE SILICON NITRIDE FILMS USING REMOTE PLASMA CVD TECHNOLOGY
    16.
    发明申请
    LOW TEMPERATURE SILICON NITRIDE FILMS USING REMOTE PLASMA CVD TECHNOLOGY 有权
    使用远程等离子CVD技术的低温硅氮化硅膜

    公开(公告)号:US20150126045A1

    公开(公告)日:2015-05-07

    申请号:US14520721

    申请日:2014-10-22

    Abstract: Embodiments of the present invention generally provide methods for forming a silicon nitride layer on a substrate. In one embodiment, a method of forming a silicon nitride layer using remote plasma chemical vapor deposition (CVD) at a temperature that is less than 300 degrees Celsius is disclosed. The precursors for the remote plasma CVD process include tris(dimethylamino)silane (TRIS), dichlorosilane (DCS), trisilylamine (TSA), bis-t-butylaminosilane (BTBAS), hexachlorodisilane (HCDS) or hexamethylcyclotrisilazane (HMCTZ).

    Abstract translation: 本发明的实施方案通常提供在衬底上形成氮化硅层的方法。 在一个实施例中,公开了在小于300摄氏度的温度下使用远程等离子体化学气相沉积(CVD)形成氮化硅层的方法。 用于远程等离子体CVD工艺的前体包括三(二甲基氨基)硅烷(TRIS),二氯硅烷(DCS),三甲基胺(TSA),双 - 叔丁基氨基硅烷(BTBAS),六氯二硅烷(HCDS)或六甲基环三硅氮烷(HMCTZ)。

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