摘要:
Provided is a method for producing a 2-alkenylamine compound efficiently and at low cost, using a primary or secondary amine compound and a 2-alkenyl compound as the starting materials therefor. The 2-alkenyleamine compound is produced by 2-alkenylating a primary or secondary amine compound, using a specified 2-alkenylating agent and in the presence of a catalyst comprising a complexing agent and a transition metal precursor stabilized by a monovalent anionic five-membered conjugated diene.
摘要:
Provided is a method for producing a 2-alkenylamine compound efficiently and at low cost, using a primary or secondary amine compound and a 2-alkenyl compound as the starting materials therefor. The 2-alkenylamine compound is produced by adding Bronsted acid when 2-alkenylating by reacting the primary or secondary amine compound with the 2-alkenyl compound, and 2-alkenylating in the presence of a catalyst comprising a complexing agent and a transition metal precursor stabilized by a monovalent anionic five-membered conjugated diene.
摘要:
An air breather structure for an automatic transmission. The structure includes a transmission case housing a power train accommodating a plurality of friction engagement devices, and an extension case housing a rotational member. The extension case and the transmission case are united with each other to constitute an automatic transmission housing. A breather chamber is located upside the automatic transmission housing in a state where the automatic transmission is mounted in a vehicle, and formed with an air vent for communication with outside air. An end wall is provided for partitioning the transmission case and the extension case therebetween to define a transmission case-side space and an extension case-side space. In this structure, the automatic transmission housing is formed with a transmission case-side communication passage through which the breather chamber communicates with the transmission case-side space, and an extension case-side communication passage through which the breather chamber communicates with the transmission case-side space.
摘要:
A moisture-permeable waterproof coating is formed by coating a fabric with a water-based coating composition containing a film forming polymer and a water-soluble polymer in a proportion of 5 to 70% based on total solids, drying or heating the fabric to form a film thereon; and then treating the resulting film with an aqueous solution of an enzyme which selectively degrades the water-soluble polymer, thereby enzymatically degrading the water-soluble polymer and extracting the degraded water soluble polymer from the film, whereby the film on the fabric is rendered microporous.
摘要:
A one-dimensional coordination polymer having a linear structure and represented by general formula (I) given below: where M denotes copper or nickel, X denotes a halogen atom, R denotes a pyrazine derivative represented by general formula (II) given below, and n is an integer: where each of Z1 and Z2, which may be the same or different, denotes an atomic group required for forming a carbon ring by joining with a methylene chain the carbon atoms in the 2-position and 3-position or the carbon atoms in the 5-position and 6-position of the pyrazine ring, and * denotes the binding position with M included in general formula (I).
摘要:
Disclosed are: a ligand for an asymmetric synthesis catalyst; and a process for producing an α-alkenyl cyclic compound using the ligand. Specifically disclosed are: a ligand for an asymmetric synthesis catalyst, which is represented by any one of formulae (1) to (4) [wherein R1 represents —Cl or —Br; R2 represents —CH3 or —CF3; and R3 represents —CH2—CH═CH2 or —H]; and a process for producing an α-alkenyl cyclic compound using the ligand.
摘要:
Provided is a method for producing a 2-alkenylamine compound efficiently and at low cost, using a primary or secondary amine compound and a 2-alkenyl compound as the starting materials therefor. The 2-alkenyleamine compound is produced by 2-alkenylating a primary or secondary amine compound, using a specified 2-alkenylating agent and in the presence of a catalyst comprising a complexing agent and a transition metal precursor stabilized by a monovalent anionic five-membered conjugated diene.
摘要:
An air breather structure for an automatic transmission. The structure includes a transmission case housing a power train accommodating a plurality of friction engagement devices, and an extension case housing a rotational member. The extension case and the transmission case are united with each other to constitute an automatic transmission housing. A breather chamber is located upside the automatic transmission housing in a state where the automatic transmission is mounted in a vehicle, and formed with an air vent for communication with outside air. An end wall is provided for partitioning the transmission case and the extension case therebetween to define a transmission case-side space and an extension case-side space. In this structure, the automatic transmission housing is formed with a transmission case-side communication passage through which the breather chamber communicates with the transmission case-side space, and an extension case-side communication passage through which the breather chamber communicates with the transmission case-side space.
摘要:
A process for preparing carnitine which comprises asymmetrically hydrogenating a .gamma.-halogeno-.beta.-keto ester represented by formula (I): ##STR1## wherein X represents a chlorine atom or a bromine atom; and R represents a lower alkyl group, in the presence of a ruthenium-optically active phosphine complex represented by formula (II), (III) or (IV):Ru.sub.2 Cl.sub.4 (L).sub.2 (C.sub.2 H.sub.5).sub.3 N (II)Ru(OCOR.sup.2).sub.2 (L) (IV)RuX.sub.2 (L) (V)wherein L represents 2,2'-bis(di-p-R.sup.1 -phenylphosphino)- 1,1'-binaphthyl of formula (III): ##STR2## wherein R.sup.1 represents a hydrogen atom, a methyl group, or a t-butyl group;R.sup.2 represents a lower alkyl group or a trifluoromethyl group; and X is as defined above,as a catalyst at a temperature of from 70.degree. to 150.degree. C. to obtain an optically active alcohol represented by formula (VI): ##STR3## wherein X and R are as defined above, and then reacting the optically active alcohol as obtained with trimethylamine without isolation, is disclosed.