公开(公告)号：US4695484A

公开(公告)日：1987-09-22

申请号：US805520

申请日：1985-12-06

申请人： Teruo Tanaka ,  Teruya Tanaka ,  Masato Kitamura

发明人： Teruo Tanaka ,  Teruya Tanaka ,  Masato Kitamura

IPC分类号： D06M16/00 ,  C08J9/26 ,  C08J9/28 ,  D06N7/00 ,  D06N7/02 ,  D06N7/04 ,  B05D3/02 ,  B05D3/10 ,  B05D5/00

CPC分类号： D06N3/128 ,  D06N3/02 ,  D06N3/047 ,  D06N2209/128 ,  D06N2209/1621

摘要： A moisture-permeable waterproof coating is formed by coating a fabric with a water-based coating composition containing a film forming polymer and a water-soluble polymer in a proportion of 5 to 70% based on total solids, drying or heating the fabric to form a film thereon; and then treating the resulting film with an aqueous solution of an enzyme which selectively degrades the water-soluble polymer, thereby enzymatically degrading the water-soluble polymer and extracting the degraded water soluble polymer from the film, whereby the film on the fabric is rendered microporous.

摘要翻译： 通过用基于总固体的5-70％的比例包含成膜聚合物和水溶性聚合物的水性涂料组合物涂布织物形成透湿防水涂料，干燥或加热织物以形成 一层薄膜; 然后用选择性降解水溶性聚合物的酶的水溶液处理所得膜，从而使水溶性聚合物酶降解并从膜中提取降解的水溶性聚合物，由此使织物上的膜变成微孔 。

公开(公告)号：US20050203273A1

公开(公告)日：2005-09-15

申请号：US11074763

申请日：2005-03-09

申请人： Masato Kitamura ,  Keiji Nakano

发明人： Masato Kitamura ,  Keiji Nakano

IPC分类号： C07D241/38 ,  C07D241/46 ,  C07F1/08 ,  C07F15/04 ,  C08G79/00 ,  C08G61/00

CPC分类号： C08G79/00

摘要： A one-dimensional coordination polymer having a linear structure and represented by general formula (I) given below: where M denotes copper or nickel, X denotes a halogen atom, R denotes a pyrazine derivative represented by general formula (II) given below, and n is an integer: where each of Z1 and Z2, which may be the same or different, denotes an atomic group required for forming a carbon ring by joining with a methylene chain the carbon atoms in the 2-position and 3-position or the carbon atoms in the 5-position and 6-position of the pyrazine ring, and * denotes the binding position with M included in general formula (I).

摘要翻译： 具有线性结构并由下式给出的通式（I）表示的一维配位聚合物：其中M表示铜或镍，X表示卤素原子，R表示下述通式（II）表示的吡嗪衍生物，和 n是整数，其中Z 1和Z 2各自可以相同或不同，表示通过与一个或多个碳原子连接形成碳环所需的原子团 亚甲基链是吡嗪环的2-位和3-位的碳原子或5-位和6-位的碳原子，*表示与通式（I）中包含的M的结合位置。

公开(公告)号：US09346740B2

公开(公告)日：2016-05-24

申请号：US14237497

申请日：2012-08-29

申请人： Yoshitaka Ishibashi ,  Naoya Fukumoto ,  Masato Kitamura

发明人： Yoshitaka Ishibashi ,  Naoya Fukumoto ,  Masato Kitamura

IPC分类号： C07C209/60 ,  C07C209/14 ,  C07C209/22 ,  C07D295/03

CPC分类号： C07C209/60 ,  C07C209/14 ,  C07C209/22 ,  C07D295/03 ,  C07C211/21 ,  C07C211/25

摘要： Provided is a method for producing a 2-alkenylamine compound efficiently and at low cost, using a primary or secondary amine compound and a 2-alkenyl compound as the starting materials therefor. The 2-alkenyleamine compound is produced by 2-alkenylating a primary or secondary amine compound, using a specified 2-alkenylating agent and in the presence of a catalyst comprising a complexing agent and a transition metal precursor stabilized by a monovalent anionic five-membered conjugated diene.

摘要翻译： 提供了使用伯或仲胺化合物和2-链烯基化合物作为起始原料有效且低成本地制备2-链烯基胺化合物的方法。 2-链烯基醇化合物是通过使用特定的2-链烯基化试剂在含有络合剂和过渡金属前体的催化剂存在下，通过2-烷基化伯胺或仲胺化合物而产生的，所述催化剂通过一价阴离子五元共轭 二烯。

公开(公告)号：US20140171687A1

公开(公告)日：2014-06-19

申请号：US14237758

申请日：2012-08-29

申请人： Yoshitaka Ishibashi ,  Naoya Fukumoto ,  Masato Kitamura

发明人： Yoshitaka Ishibashi ,  Naoya Fukumoto ,  Masato Kitamura

IPC分类号： C07C209/68

CPC分类号： C07C209/68 ,  B01J31/2217 ,  B01J2231/341 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/827 ,  C07C209/16 ,  C07C209/18 ,  C07C211/48 ,  C07C211/27

摘要： Provided is a method for producing a 2-alkenylamine compound efficiently and at low cost, using a primary or secondary amine compound and a 2-alkenyl compound as the starting materials therefor. The 2-alkenylamine compound is produced by adding Bronsted acid when 2-alkenylating by reacting the primary or secondary amine compound with the 2-alkenyl compound, and 2-alkenylating in the presence of a catalyst comprising a complexing agent and a transition metal precursor stabilized by a monovalent anionic five-membered conjugated diene.

摘要翻译： 提供了使用伯或仲胺化合物和2-链烯基化合物作为起始原料有效且低成本地制备2-链烯基胺化合物的方法。 2-链烯基胺化合物是通过在2-烷基化反应中通过使伯胺或仲胺化合物与2-烯基化合物反应而加入布朗斯台德酸而制备的，并且在包含络合剂和过渡金属前体稳定的催化剂存在下进行2-链烯基化 通过一价阴离子五元共轭二烯。

公开(公告)号：US08015898B2

公开(公告)日：2011-09-13

申请号：US11763121

申请日：2007-06-14

申请人： Masato Kitamura

发明人： Masato Kitamura

IPC分类号： F16H57/02 ,  F16H57/04 ,  F16H61/00 ,  F01M11/08

CPC分类号： F16H57/027 ,  F16H57/04 ,  F16H2057/02013 ,  Y10T74/2186 ,  Y10T74/2189

摘要： An air breather structure for an automatic transmission. The structure includes a transmission case housing a power train accommodating a plurality of friction engagement devices, and an extension case housing a rotational member. The extension case and the transmission case are united with each other to constitute an automatic transmission housing. A breather chamber is located upside the automatic transmission housing in a state where the automatic transmission is mounted in a vehicle, and formed with an air vent for communication with outside air. An end wall is provided for partitioning the transmission case and the extension case therebetween to define a transmission case-side space and an extension case-side space. In this structure, the automatic transmission housing is formed with a transmission case-side communication passage through which the breather chamber communicates with the transmission case-side space, and an extension case-side communication passage through which the breather chamber communicates with the transmission case-side space.

摘要翻译： 用于自动变速器的通气结构。 该结构包括容纳容纳多个摩擦接合装置的动力传动系的变速箱和容纳旋转构件的延伸壳体。 延伸壳体和变速器壳体相互组合以构成自动变速器壳体。 在自动变速器安装在车辆中的状态下，通气室位于自动变速器壳体的上方，并且形成有用于与外部空气通信的排气口。 设置有用于将变速器壳体和延伸壳体分隔开的端壁，以限定变速箱侧空间和扩展箱侧空间。 在这种结构中，自动变速器壳体形成有变速箱侧连通通道，通气室与变速器箱侧空间连通，以及延伸壳体侧连通通道，通气室与变速箱连通 边空间。

公开(公告)号：US09440907B2

公开(公告)日：2016-09-13

申请号：US14237758

申请日：2012-08-29

申请人： Yoshitaka Ishibashi ,  Naoya Fukumoto ,  Masato Kitamura

发明人： Yoshitaka Ishibashi ,  Naoya Fukumoto ,  Masato Kitamura

IPC分类号： C07C209/68 ,  C07C209/16 ,  C07C209/18 ,  B01J31/22

CPC分类号： C07C209/68 ,  B01J31/2217 ,  B01J2231/341 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/827 ,  C07C209/16 ,  C07C209/18 ,  C07C211/48 ,  C07C211/27

摘要： Provided is a method for producing a 2-alkenylamine compound efficiently and at low cost, using a primary or secondary amine compound and a 2-alkenyl compound as the starting materials therefor. The 2-alkenylamine compound is produced by adding Bronsted acid when 2-alkenylating by reacting the primary or secondary amine compound with the 2-alkenyl compound, and 2-alkenylating in the presence of a catalyst comprising a complexing agent and a transition metal precursor stabilized by a monovalent anionic five-membered conjugated diene.

摘要翻译： 提供了使用伯或仲胺化合物和2-链烯基化合物作为起始原料有效且低成本地制备2-链烯基胺化合物的方法。 2-链烯基胺化合物是通过在2-烷基化反应中通过使伯胺或仲胺化合物与2-烯基化合物反应而加入布朗斯台德酸而制备的，并且在包含络合剂和过渡金属前体稳定的催化剂存在下进行2-链烯基化 通过一价阴离子五元共轭二烯。

公开(公告)号：US06520203B2

公开(公告)日：2003-02-18

申请号：US09800468

申请日：2001-03-08

申请人： Masato Kitamura ,  Toshiaki Noda ,  Masumi Katsuki ,  Hideko Natsume

发明人： Masato Kitamura ,  Toshiaki Noda ,  Masumi Katsuki ,  Hideko Natsume

IPC分类号： F16K322

CPC分类号： F16K11/083 ,  Y10T137/4259 ,  Y10T137/86083 ,  Y10T137/86646 ,  Y10T137/86871

摘要： The evacuation and inert gas introduction apparatus capable of quickly switching over between the evacuation state and the inert gas introduction state, is provided for a synthesizing device for molecular asymmetrical catalysts. The evacuation line is connected to a vacuum pump via a cock and solvent trap. The inert gas introduction line is connected to an argon gas cylinder via a cock. The vacuum cavity is provided at a tip end of the housing of the three-way cock, and thus the inside plug is attracted towards the vacuum cavity. The evacuation line is connected to the first port of the three-way cock, the inert gas introduction line is connected to the second port and the each reaction chamber of the synthesizing apparatus is connected to the third port. As the rotation angle of the inside plug is changed, the connection state of the line is switched.

公开(公告)号：US06326512B1

公开(公告)日：2001-12-04

申请号：US09584747

申请日：2000-06-01

申请人： Masato Kitamura ,  Masahiro Yoshimura ,  Naoki Kanda ,  Ryoji Noyori

发明人： Masato Kitamura ,  Masahiro Yoshimura ,  Naoki Kanda ,  Ryoji Noyori

IPC分类号： C07C30900

CPC分类号： C07C303/22 ,  C07C303/32 ,  C07C309/24

摘要： Disclosed is a method of producing an optically active &bgr;-hydroxy sulfonic acid compound comprising hydrogenating a &bgr;-keto sulfonic acid compound represented by formula 1: where R1 represents an alkyl or a phenyl group, which may be substituted, and R2 represents sodium or an alkyl group, in an acidic solvent, in the presence of an asymmetric catalyst comprising a complex of bivalent Ru, having 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl as a ligand, to produce a compound represented by formula 2: where R1 and R2 are as defined above, and * designates an asymmetric carbon atom.

摘要翻译： 公开了一种制备光学活性β-羟基磺酸化合物的方法，包括氢化由式1表示的β-酮磺酸化合物：其中R 1表示可被取代的烷基或苯基，R 2表示钠或 烷基，在酸性溶剂中，在包含具有2,2'-双（二苯基膦基）-1,1'-联萘作为配体的二价Ru的络合物的不对称催化剂的存在下，制备由式 2：其中R1和R2如上所定义，*表示不对称碳原子。

公开(公告)号：US5532402A

公开(公告)日：1996-07-02

申请号：US402654

申请日：1995-03-13

申请人： Ryoji Noyori ,  Masato Kitamura ,  Makoto Tokunaga

发明人： Ryoji Noyori ,  Masato Kitamura ,  Makoto Tokunaga

IPC分类号： B01J31/24 ,  C07B53/00 ,  C07B61/00 ,  C07F9/40

CPC分类号： C07F9/4006

摘要： Disclosed herein is a process for producing an optically active hydroxyalkylphosphonate represented by the formula (4), which comprises asymmetrically hydrogenating an oxoalkylphosphonate represented by the formula (1) using, as a catalyst, a ruthenium-optically active phosphine complex represented by the formula (2). ##STR1##

摘要翻译： 本文公开了一种制备由式（4）表示的光学活性羟烷基膦酸酯的方法，其包括使用由式（4）表示的钌光学活性膦配合物作为催化剂不对称地氢化由式（1）表示的氧代烷基膦酸酯， 2）。 + TR

公开(公告)号：US4851537A

公开(公告)日：1989-07-25

申请号：US38571

申请日：1987-04-15

申请人： Ryoji Noyori ,  Masato Kitamura ,  Hidemasa Takaya ,  Hidenori Kumobayashi ,  Susumu Akutagawa

发明人： Ryoji Noyori ,  Masato Kitamura ,  Hidemasa Takaya ,  Hidenori Kumobayashi ,  Susumu Akutagawa

IPC分类号： C07B61/00 ,  B01J31/00 ,  B01J31/24 ,  C07D217/06 ,  C07D217/20

CPC分类号： C07D217/06 ,  C07D217/20

摘要： A process for preparing an N-acyltetrahydroisoquinoline represented by formula (II) ##STR1## wherein A represents a phenylene ring substituted with a hydroxyl group, a lower alkoxy group, an acetoxy group, or a benzyloxy group; R represents a hydrogen atom, a lower alkyl group, or a phenyl group; and X represents a hydrogen atoms, a phenyl group, or a phenyl group substituted with a hydroxyl group, a lower alkoxy group, or an acetoxy group, which comprises asymmetrically hydrogenating an N-acyl-1-methylenetetrahydroisoquinoline or N-acyl-1-benzylidenetetrahydroisoquinoline represented by formula (I) ##STR2## wherein A, R, and X are as defined above, in the presence of an optically active ruthenium-phosphine complex as a catalyst. The process exclusively and efficiently provides a useful isomer of the N-acyltetrahydroisoquinoline of high purity which is useful as an intermediate for synthesizing isoquinoline type alkaloids as pharmaceuticals without involving optical resolution of a racemate.

摘要翻译： 制备由式（II）表示的N-酰基四氢异喹啉的方法其中A表示被羟基，低级烷氧基，乙酰氧基或苄氧基取代的亚苯基环; R表示氢原子，低级烷基或苯基; X表示氢原子，苯基或被羟基，低级烷氧基或乙酰氧基取代的苯基，其包括不对称地氢化N-酰基-1-亚甲基四氢异喹啉或N-酰基-1- 由式（I）表示的亚苄基四氢异喹啉，其中A，R和X如上所定义，在光学活性钌 - 膦配合物作为催化剂存在下进行。 该方法专门有效地提供了高纯度的N-酰基四氢异喹啉的有用异构体，其可用作合成异喹啉类生物碱作为药物而不涉及外消旋物的光学拆分的中间体。