Abstract:
The present disclosure provides and article. The article includes: (A) a polyester fabric; (B) a coating on a surface of the polyester fabric, the coating comprising at least one of (i) an ethylene/vinyl acetate/maleic anhydride terpolymer and (ii) an ethylene/methyl acrylate/glycidyl methacrylate terpolymer.
Abstract:
A functionalized carbon fiber having covalently bound on its surface a sizing agent containing epoxy groups, at least some of which are engaged in covalent bonds with crosslinking molecules, wherein each of said crosslinking molecules possesses at least two epoxy-reactive groups and at least one free functional group reactive with functional groups of a polymer matrix in which the carbon fiber is to be incorporated, wherein at least a portion of said cros slinking molecules are engaged, via at least two of their epoxy-reactive groups, in crosslinking bonds between at least two epoxy groups of the sizing agent. Composites comprised of these functionalized carbon fibers embedded in a polymeric matrix are also described. Methods for producing the functionalized carbon fibers and composites thereof are also described.
Abstract:
In accordance with one aspect, a material for energy management and peak energy reduction in a building structure, comprises an insulative base material, a first phase change material, and a functional polymeric phase change material that dynamically absorbs and releases heat to adjust heat transfer at or within a temperature stabilizing range. The functional polymeric phase change material has at least one phase change temperature in the range between −10° C. and 100° C. and a phase change enthalpy of at least 5 Joules per gram, the functional polymeric phase change material including a plurality of polymer chains that include a backbone chain and a plurality of side chains, wherein a first portion of the plurality of polymer chains are crosslinked to each other, wherein a second portion of the plurality of polymer chains are crosslinked with the first phase change material and a third portion of the plurality of side chains are mechanically entangled with the inorganic insulative base material.
Abstract:
A functionalized carbon fiber having covalently bound on its surface a sizing agent containing epoxy groups, at least some of which are engaged in covalent bonds with crosslinking molecules, wherein each of said crosslinking molecules possesses at least two epoxy-reactive groups and at least one free functional group reactive with functional groups of a polymer matrix in which the carbon fiber is to be incorporated, wherein at least a portion of said crosslinking molecules are engaged, via at least two of their epoxy-reactive groups, in crosslinking bonds between at least two epoxy groups of the sizing agent. Composites comprised of these functionalized carbon fibers embedded in a polymeric matrix are also described. Methods for producing the functionalized carbon fibers and composites thereof are also described.
Abstract:
A method of producing a temperature regulating article is disclosed. The method includes combining a functional polymeric phase change material with a substrate. The functional polymeric PCM has the capability of absorbing or releasing heat to adjust heat transfer at or within a temperature stabilizing range and having at least one phase change temperature in the range between −10° C. and 100° C. and a phase change enthalpy of at least 5 Joules per gram, the functional polymeric PCM has a backbone chain, side chains, and a crystallizable section. The side chains form the crystallizable section. The functional PCM carries at least one reactive function on at least one of the side chains or the backbone chain. The reactive function is capable of forming at least a first covalent bond with the second material or with a connecting compound capable of reacting with reactive functions of the second material.
Abstract:
A method is provided for functionalizing nanoscale fibers including reacting a plurality of nanoscale fibers with at least one epoxide monomer to chemically bond the at least one epoxide monomer to surfaces of the nanoscale fibers to form functionalized nanoscale fibers. Functionalized nanoscale fibers, nanoscale fiber films, and composite materials are also provided.
Abstract:
A fabric that contains a blend of textile and polyarylene sulfide fibers is provided. At least a portion of the textile fibers, polyarylene sulfide fibers, or a combination thereof are coated with an emulsion copolymer that is crosslinked. The copolymer composition is cured after it is applied to the fibers to initiate the formation of crosslink bonds between the emulsion copolymer and create a three-dimensional network that is capable of coating and encapsulating the fibers. It is believed that this three-dimensional network is able to physically entrap disperse additives when applied to the fibers. Still further, the present inventors have discovered that the emulsion copolymer can uniformly coat the fibers and thus readily receive the additive, which eliminates the need for high temperatures and/or pressures during a dyeing process, for example, and can also result in a relatively uniform coating of the additive on the fibers.
Abstract:
In accordance with one aspect, a thermally regulating construction material comprises a base material and a polymeric phase change material bound to the base material, wherein the base material provides reversible temperature regulation properties to the building construction material. In accordance with another aspect, an insulation material for use in building construction comprises a base material and a polymeric phase change material bound to the base material, wherein the base material provides reversible temperature regulation properties to the insulation material. The base material may be selected from the group consisting of foam insulation, loose fill insulation, and batted insulation.
Abstract:
Disclosed is a process for modification of a substrate so as to form an ultrahydrophobic surface on the substrate. Also disclosed are surface-modified substrates that can be formed according to the disclosed processes. The process includes attachment of a multitude of nano- and/or submicron-sized structures to a surface to provide increased surface roughness. In addition, the process includes grafting a hydrophobic material to the surface in order to decrease the surface energy and decrease wettability of the surface. The combination of increase surface roughness and decreased surface energy can provide an ultrahydrophobic surface on the treated substrate.
Abstract:
To provide an antifouling composition which is an fluorine-type antifouling composition using a short chain perfluoroalkyl group and which can be made in the form of an aqueous dispersion containing substantially no volatile organic solvent and has excellent soil release properties.An antifouling composition comprising a fluorocopolymer which comprises from 30 to 70 mass % of polymerized units (a′) having a C1-6 perfluoroalkyl group, from 20 to 69 mass % of polymerized units (b′) having an alkylene oxide chain and from 1 to 10 mass % of polymerized units (c′) having an amino group, and which has anionic groups at its main chain terminals.