Abstract:
The present invention provides methods for reducing extractables from plastic articles and improving barrier properties of such plastic articles. The method includes the steps of: (a) providing a plastic article in a chamber; and (b) providing a fluorination gas and a second gas, such as oxygen or another halogen other than fluorine, in a chamber, thereby exposing the plastic article to the fluorination gas and the second gas. The method produces a treated plastic article that is both low in extractable components and suitable for use in packaging formulations containing an organic ingredient.
Abstract:
The present invention relates to an iminodiacetic acid chelating resin, wherein the water amount in the resin is from 50 to 75% and the volume ratio of Na form/H form is from 1.4 to 1.8. Furthermore, the present invention relates to a method for producing an iminodiacetic acid chelating resin, wherein an alcohol is used as a solvent for the amination reaction of a chloromethylated styrene crosslinked copolymer with iminodiacetonitrile or sodium iodide and/or potassium iodide is used as a catalyst for the amination reaction.
Abstract:
The present invention provides an optical member comprising a silicone material having excellent antifouling property while having good light transmittance, heat resistance, and strength, and an optical semiconductor device and illumination apparatus having excellent antifouling property. The present invention is an optical member comprising a silicone material containing a fluorinated surface, the proportion of F atoms being from 0.1 to 45 at % and/or the ratio of F atoms relative to C atoms being from 0.01 to 1.00 in the atomic composition percentage according to X-ray photoelectron spectroscopy (XPS) of the fluorinated surface.
Abstract:
This invention relates to an elastomeric article with improved lubricity and donnablity and reduced stickiness/tackiness. According to the methods of the invention, the internal surface of the elastomeric article is coated with a polyisoprene coating. The coating of the invention is formed from synthetic polyisoprene rubber that may or may not contain minor amounts of other components. The coating is preferably directly bonded to the underlying elastomeric article.
Abstract:
Article based on an elastomeric composition (C) comprising a crosslinked blend (B) of at least: (1) one substantially saturated synthetic elastomer; and (2) a copolymer containing repeating units derived from at least one conjugated diene and at least one α,β-unsaturated nitrile, the article having been subjected to a surface halogenation treatment.
Abstract:
A method for the improvement of the barrier properties of ethylene homo- or copolymer compositions against permeation of hydrocarbons comprised in liquid fuels or mineral oils is disclosed. The ethylene homo- or copolymer comprises at least one sterically hindered amine compound in an amount of from 100 to 10 000 ppm, calculated on total weight of the polymer. At least one surface of a hollow body made of said ethylene homo- or copolymer is subjected to fluorination.
Abstract:
This invention relates to an elastomeric article with improved lubricity and donnablity and reduced stickiness/tackiness. According to the methods of the invention, the internal surface of the elastomeric article is coated with a polyisoprene coating. The coating of the invention is formed from synthetic polyisoprene rubber that may or may not contain minor amounts of other components. The coating is preferably directly bonded to the underlying elastomeric article.
Abstract:
Hollow body made of plastic having a fluorinated inner surface according to the present invention is characterized in that in one or more defined regions of the inner surface, the fluorine occupancy deviates from the mean fluorine occupancy by at least ±10%.Furthermore, a method for the production of a hollow body made of plastic having a fluorinated inner surface is presented, in which, for the formation of fluorocarbon and hydrofluorocarbon compounds, the inner surface is exposed to the action of a defined amount of a fluorine-containing treatment gas and the hollow body is thermostatted on its outside so that the temperature in one or more defined regions of the outside is at least ±2° C. above/below the mean temperature of the outside.
Abstract:
The present invention refers to medical devices comprising fluorinated polymers, especially to tubings, used for constructing catheters like balloon catheters, delivery catheters or guide catheters.
Abstract:
The gas-phase fluorination of plastic articles is effected in a reaction chamber 1 into which the plastic articles to be fluorinated are introduced. The gas-phase fluorination is effected at normal or atmospheric ambient pressure of about 1 kPa in the reaction chamber. The gas-phase fluorination can be carried out statically or dynamically. The flushing carried out before the gas-phase fluorination for complete or partial removal of atmospheric oxygen from the reaction chamber 1 can also be effected at atmospheric pressure in the reaction chamber. The reaction chamber 1 is equipped with a cover 2 and metering valves V0, V1, V2 for air, inert gas and gas mixture comprising fluorine and one or more inert gases are present on the entrance side of the reaction chamber, which is not vacuum-tight and hence also cannot be evacuated. The metering valves are connected to the reaction chamber 1 via a flow meter 4. A release valve V3 and a flow-through/shut-off valve V4 are arranged in an exhaust gas line 8 of the reaction chamber 1.