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    Blends of quinone alkide and nitroxyl compounds as polymerization inhibitors
    2.
    发明授权
    Blends of quinone alkide and nitroxyl compounds as polymerization inhibitors 失效
    醌类和硝酰基化合物的共混物作为聚合抑制剂

    公开(公告)号：US07473795B2

    公开(公告)日：2009-01-06

    申请号：US11370691

    申请日：2006-03-07

    申请人： Brigitte Benage

    发明人： Brigitte Benage

    IPC分类号： C07C69/00

    CPC分类号： C09K15/30 ,  C07B63/04 ,  C07C7/20 ,  C07C17/42 ,  C07C59/82 ,  C07C67/62 ,  C08F4/40 ,  C09K15/08 ,  G03F7/027 ,  C07C21/21 ,  C07C69/54

    摘要： Disclosed herein is a method for inhibiting the premature polymerization of ethylenically unsaturated monomers comprising adding to said monomers an effective amount of: A) at least one nitroxyl compound, and B) at least one quinone alkide compound having an electron-withdrawing group at the 7-position. Additionally, a composition is disclosed that comprises: A) at least one nitroxyl compound, and B) at least one quinone alkide compound having an electron-withdrawing group at the 7-position.

    摘要翻译： 本文公开了一种抑制烯键式不饱和单体的过早聚合的方法，其包括向所述单体中加入有效量的：A）至少一种硝酰化合物，和B）在7位具有吸电子基团的至少一种醌化合物 -位置。 此外，公开了一种组合物，其包含：A）至少一种硝酰化合物，和B）至少一种在7-位具有吸电子基团的醌类化合物。

    Bioprocess for the high-yield production of food flavor-acceptable jasmonic acid and methyl jasmonate, novel jasmonic acid isomer produced thereby and uses thereof
    3.
    发明授权
    Bioprocess for the high-yield production of food flavor-acceptable jasmonic acid and methyl jasmonate, novel jasmonic acid isomer produced thereby and uses thereof 有权
    用于高产量生产食品香料可接受的茉莉酸和茉莉酸甲酯的生物工艺，由此产生的新颖茉莉酸异构体及其用途

    公开(公告)号：US06458569B1

    公开(公告)日：2002-10-01

    申请号：US09935320

    申请日：2001-08-22

    申请人： Mohamad I. Farbood ,  Robert W. Blocker ,  Lynda B. McLean ,  Mark A. Sprecker ,  Michael P. McLean ,  Nicolas Kossiakoff ,  Augustine Yonghwi Kim ,  Myrna Hagedorn

    发明人： Mohamad I. Farbood ,  Robert W. Blocker ,  Lynda B. McLean ,  Mark A. Sprecker ,  Michael P. McLean ,  Nicolas Kossiakoff ,  Augustine Yonghwi Kim ,  Myrna Hagedorn

    IPC分类号： C12P1702

    CPC分类号： C07C69/738 ,  A23L27/203 ,  A23L27/24 ,  A24B15/34 ,  C07C59/82 ,  C07C2601/08 ,  C11B9/003 ,  C12N1/14 ,  C12P7/40 ,  C12P7/62

    摘要： Described is a bioprocess for the high-yield production of food flavor-acceptable jasmonic acid and methyl jasmonate, as well as a novel jasmonic acid isomer produced thereby and organoleptic uses thereof. The process yields at least 5% of the “cis” isomer defined according the structure: (wherein R is hydrogen or methyl) or at least 5% of the “cis” isomer defined according to the structure: (wherein R is hydrogen or methyl). Compositions containing at least 98% of the isomer having the structure: with an optical rotation (&agr;D20) of +58° are novel. Compositions containing at least 98% of the isomer having the structure: with an optical rotation (&agr;D20) of +58° are also novel. The process of our invention comprises the cultivation under aerobic condition of one or more specific strain of Diplodia gossypina in a nutrient medium followed either by (1) isolation of the jasmonic acid product or (2) esterification of the jasmonic acid to form methyl jasmonate followed by the isolation of the methyl jasmonate and novel products produced by such process.

    摘要翻译： 描述了用于高产量生产食用香料可接受的茉莉酸和茉莉酮酸甲酯的生物过程，以及由此产生的新型茉莉酸异构体及其感官应用。 该方法得到根据以下结构定义的至少5％的“顺式”异构体：（其中R是氢或甲基）或根据以下结构定义的至少5％的“顺式”异构体：（其中R是氢或甲基 ）。 含有至少98％具有以下结构的异构体的组合物：具有+ 58°的旋光度（αD20）是新颖的。 含有至少98％具有以下结构的异构体的组合物：具有+ 58°的旋光度（αD20）也是新颖的。 本发明的方法包括在营养培养基中培养一种或多种特异性棉花Diplodia gossypina菌株的好氧条件，然后通过（1）分离茉莉酸产物或（2）茉莉酸酯化形成茉莉酸甲酯，随后 通过分离这种方法生产的茉莉酸甲酯和新产品。

    Polyhydrophenanthrene diols
    9.
    发明授权
    Polyhydrophenanthrene diols 失效
    聚二氢菲二醇

    公开(公告)号：US3922312A

    公开(公告)日：1975-11-25

    申请号：US39362373

    申请日：1973-08-31

    申请人： STERLING DRUG INC

    发明人： SHAW PHILIP E ,  DAUM SOL J ,  CLARKE ROBERT L

    IPC分类号： C07C59/40 ,  C07C59/46 ,  C07C59/56 ,  C07C59/72 ,  C07C59/82 ,  C07C59/90 ,  C07C35/42

    CPC分类号： C07C59/56 ,  C07C59/40 ,  C07C59/46 ,  C07C59/72 ,  C07C59/82 ,  C07C59/90 ,  C07C2603/26

    摘要： Alkyl polyhydro-2-phenanthrylideneacetates are prepared by interacting the corresponding 2-oxopolyhydrophenanthrenes with a tri-lower-alkyl Alpha -phosphono-lower-alkanoate. Said alkyl polyhydro-2-phenanthrylideneacetates are hydrolyzed to the free acid, and then reesterified via the acid chloride with a tertiary-amino-lower-alkanol to give basic esters having cardiotonic activity.

    摘要翻译： 烷基多​​羟基-2-菲基亚丙基乙酸酯是通过将相应的2-氧代多羟基苯醚与α-低级烷基α-膦酰基低级链烷酸酯相互作用来制备的。 所述烷基多氢-2-菲基亚丙基乙酸酯水解成游离酸，然后通过酰氯与叔氨基 - 低级链烷醇进行再酯化，得到具有强心活性的碱性酯。