DEVICE AND METHOD FOR RADIALLY STRENGTHENING POLYLACTIC ACID TUBE

    公开(公告)号:US20230150213A1

    公开(公告)日:2023-05-18

    申请号:US18093408

    申请日:2023-01-05

    CPC classification number: B29C71/0072 B29C71/02 B29C2071/027 B29K2067/046

    Abstract: A device is provided for radially strengthening a polylactic acid tube, which includes a tubular mold, a rotating blade and a distal blade, wherein a rotating shaft of the rotating blade is arranged at an axial position of the tubular mold, a first end of the distal blade is movably connected to the rotating blade, and a second end of the distal blade is controlled by a control rod so as to open and close the distal blade. A strengthening method is provided, in which the device for radially strengthening a polylactic acid tube is used. The method includes loading a polylactic acid tube to be strengthened into the strengthening device, heating the strengthening device for a first preset time, rotating the rotating blade in a constant direction while opening the distal blade at a first speed such that the second end of the distal blade approaches the tubular mold, closing the distal blade and restoring the distal blade to an initial state after squeezing and scraping for a second preset time, cooling the strengthening device to room temperature, taking out a strengthened polylactic acid tube, and cutting off redundant sections. The tube strengthened by the above-mentioned strengthening device and method has a better wall thickness uniformity, more precise inner and outer diameter dimensions, with no axial orientation, and no thermal creep in a low temperature range such as body temperature, etc.

    Polymer material and method for producing same
    3.
    发明授权
    Polymer material and method for producing same 有权
    聚合物材料及其制造方法

    公开(公告)号:US08796413B2

    公开(公告)日:2014-08-05

    申请号:US13818553

    申请日:2011-08-04

    Abstract: Provided are a method for producing a polymer material having a high degree of crystallization, a small variability in degree of crystallization, and a three-dimensionally isotropic crystallinity to thus give high thermal resistance, high isotropy of resin physical properties, and a small variability in resin physical properties; and the polymer material. The method for producing a polymer material includes the steps of: heating a thermoplastic resin to or above a melting point determined from a melting peak measured by DSC into a thermoplastic resin melt; applying a pressure higher than atmospheric pressure to the thermoplastic resin melt; starting cooling the thermoplastic resin melt with a pressure higher than atmospheric pressure applied thereto; releasing the pressure on the thermoplastic resin melt after cooling the thermoplastic resin melt to a cooling-end-temperature lower than an upper limit of a crystallization temperature range, wherein during the cooling, the pressure on the thermoplastic resin melt is maintained at the pressure higher than atmospheric pressure or raised. The polymer material is one obtained by the above production method.

    Abstract translation: 本发明提供了具有高结晶度,结晶度变化小,三维各向同性结晶性的高分子材料的制造方法,从而得到高耐热性,树脂物性的各向异性高,变异性小 树脂物理性能; 和聚合物材料。 聚合物材料的制造方法包括以下步骤:将热塑性树脂加热到由DSC测定的熔融峰值确定的熔点以上的热塑性树脂熔融体; 将高于大气压的压力施加到热塑性树脂熔体; 以高于大气压的压力开始冷却热塑性树脂熔体; 在将热塑性树脂熔体冷却至低于结晶温度范围的上限的冷却终止温度之后,释放热塑性树脂熔体上的压力,其中在冷却期间,热塑性树脂熔体上的压力保持在更高的压力 比大气压或升高。 聚合物材料是通过上述制备方法得到的。

    Chemically and electrically stabilized polymer films
    9.
    发明授权
    Chemically and electrically stabilized polymer films 有权
    化学和电化学稳定的聚合物薄膜

    公开(公告)号:US06881447B2

    公开(公告)日:2005-04-19

    申请号:US10116724

    申请日:2002-04-04

    Abstract: Preparation methods and stabilization processes for low k polymers that consist of sp2C—X and HC-sp3Cα—X bonds. A preparation method is achieved by controlling the substrate temperature and feed rate of the polymer precursors. One stabilization process includes a post annealing of as-deposited polymer films under the presence of hydrogen under high temperatures. The reductive annealing of these films is conducted at temperatures from −20° C. to −50° C. to +20° C. to +50° C. of their Reversible Crystal Transformation (“CRT”) temperatures, then quenching the resulting films to −20° C. to −50° C. below their “CRT” temperatures. The reductive annealing is conducted before the as-deposited film was removed from a deposition system and still under the vacuum. “Re-stabilization” processes of polymer surfaces that are exposed to reactive plasma etching are also disclosed; thus, further coating by barrier metal, cap layer or etch-stop layer can be safely applied.

    Abstract translation: 由k-S-X和HC-sp-3-α-X键组成的低k聚合物的制备方法和稳定化方法。 通过控制聚合物前体的基板温度和进料速率来实现制备方法。 一种稳定化方法包括在氢气存在下在高温下对沉积的聚合物膜进行后退火。 这些膜的还原退火在其可逆晶体转变(“CRT”)温度的-20℃至-50℃至+ 20℃至+ 50℃的温度下进行,然后淬灭所得 在-20℃至-50℃的温度下低于它们的“CRT”温度。 还原退火在沉积膜从沉积系统中移除之前仍然在真空下进行。 还公开了暴露于反应性等离子体蚀刻的聚合物表面的“再稳定化”工艺; 因此,可以安全地施加通过阻挡金属,盖层或蚀刻停止层的进一步涂覆。

Patent Agency Ranking