摘要:
The aim of the invention is to provide particles or coatings for splitting water, which are largely protected from corrosive damage. To this end, the particles or the coating consist(s) of a nucleus or a sub-layer and a shell or top layer, the nucleus or the sub-layer forming a reactive unit and consisting of a material which, on input of energy from sunlight, releases electrons capable of splitting water into hydrogen and oxygen, and the shell or top layer forming a protective unit capable of keeping the cleavage products away from the surface of the reactive unit and simultaneously having conductive fractions. Surprisingly, it has been found that corrosive damage to the reactive particles is (largely) prevented by the targeted separation of the reaction particles and the cleavage products over the kinetic range of the released electrons.
摘要:
The invention relates to a coating material having catalytic activity for reducing the combustion temperature of soot and organic substances. It also relates to the use of the coating material. In order to create a catalytically active coating material with which an abrasion-proof coating suitable also for optical applications can be produced for the combustion of soot and organic substances, it is proposed within the scope of the invention that the coating material contains at least 20 and less than 50 wt. % of compounds of subgroup metals or of elements of the third and fourth main groups, and between 10 and 80 wt. % of alkali or alkaline earth compounds, the molar proportion of alkali or alkaline earth compounds being higher than the molar proportion of compounds of subgroup metals or of elements of the third and fourth main groups. Surprisingly, the catalytic composition according to the invention permits the production of a colorless, transparent or translucent coating which also shows high abrasion resistance.
摘要:
A method for producing alkali and alkaline earth alloys. It also relates to the use of the alkali and alkaline earth compositions. In order to create a novel method for producing alkali and alkaline earth alloys, it is proposed within the context of the invention that salts, hydroxides, alkoxides or oxides of alkali or alkaline earth compounds be mixed with salts, hydroxides, alkoxides or oxides of semi-metals, nonmetals or metals and then heated to at least 100° C., the salts, hydroxides, alkoxides or oxides of alkali or alkaline earth metals being present in a molar ratio of 1:1 or in excess thereof in relation to the salts, hydroxide, alkoxides or oxides of the semi-metals, nonmetals or metal. Surprisingly, it was found within the context of the invention that by mixing salts, hydroxides, alkoxides or oxides of alkali or alkaline earth compounds with salts, hydroxides, alkoxides or oxides of semi-metals or metals from the 3rd or 4th main group and subsequent heating, alkali or alkaline earth alloys can be produced.
摘要:
The invention relates to a method for producing alkali and alkaline earth alloys. It also relates to the use of the alkali and alkaline earth compositions.In order to create a novel method for producing alkali and alkaline earth alloys, it is proposed within the context of the invention that salts, hydroxides, alkoxides or oxides of alkali or alkaline earth compounds be mixed with salts, hydroxides, alkoxides or oxides of semi-metals, nonmetals or metals and then heated to at least 100° C., the salts, hydroxides, alkoxides or oxides of alkali or alkaline earth metals being present in a molar ratio of 1:1 or in excess thereof in relation to the salts, hydroxide, alkoxides or oxides of the semi-metals, nonmetals or metals.Surprisingly, it was found within the context of the invention that by mixing salts, hydroxides, alkoxides or oxides of alkali or alkaline earth compounds with salts, hydroxides, alkoxides or oxides of semi-metals or metals from the 3rd or 4th main group and subsequent heating, alkali or alkaline earth alloys can be produced.
摘要:
Described are nanostructured molded articles and layers which are produced by a wet chemical process comprising the following steps: a) provision of a free-flowing composition containing solid nanoscaled inorganic particles having polymerizable and/or polycondensable organic surface groups; b) introduction of said composition of step a) into a mold; or b2) application of said composition of step a) onto a substrate; and c) polymerization and/or polycondensation of the surface groups of said solid particles with formation of a cured molded article or a cured layer.
摘要:
Optical components have a material-distribution gradient due to nanometer-size particles embedded in a solid matrix. The components are manufactured by forming a dispersion of nanometer-size particles in a liquid, curable matrix material, causing the particles to migrate in the matrix material on the basis of a potential difference to form a distribution gradient, and subsequently curing the matrix material, retaining the distribution gradient. The method is suitable for use in the manufacture of optical lenses with a refractive index gradient.
摘要:
A method is described for producing a microstructured surface relief by applying to a substrate a coating composition which is thixotropic or which acquires thixotropic properties by pretreatment on the substrate, embossing the surface relief into the applied thixotropic coating composition with an embossing device, and curing the coating composition following removal of the embossing device. The substrates obtainable by this method, provided with a microstructured surface relief, are particularly suitable for optical, electronic, micromechanical and/or dirt repellency applications.
摘要:
Substrates provided with a microstructured surface have a surface layer which (a) comprises a composition comprising condensates of one or more hydrolysable compounds of at least one element M from main groups III to V and/or transition groups II to IV of the Periodic Table of the Elements, at least some of these compounds containing not only hydrolysable groups A but also non-hydrolysable, carbon-containing groups B and the total molar ratio of groups A to groups B in the parent monomeric starting compounds being from 10:1 to 1:2, from 0.1 to 100 mol % of the groups B being groups B′ containing on average from 5 to 30 fluorine atoms which are attached to one or more aliphatic carbon atoms distanced from M by at least two atoms, and (b) has a microstructuring of such kind that the contact angle with respect to water or hexadecane is at least 5° higher than the contact angle of a corresponding smooth surface. The substrates provided with a microstructured surface are particularly suitable as transparent or translucent easy-to-clean systems.
摘要:
A process produces a coated metal strip from a semi-finished strip, in which the semi-finished strip is reeled off a coil. A corrosion protection layer is then applied to the semi-finished strip and the coated semi-finished strip is then reeled up to form a coil. The semi-finished strip is a cold-rolled strip obtained by cold rolling, cooling and recrystallization annealing. A medium containing metallic particles is applied to form the corrosion protection layer. The medium is a wet-chemical solution which is applied by spraying, dipping, squirting, flooding or rolling. The corrosion protection layer is dried on the cold-rolled strip by supplying heat at a temperature below the recrystallization annealing temperature of the cold-rolled strip after application of the medium and before reeling-up.
摘要:
The invention relates to a coating material for protecting metals, especially steel, from corrosion and/or scaling, to a method for coating metals and to a metal element. The aim of the invention is to provide a coating material that protects steel from corrosion and/or scaling and that can be welded after heat treatment of the coated steel at temperatures of more than 800° C. For this purpose, substances are provided that render the applied coating material suitable for welding, especially for spot welding. The coating material can be applied by wet chemical methods, it changes its structure when subjected to high temperature processes of more than 600° C. and is suitable as a primer for additional coating materials. It was surprisingly found that when a suitable binder including a suitable filler is used during the high temperature treatment of a curing process, the coating materials of the invention change in such a manner that electrically conducting reactive layers are formed that allow welding and especially spot welding together with the metal substrate even after treatment at temperatures of more than 800° C.