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1.发明申请ACTINIC ENERGY RADIATION-CURABLE ACRYLIC SILICONE RESIN COMPOSITION AND COATED ARTICLE 审中-公开能量可辐射固化丙烯酸硅树脂组合物和涂层物品公开(公告)号：US20160208132A1
公开(公告)日：2016-07-21
申请号：US14995793
申请日：2016-01-14
发明人： Kohei MASUDA , Koichi HIGUCHI
IPC分类号： C09D135/02
CPC分类号： C09D135/02 , C08F220/14 , C08G77/18 , C08K3/36 , C08K9/02 , C08K2003/2213 , C08K2003/2241 , C08K2003/2296 , C08K2201/003 , C08L83/04 , C09D4/06 , C08F2230/085 , C08F2220/325 , C08F265/06 , C08F283/122 , C08L43/04 , C08K3/22
摘要： An acrylic silicone resin composition is curable with actinic energy radiation, comprising (i) a vinyl base polymer composed of a vinyl base monomer having an alkoxysilyl group, a UV-absorbing vinyl base monomer, and a copolymerizable monomer, (ii) a hydrolytic condensate of an alkoxysilane, (iii) core/shell type tetragonal titanium oxide solid-solution microparticles, (iv) a polycarbonate and/or polyester-based urethane-modified vinyl polymer, (v) a vinyl polymerizable monomer free of alkoxysilyl, (vi) an initiator, and (vii) a solvent.
摘要翻译： 丙烯酸有机硅树脂组合物可用光化能辐射固化，包括（i）由具有烷氧基甲硅烷基的乙烯基单体，紫外线吸收乙烯基单体和可共聚单体组成的乙烯基聚合物，（ii）水解缩合物 的（iii）核/壳型四方钛氧化物固溶体微粒，（iv）聚碳酸酯和/或聚酯类氨基甲酸酯改性的乙烯基聚合物，（v）不含烷氧基硅烷的乙烯基聚合性单体，（vi） 引发剂，和（vii）溶剂。
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公开(公告)号：US20150125707A1
公开(公告)日：2015-05-07
申请号：US14529265
申请日：2014-10-31
发明人： Kohei MASUDA , Yukimasa AOKI , Koichi HIGUCHI
摘要： A coating composition is provided comprising (A) 1-50 parts by weight of surface-treated titanium oxide comprising core/shell type microparticles each consisting of a titanium oxide core and a silicon oxide shell, which are treated with two surface treating components having formula (I): R1Si(OR2)3 and formula (II): (R3R42Si)2NH, (B) 100 parts by weight of a vinyl copolymer obtained from copolymerization of (b-1) an alkoxysilyl-containing vinyl monomer, (b-2) a UV-absorbing vinyl monomer, and (b-3) another monomer, and (C) a solvent. A cured film of the composition has improved mar resistance and UV shielding while maintaining visible light transparency.
摘要翻译： 提供一种涂料组合物，其包含（A）1-50重量份的包含由氧化钛芯和氧化硅壳组成的核/壳型微粒的表面处理氧化钛，其用两种表面处理组分处理，所述表面处理组分具有式 （I）：R1Si（OR2）3和式（II）：（R3R42Si）2NH，（B）100重量份由（b-1）含烷氧基甲硅烷基的乙烯基单体共聚获得的乙烯基共聚物，（b- 2）UV吸收乙烯基单体和（b-3）另一单体，和（C）溶剂。 组合物的固化膜具有改善的耐擦伤性和紫外线屏蔽性，同时保持可见光透明度。
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3.发明申请CORE/SHELL TYPE TETRAGONAL TITANIUM OXIDE PARTICLE WATER DISPERSION, MAKING METHOD, UV-SHIELDING SILICONE COATING COMPOSITION AND COATED ARTICLE 审中-公开核心/壳型四面体氧化钛颗粒水分散体，制备方法，紫外线屏蔽硅胶涂料组合物和涂层制品公开(公告)号：US20140023855A1
公开(公告)日：2014-01-23
申请号：US13945364
申请日：2013-07-18
发明人： Kohei MASUDA , Koichi HIGUCHI , Hisatoshi KOMORI , Manabu FURUDATE , Tomohiro INOUE , Yoshitsugu EGUCHI
IPC分类号： G02B1/10
CPC分类号： G02B1/14 , B82Y30/00 , C01G23/002 , C01P2002/52 , C01P2002/72 , C01P2002/84 , C01P2004/64 , C01P2004/84 , C08J7/042 , C08J2443/04 , C08J2483/04 , C09C1/3684 , G02B1/105 , Y10T428/256
摘要： Core/shell type tetragonal titanium oxide particles consisting of a nanosized core of tetragonal titanium oxide having tin and manganese incorporated in solid solution and a shell of silicon oxide around the core are dispersed in an aqueous dispersing medium. The cores and the core/shell type titanium oxide particles have an average particle size of ≦30 nm and ≦50 nm, respectively. The amount of tin or manganese in solid solution is to provide a molar ratio Ti/Sn or Ti/Mn between 10 and 1,000.
摘要翻译： 由固溶体中掺入锡和锰的四方晶氧化钛的纳米尺寸核心和芯周围的氧化硅壳组成的核/壳型四方钛氧化物颗粒分散在水性分散介质中。 芯和核/壳型氧化钛颗粒的平均粒度分别为30nm和50nm。 固溶体中的锡或锰的含量为提供10〜1000摩尔比Ti / Sn或Ti / Mn。
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公开(公告)号：US20200165364A1
公开(公告)日：2020-05-28
申请号：US16627263
申请日：2018-04-10
发明人： Koichi HIGUCHI
IPC分类号： C08F30/08 , C09D143/04 , C09D7/62 , C08K9/06 , C08K3/36
摘要： A poly(meth)acrylate represented by formula (1) can impart a hardcoat layer having exceptional scratch resistance, strong impact resistance, and excellent weather resistance, especially weather crack resistance. (R1-R4 represent hydrogen atoms, etc.; Y represents a divalent hydrocarbon group having a polycyclic structure; X represents a divalent or trivalent saturated hydrocarbon group in which at least one selected from oxygen atoms, etc., may be interposed; T represents a urethane group (bonds with X by an oxygen atom); Q represents a divalent or trivalent saturated hydrocarbon group in which at least one selected from oxygen atoms, etc., may be interposed; P represents a (meth)acryloyloxy group; a and c represent the number of Q-T bonded to X, a and c being 1 when X is divalent and 2 when X is trivalent; b and d represent the number of (meth)acryloyloxy groups bonded to Q, b and d being 1 or 2 when a or c is 1, and being 2, 3, or 4 when a is 2; and n represents an integer of 0-6.)
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5.发明申请REACTIVE UV ABSORBER, MAKING METHOD, COATING COMPOSITION, AND COATED ARTICLE 有权反应性紫外线吸收剂，制备方法，涂料组合物和涂层物品公开(公告)号：US20140295191A1
公开(公告)日：2014-10-02
申请号：US14230816
申请日：2014-03-31
发明人： Koichi HIGUCHI , Yukimasa AOKI
IPC分类号： C09D133/08 , C07D251/24
CPC分类号： C07D251/24 , C08F222/1006 , C08J7/047 , C08J2369/00 , C08J2433/10 , C08K5/3492 , C09D4/00 , Y10T428/31551 , Y10T428/31591 , C08F2222/1053 , C08F2222/1026 , C08F2222/1013 , C08F2222/1086 , C08F2230/085
摘要： Novel UV absorbers of benzotriazine type having a plurality of (meth)acryloxy groups have a UV absorbing capacity and a high solubility in multifunctional (meth)acrylate. By combing the (meth)acrylic functional UV absorber with various binder precursors such as photo-curable multifunctional (meth)acrylate, there are obtained coating compositions having improved crosslinking density, UV absorbing capacity, anti-bleeding property, and shelf stability.
摘要翻译： 具有多个（甲基）丙烯酰氧基的苯并三嗪类的新型紫外线吸收剂在多官能（甲基）丙烯酸酯中具有UV吸收能力和高溶解度。 通过将（甲基）丙烯酸官能的紫外线吸收剂与光固化性多官能（甲基）丙烯酸酯等各种粘合剂前体结合，得到交联密度，紫外线吸收能力，防渗性能和贮存稳定性提高的涂料组合物。
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公开(公告)号：US20220195136A1
公开(公告)日：2022-06-23
申请号：US17644751
申请日：2021-12-16
发明人： Kazuaki YAMAMOTO , Shinji KADOSHIMA , Hiroyuki KOGA , Kazuyuki NEGISHI , Masahiko MINEMURA , Koichi HIGUCHI
摘要： In a heat-shielding film formed of addition-curing silicone resin containing organopolysiloxane, organopolysiloxane includes the combination of a plurality of units including at least a R1SiO3/2 unit (a T unit), a R2R3SiO2/2 unit (a D unit), and a R4R5R6SiO1/2 unit (a M unit) (in each unit, R1 to R6 is aliphatic hydrocarbon or hydrogen), and the molar ratio of the T unit, the D unit, and the M unit among all structural units is T:33.3 mol % to 71.4 mol %, D:11.1 mol % to 42.9 mol %, and M:7.0 mol % to 42.9 mol %.
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7.发明申请公开(公告)号：US20170158859A1
公开(公告)日：2017-06-08
申请号：US15371430
申请日：2016-12-07
发明人： Ryosuke YOSHII , Kohei MASUDA , Koichi HIGUCHI , Tsuneo KIMURA
CPC分类号： C09C1/0081 , C01P2004/64 , C01P2004/84 , C08K3/22 , C08K3/36 , C08K9/06 , C09C3/08 , C09C3/12 , C08L83/04
摘要： An inorganic particle-polysiloxane composite comprising inorganic particles having a polysiloxane containing SiR2R3O2/2 and SiR4R5R6O1/2 units grafted to their surface is prepared without mechanical treatment. The inorganic particles have an average particle size of 1-200 nm, the polysiloxane may be bonded to the inorganic particle surface via a siloxane coating layer containing SiR1O3/2 units, and a total of siloxane constituents is 20-20,000 pbw per 100 pbw of the inorganic particles. R1 to R5 are H, alkyl, alkenyl, aryl or dimethylsiloxy group, and R6 is H, alkyl, alkenyl, aryl, dimethylsiloxy, alkoxy or hydroxyl group. The inorganic particle-polysiloxane composite is dispersible in silicone oil, and so a transparent functional silicone material is obtained.
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8.发明申请ORGANIC SOLVENT DISPERSION OF TITANIUM OXIDE SOLID-SOLUTION PARTICLES, MAKING METHOD, AND COATING COMPOSITION 审中-公开氧化钛固溶体颗粒的有机溶剂分散体，制备方法和涂料组合物公开(公告)号：US20150299417A1
公开(公告)日：2015-10-22
申请号：US14687344
申请日：2015-04-15
发明人： Kohei MASUDA , Koichi HIGUCHI , Manabu FURUDATE , Tomohiro INOUE
IPC分类号： C08K3/22 , C09D1/00 , C08K3/36 , C08K3/08 , C08K5/5419
CPC分类号： C08K3/22 , C01G23/04 , C01G23/0538 , C01P2002/52 , C01P2002/86 , C01P2004/64 , C08K3/08 , C08K3/36 , C08K5/5419 , C08K2003/2241 , C09C1/3661 , C09C1/3684 , C09D1/00 , C09D7/62 , C09D7/67
摘要： Core/shell type tetragonal titanium oxide solid-solution particles each consisting of a core of tetragonal titanium oxide having tin and manganese incorporated in solid solution and a shell of silicon oxide are dispersed in an organic solvent. The core/shell type particles have a diameter D50 of 5-50 nm. The amount of tin incorporated in solid solution is to provide a molar ratio Ti/Sn of 10-1,000, and the amount of manganese incorporated in solid solution is to provide a molar ratio Ti/Mn of 10-1,000.
摘要翻译： 由固体溶液中含有锡和锰的四方晶氧化钛芯和氧化硅壳组成的核/壳型四方钛氧化物固溶体颗粒分散在有机溶剂中。 核/壳型颗粒的直径D50为5-50nm。 掺入固溶体中的锡的量为Ti / Sn的摩尔比为10-1,000，并且固溶体中掺入的锰的量为10-1,000的Ti / Mn摩尔比。
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9.发明申请PHOTOCURABLE COATING COMPOSITION, LAMINATE, AND AUTOMOTIVE HEADLAMP COVERING SHEET 审中-公开可涂层涂料组合物，层压板和汽车头盖封面公开(公告)号：US20150118483A1
公开(公告)日：2015-04-30
申请号：US14521549
申请日：2014-10-23
发明人： Kohei MASUDA , Koichi HIGUCHI , Yuji YOSHIKAWA
摘要： A photocurable coating composition is provided comprising (1) surface-treated titanium oxide comprising core/shell type microparticles each consisting of a titanium oxide core and a silicon oxide shell, which are treated with two surface treating components having formula (I): R1Si(0R2)3 wherein R1 is an organic group which may have a (meth)acrylic moiety, and R2 is alkyl, and formula (II): (R3R42Si)2NH wherein R3 is an organic group which may have a (meth)acrylic moiety, and R4 is alkyl, (2) a photopolymerizable monomer or oligomer, and (3) a photoinitiator. The composition has improved transparency and mar resistance despite titanium oxide loading.
摘要翻译： 提供了一种可光固化的涂料组合物，其包括（1）包含由氧化钛核和氧化硅壳组成的核/壳型微粒的表面处理氧化钛，其用两种具有式（I）的表面处理组分处理：R1Si（ 0R2）3其中R1是可以具有（甲基）丙烯酸部分，R2是烷基的有机基团，和式（II）：（R3R42Si）2NH其中R3是可以具有（甲基）丙烯酸部分的有机基团， 和R4是烷基，（2）可光聚合的单体或低聚物，和（3）光引发剂。 尽管氧化钛负载，组合物具有改善的透明度和耐划痕性。
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10.发明申请公开(公告)号：US20190264032A1
公开(公告)日：2019-08-29
申请号：US16349175
申请日：2017-11-06
发明人： Ryosuke YOSHII , Kohei MASUDA , Koichi HIGUCHI
IPC分类号： C09C1/36 , C09D183/04 , C09C3/12 , C09D7/40
摘要： An inorganic particle/siloxane composite which comprises a product of cohydrolysis and cocondensation of (A) at least one compound or product selected from among silicon compounds represented by general formulae (1) to (4) and products of partial hydrolysis and condensation thereof and (B) inorganic particles which, when examined by the dynamic light scattering method, give a volume-based particle diameter distribution that has a 50%-cumulation particle diameter (D50) of 3-100 nm, wherein the number of silicon atoms derived from the silicon compound represented by general formula (2) is 20 mol % or more of the number of all the silicon atoms in the component (A). The component (B) is contained in an amount of 65 mass % or less with respect to the whole product of cohydrolysis and cocondensation. The inorganic particle/siloxane composite has satisfactory compatibility with silicone materials although containing substantially no volatile organic solvent. Si(OR1)4 (1) R2Si(OR1)3 (2) R3R4Si(OR1)2 (3) R5R6R7SiOR1 (4) (In the formulae, R1 represents a C1-20 alkyl group, etc. and R2 to R7 each represent a C1-20 alkyl group, etc.)
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