公开(公告)号：US4306874A

公开(公告)日：1981-12-22

申请号：US174732

申请日：1980-08-01

Applicant: Horst Tappe ,  Claus Schuster

Inventor： Horst Tappe ,  Claus Schuster

IPC: C09B29/10 ,  C09B29/42 ,  D06P1/02 ,  D06P5/28 ,  D06P5/13 ,  D06P3/82

CPC classification number: D06P5/006 ,  C09B29/363 ,  Y10S8/918 ,  Y10S8/922

Abstract: A sublimable monoazo dyestuff of the formula ##STR1## wherein X is alkyl of 1-4 carbon atoms is used as the dyestuff in the process for printing synthetic, hydrophobic materials, treated cellulose materials or materials containing both by transfer printing using formulations containing said sublimable monoazo dyestuff.

Abstract translation: 在印刷合成，疏水材料，经处理的纤维素材料或含有两者的材料的过程中，将具有1-4个碳原子的烷基的升华性单偶氮染料用作染料，其中使用含有所述可升华的制剂 单偶氮染料

公开(公告)号：US5548072A

公开(公告)日：1996-08-20

申请号：US462131

申请日：1995-06-05

Applicant: J org Dannheim ,  Dieter Oehme ,  Horst Tappe

Inventor： J org Dannheim ,  Dieter Oehme ,  Horst Tappe

IPC: C07D251/50 ,  C07C317/36 ,  C09B29/30 ,  C09B62/008 ,  C09B62/44 ,  C09B62/51 ,  D06P1/38 ,  D06P3/10 ,  D06P3/66 ,  C09B62/085

CPC classification number: C09B62/4413

Abstract: Water-soluble azo compounds, preparation thereof and use thereof as dyesThere are described monoazo compounds conforming to the formula (1) ##STR1## which are used as dyes having fiber-reactive properties for preparing strong, red, fast dyeings and prints on hydroxy- and/or carboxamido-containing material, in particular fiber material, such as wool and synthetic polyamide fibers and in particular cellulose fibers, such as cotton.In the formula (1):M is hydrogen or an alkali metal; R.sup.1 is hydrogen or sulfo; R.sup.2 is hydrogen, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, sulfo, hydroxy, halogen or carboxy; R.sup.3 is hydrogen, halogen, alkyl of 1 to 4 carbon atoms or alkoxy of 1 to 4 carbon atoms; Y is vinyl or is ethyl which contains in the .beta.-position a substituent which is eliminable with alkali to form a vinyl group; p is 1 or 2; the one --SO.sub.3 M group is attached to the naphthalene ring para or meta to the amino group.

Abstract translation: 水溶性偶氮化合物及其作为染料的用途描述符合式（1）的单偶氮化合物作为具有纤维反应性的染料，用于制备强，红，快速染色， 印刷在含羟基和/或含羧酰胺的材料上，特别是纤维材料，如羊毛和合成聚酰胺纤维，特别是纤维素纤维，如棉花。 在式（1）中：M是氢或碱金属; R1是氢或磺基; R2是氢，1至4个碳原子的烷基，1至4个碳原子的烷氧基，磺基，羟基，卤素或羧基; R3是氢，卤素，1至4个碳原子的烷基或1至4个碳原子的烷氧基; Y是乙烯基或是在β-位上含有可用碱消除以形成乙烯基的取代基的乙基; p为1或2; 一个-SO 3 M基团与萘环相对或氨基连接。

公开(公告)号：US4431585A

公开(公告)日：1984-02-14

申请号：US237628

申请日：1981-02-24

Applicant: Horst Tappe ,  Ulrich Buhler ,  Kurt Roth ,  Hans-J. Weyer ,  Uwe Kosubek

Inventor： Horst Tappe ,  Ulrich Buhler ,  Kurt Roth ,  Hans-J. Weyer ,  Uwe Kosubek

IPC: C09B29/08 ,  C09B31/043 ,  C09B43/40 ,  C09B43/42 ,  C09B29/06 ,  C09B29/00

CPC classification number: C09B43/405 ,  C09B29/0813 ,  C09B31/043 ,  C09B43/40 ,  C09B43/42

Abstract: Water-insoluble azo dyestuffs suitable for dyeing and printing synthetic hydrophobic fiber materials are produced by azo coupling and have the formula ##STR1## wherein D is free from ionic moieties and is an unsubstituted or substituted phenyl, thiazole, isothiazole, benzthiazole, thiadiazole, benzisothiazole or thiophene moiety;A is alkylene having 2 to 6 carbon atoms which is unsubstituted or substituted by --OH;B is hydrogen, alkyl having 1 to 4 carbon atoms, hydroxyalkyl having 2 to 4 carbon atoms, alkoxyalkyl having 1 to 4 carbon atoms in the alkoxy moiety and a total of 3 to 8 carbon atoms, alkanoyloxyalkyl having 2 to 6 carbon atoms in the alkanoyl moiety and a total of 3 to 8 carbon atoms, hydroxypolyoxyalkylene having 4 to 12 carbon atoms, alkoxypolyoxyalkylene having 1 to 4 carbon atoms in the alkoxy moiety and a total of 5 to 16 carbon atoms, alkanoyloxypolyoxyalkylene having 2 to 5 carbon atoms in the alkanoyl moiety and a total of 5 to 16 carbon atoms, alkanoyl having 2 to 6 carbon atoms or benzoyl;R.sup.1 is hydrogen, methyl or chlorine;R.sup.2 is hydrogen, halogen, alkyl having 1 to 4 carbon atoms or alkoxy having 1 to 4 carbon atoms;and R.sup.3 is hydrogen or alkoxy having 1 to 8 carbon atoms.

Abstract translation: 适用于染色和印刷合成疏水性纤维材料的水不溶性偶氮染料是通过偶氮偶合产生的，并具有式“IMAGE”，其中D不含离子部分，是未取代或取代的苯基，噻唑，异噻唑，苯并噻唑，噻二唑，苯并异噻唑 或噻吩部分; A是未被取代或被-OH取代的具有2至6个碳原子的亚烷基; B是氢，具有1至4个碳原子的烷基，具有2至4个碳原子的羟基烷基，烷氧基部分中具有1至4个碳原子的烷氧基烷基和总共3至8个碳原子，在该化合物中具有2至6个碳原子的烷酰氧基烷基 烷酰基部分和总共3至8个碳原子，具有4至12个碳原子的羟基聚氧化烯，烷氧基部分中具有1至4个碳原子的烷氧基聚氧化烯和总共5至16个碳原子，在2至5个碳原子上具有2至5个碳原子的烷酰氧基聚氧化烯 烷酰基部分和总共5至16个碳原子，具有2至6个碳原子的烷酰基或苯甲酰基; R1是氢，甲基或氯; R2是氢，卤素，具有1至4个碳原子的烷基或具有1至4个碳原子的烷氧基; 并且R 3是氢或具有1至8个碳原子的烷氧基。

公开(公告)号：US4342688A

公开(公告)日：1982-08-03

申请号：US244910

申请日：1981-03-18

Applicant: Horst Tappe

Inventor： Horst Tappe

IPC: C07D209/82 ,  C07D209/86

CPC classification number: C07D209/86

Abstract: The process for manufacture of an N-hydroxyalkylcarbazole of the formula ##STR1## wherein R is H, CH.sub.3 or C.sub.2 H.sub.5 and n is a number from 0 to 4 which comprises reacting carbazole with an epoxide of the formula ##STR2## or a chlorohydrin of the formula ##STR3## at temperatures from 20.degree. to 150.degree. C. in the presence of a base and a phase transfer catalyst, in an organic solvent which is immiscible with water.

Abstract translation: 或者式 在碱和相转移催化剂的存在下，在20℃至150℃的温度下在与水不混溶的有机溶剂中制备“IMAGE”。

公开(公告)号：US4158670A

公开(公告)日：1979-06-19

申请号：US879852

申请日：1978-02-22

Applicant: Rolf Muller ,  Joachim Ribka ,  Horst Tappe

Inventor： Rolf Muller ,  Joachim Ribka ,  Horst Tappe

IPC: C07B61/00 ,  B01J31/00 ,  B01J31/02 ,  C07C20060101 ,  C07C67/00 ,  C07C301/00 ,  C07C303/28 ,  C07C309/63 ,  C07C309/72 ,  C07C143/68

CPC classification number: C07C303/28

Abstract: A process for the manufacture of esters of aromatic sulphonic acids and aromatic aminohydroxy compounds, of the formula Ih.sub.2 n--a--o--so.sub.2 --b (i)comprising reacting an aromatic aminohydroxy compound of the formula IIh.sub.2 n--a--oh (ii)having a pK.sub.a value of from 8.5 to 10.1, with a sulphochloride of the formula IIIcl--SO.sub.2 --B (III)whereinA is phenylene, substituted phenylene, naphthylene or substituted naphthylene,B is phenyl, substituted phenyl, naphthyl or substituted naphthyl, and both A and B are free from --COOH and --SO.sub.3 H substituents;The reaction taking place in a reaction medium consisting essentially of water and a water-immiscible organic solvent for the sulphochloride,At a temperature of from 0.degree. to 95.degree. C., at a pH which is determined from and associated with the pK.sub.a value of said aromatic aminohydroxy compound of formula II by the equationpK.sub.a -pH=0.5 to -1.5, and in the presence of a phase transfer catalyst.

Abstract translation: 制备式I H 2 N-AO-SO 2 -B（I）的芳族磺酸和芳族氨基羟基化合物的酯的方法，包括使具有式II的芳族氨基羟基化合物H 2 N-A-OH（II） 其中A为亚苯基，取代亚苯基，亚萘基或取代亚萘基，B为苯基，取代的苯基，萘基或取代的萘基，并且两者均为 A和B不含-COOH和-SO 3 H取代基; 在pH为0〜95℃的温度下，在由碱性水溶液组成的反应介质中进行反应和在硫酸盐的水不溶性有机溶剂中反应，其pH值由pKa值 所述式II的芳族氨基羟基化合物通过PKa-pH = 0.5至-1。

公开(公告)号：US5484458A

公开(公告)日：1996-01-16

申请号：US243111

申请日：1994-05-16

Applicant: Werner H. Russ ,  Horst Tappe ,  Christian Schumacher

Inventor： Werner H. Russ ,  Horst Tappe ,  Christian Schumacher

IPC: C07C317/28 ,  C09B62/44 ,  C09B62/503 ,  C09B67/22 ,  D06P3/24 ,  D06P3/66 ,  C09B62/002 ,  D06P1/38

CPC classification number: C09B62/503 ,  C07C317/28 ,  C09B62/4403 ,  C09B67/0033 ,  Y10S8/917 ,  Y10S8/918 ,  Y10S8/924

Abstract: Triphendioxazine compounds corresponding to the formula ##STR1## which are suitable as fiber-reactive dyestuffs for dyeing and printing material, in particular fiber material, containing hydroxy and/or carboxamide groups, such as wool and synthetic polyamide fibers, and especially cellulose fibers, such as cotton, are described. In formula (1), M is hydrogen or an alkali metal and Z is a radical of the formula (2) ##STR2## in which R is hydrogen, sulfo, alkyl having 1 to 4 carbon atoms, alkoxy having 1 to 4 carbon atoms, nitro or cyano, W is alkylene having 3 to 6 carbon atoms and the group --SO.sub.2 --Y is a fiber-reactive group of the vinyl sulfone series.

Abstract translation: 对应于式（1）的三苯并二恶嗪化合物适合用作染色和印刷材料的纤维反应性染料，特别是含有羟基和/或羧酰胺基团的纤维材料，例如羊毛和合成聚酰胺纤维，特别是纤维素 描述了诸如棉花之类的纤维。 在式（1）中，M是氢或碱金属，Z是式（2）的基团，其中R是氢，磺基，具有1至4个碳原子的烷基，具有1至 4个碳原子，硝基或氰基，W是具有3至6个碳原子的亚烷基，基团-SO 2 -Y是乙烯基砜系列的纤维反应性基团。

公开(公告)号：US4857070A

公开(公告)日：1989-08-15

申请号：US154495

申请日：1988-02-08

Applicant: Winfried Seidel ,  Horst Tappe

Inventor： Winfried Seidel ,  Horst Tappe

IPC: A61K8/00 ,  A61K8/49 ,  A61Q5/10 ,  C07D307/12 ,  C09B53/00 ,  D06P1/32 ,  D06P3/08

CPC classification number: D06P1/32 ,  A61K8/4973 ,  A61Q5/10 ,  C07D307/12

Abstract: The invention relates to new 2,4-diaminophenyl tetrahydrofurfuryl ethers of the general formula VIII and to their salts with inorganic or organic acids ##STR1## in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4, independently of one another, each represent a hydrogen atom, a (C.sub.1 -C.sub.4)alkyl group, hydroxy(C.sub.2 -C.sub.4)alkyl group, dihydroxy(C.sub.3 -C.sub.4)alkyl group, halogeno(C.sub.2 -C.sub.4)alkyl group, amino(C.sub.2 -C.sub.4)alkyl group or an amino(C.sub.2 -C.sub.4)alkyl group which is substituted once or twice by methyl, ethyl or hydroxyethyl radicals on the nitrogen, the carbon chain having a straight or branched arrangement, and it being a proviso that at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represents a hydrogen atom, to processes for their preparation, and to aqueous tinting compositions for keratin fibres such as fur and human hair, containing at least one coupler and at least one developing component together with customary additives and auxiliaries, the coupler corresponding to the general formula VIII or to the acid salts of these compounds.

Abstract translation: 本发明涉及通式VIII的新的2,4-二氨基苯基四氢糠基醚及其与无机或有机酸（VIII）的盐，其中R 1，R 2，R 3和R 4彼此独立地表示 氢原子，（C1-C4）烷基，羟基（C2-C4）烷基，二羟基（C3-C4）烷基，卤代（C2-C4）烷基，氨基（C2-C4）烷基或氨基 （C 2 -C 4）烷基，其被氮上的甲基，乙基或羟乙基取代一次或两次，所述碳链具有直链或支链排列，条件是R1，R2，R3和 R4代表氢原子，其制备方法，以及含有至少一种偶联剂和至少一种显影组分以及常规添加剂和助剂的角蛋白纤维如毛皮和人发的水性着色组合物，所述成色剂对应于 通式VIII或这些化合物的酸式盐。

公开(公告)号：US4567252A

公开(公告)日：1986-01-28

申请号：US492240

申请日：1983-05-06

Applicant: Ulrich Buhler ,  Horst Tappe ,  Albert Bode ,  Manfred Hahnke ,  Kurt Roth

Inventor： Ulrich Buhler ,  Horst Tappe ,  Albert Bode ,  Manfred Hahnke ,  Kurt Roth

IPC: C09B29/01 ,  C09B29/15 ,  C09B29/02 ,  C09B29/34 ,  D06P3/24 ,  D06P3/52

CPC classification number: C09B29/0003 ,  C09B29/103 ,  Y10S534/02

Abstract: Azo dyestuff of the formula ##STR1## wherein X is secondary amino or tertiary amino moiety, useful for dyeing and printing hydrophobic fiber materials to produce a deep orange color having excellent fastness properties and also useful for coloring organic solvents, mineral oil products, waxes, plastics and surface coatings.

Abstract translation: 其中X是仲氨基或叔氨基部分的偶氮染料，其可用于染色和印刷疏水纤维材料以产生具有优异坚牢性的深橙色，并且还可用于着色有机溶剂，矿物油产品，蜡， 塑料和表面涂层。

公开(公告)号：US4265629A

公开(公告)日：1981-05-05

申请号：US105204

申请日：1979-12-19

Applicant: Joachim Ribka ,  Horst Tappe ,  Kurt Roth ,  Hans-Jurgen Weyer

Inventor： Joachim Ribka ,  Horst Tappe ,  Kurt Roth ,  Hans-Jurgen Weyer

IPC: D06P5/12 ,  D06P5/15

CPC classification number: D06P5/15 ,  D06P5/12

Abstract: In the process for production of resist effects on textile materials of mixed fibers of polyester and cellulose comprising impregnating the materials with a dye liquor containing disperse dyestuffs and reactive dyestuffs which react with the resisting agents, drying or partially drying the padded materials and subsequently printing a resist paste on the material, and heat-treating the materials the improvement comprises the dischargeable disperse dyestuffs being of a class of dyestuffs of which an exemplary species is ##STR1## one of the tautomeric forms of a class of dyestuffs of which an exemplary species is ##STR2## or disperse dyestuffs which are free from groups conferring solubility in water and which contain at least two carboxylic acid ester moieties.

Abstract translation: 在对聚酯和纤维素的混合纤维的纺织材料的抗蚀剂效果的生产过程中，包括用含有分散染料的染液和与抗蚀剂反应的活性染料浸渍材料，干燥或部分干燥填充材料并随后印刷 在材料上抵抗糊料，并且对材料进行热处理，改进包括可排放的分散染料是一类染料，其示例性物质是一类染料的互变异构体之一，其示例性物质是 或分散不含赋予在水中溶解度且含有至少两个羧酸酯部分的基团的染料。

公开(公告)号：US4157446A

公开(公告)日：1979-06-05

申请号：US819756

申请日：1977-07-29

Applicant: Horst Tappe

Inventor： Horst Tappe

IPC: C07D213/69 ,  C07D213/71 ,  C07D213/76

CPC classification number: C07D213/69 ,  C07D213/71

Abstract: A .beta.,.beta.,.beta.-trihalo-.alpha.-hydroxyethyl (e.g. --CHOH--CCl.sub.3) group is introduced into a 2,6-dihydroxy pyridine. The 3-formyl-4-methyl-2,6-dihydroxy pyridine produced by splitting off haloform from the trihalohydroxyethyl product, is a desirable intermediate for the making of dyes and other products, and the alkali metal or alkaline earth metal salts of the formyl compound are more stable forms of this intermediate.

Abstract translation: 将β，β，β-三卤-α-羟乙基（例如-CHOH-CCl 3）基团引入2,6-二羟基吡啶中。 通过从三卤羟乙基产物中分离卤代衍生的3-甲酰基-4-甲基-2,6-二羟基吡啶是制备染料和其它产物的理想中间体，以及甲酰基的碱金属或碱土金属盐 化合物是该中间体的更稳定的形式。