公开(公告)号：US20220097033A1

公开(公告)日：2022-03-31

申请号：US17309783

申请日：2019-12-18

申请人： BASF SE ,  The University of Tokyo

发明人： Hannah SCHREYER ,  Andrei-Nicolae Parvulescu ,  Ulrich MUELLER ,  Karsten SEIDEL ,  Tatsuya OKUBO ,  Toru WAKIHARA ,  Kenta IYOKI ,  Watcharop CHAIKITTISILP

IPC分类号： B01J29/76 ,  C01B39/48 ,  B01J37/08 ,  B01J37/30 ,  B01J37/02 ,  B01J35/10

摘要： The present disclosure relates to a process for the preparation of a zeolitic material having a CHA-type framework structure comprising YO2 and X2O3, wherein the process comprises: (1) providing a mixture comprising one or more sources for YO2, one or more sources for X2O3, one or more tetraalkylammonium cation R1R2R3R4N+-containing compounds, and one or more tetraalkylammonium cation R5R6R7R8N+-containing compounds as structure directing agent; (2) crystallizing the mixture to obtain a zeolitic material having a CHA-type framework structure; wherein Y is a tetravalent element and X is a trivalent element, wherein R1, R2, R3, R5, R6, and R7 independently from one another stand for alkyl, wherein R4 stands for CnH2nOH with n=1 to 6, and wherein R8 stands for cycloalkyl.

公开(公告)号：US11180467B2

公开(公告)日：2021-11-23

申请号：US16500313

申请日：2018-04-13

申请人： BASF SE

发明人： Nicolai Tonio Woerz ,  Ulrich Mueller ,  Andrei-Nicolae Parvulescu ,  Dominic Riedel ,  Marvin Kramp ,  Daniel Urbanczyk ,  Ulrike Wegerle ,  Christian Mueller ,  Bernd Metzen ,  Markus Weber ,  Joaquim Henrique Teles

IPC分类号： C07D301/32 ,  C07D301/19 ,  C07D301/12

摘要： The invention relates to a process for preparing propylene oxide, comprising (i) providing a stream comprising propene, propane, hydrogen peroxide or a source of hydrogen peroxide, water, and an organic solvent; (ii) passing the liquid feed stream provided in (i) into an epoxidation zone comprising an epoxidation catalyst comprising a titanium zeolite, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation zone, obtaining a reaction mixture comprising propene, propane, propylene oxide, water, and the organic solvent; (iii) removing an effluent stream from the epoxidation zone, the effluent stream comprising propene, propane, propylene oxide, water, and the organic solvent; (iv) separating propene and propane from the effluent stream by distillation, comprising subjecting the effluent stream to distillation conditions in a distillation unit, obtaining a gaseous stream (S1) which is enriched in propene and propane compared to the effluent stream subjected to distillation conditions, and a liquid bottoms stream (S2) which is enriched in propylene oxide, water and organic solvent compared to the effluent stream subjected to distillation conditions; (v) separating propane from the stream (S1) in a separation zone, comprising subjecting the stream (S1) to washing conditions in a scrubber, wherein a solvent mixture comprising organic solvent and water is added as entraining agent, obtaining a bottoms stream (S3), which comprises organic solvent, water and at least 70 weight-% of the propene comprised in (S1); and a gaseous top stream (S4), which comprises at least 5 weight-% of the propane comprised in stream (S1).

公开(公告)号：US10766781B2

公开(公告)日：2020-09-08

申请号：US16060229

申请日：2016-12-07

申请人： BASF SE

发明人： Andrei-Nicolae Parvulescu ,  Joaquim Henrique Teles ,  Nicolas Vautravers ,  Ulrich Müller

IPC分类号： B01J29/06 ,  C01B39/08 ,  C01B37/02 ,  C01B39/12 ,  C01B39/48 ,  C07D313/04 ,  C07F5/02 ,  C07F7/22 ,  C07C51/00 ,  C07C67/00 ,  B01J29/70 ,  B01J29/86 ,  B01J29/035 ,  B01J37/10 ,  B01J35/10 ,  B01J37/03 ,  C07C51/02

摘要： A process for preparing a tin-containing zeolitic material having framework type BEA, comprising providing an aqueous synthesis mixture comprising a boron source, a silicon source, and a BEA structure directing agent; subjecting the synthesis mixture provided in to hydrothermal pre-crystallization conditions; adding the tin source to the obtained mixture; subjecting the obtained aqueous synthesis mixture to hydrothermal crystallization conditions, obtaining a tin-containing zeolitic material having framework type BEA comprised in its mother liquor.

公开(公告)号：US10676451B2

公开(公告)日：2020-06-09

申请号：US16315345

申请日：2017-07-19

申请人： BASF SE ,  Dow Global Technologies LLC

发明人： Joaquim Henrique Teles ,  Marvin Kramp ,  Christian Mueller ,  Nicolai Tonio Woerz ,  Bernd Metzen ,  Tobias Keller ,  Dominic Riedel ,  Heiner Schelling ,  Markus Weber ,  Daniel Urbanczyk ,  Andrei-Nicolae Parvulescu ,  Ulrike Wegerle ,  Ulrich Mueller ,  Meinolf Weidenbach ,  Werner J. Witzl

IPC分类号： C07D301/32 ,  B01D3/14 ,  C07D303/04

摘要： Disclosed is a process for purifying propylene oxide. A stream S0 containing propylene oxide, acetonitrile, water, and an organic compound containing one or more of acetone and propionaldehyde is provided. Propylene oxide is separated from S0 by subjecting S0 to distillation in a first distillation unit, obtaining a gaseous top stream S1c enriched in propylene oxide, a liquid bottom stream S1a enriched in acetonitrile and water, and a side stream S1b containing propylene oxide and enriched in the carbonyl compound; reacting the carbonyl compound in S1b with an organic compound containing an amino group to obtain a reaction product; separating propylene oxide from the reaction product in a second distillation unit, obtaining a gaseous top stream S3a enriched in propylene oxide and a liquid bottoms stream S3b enriched in the reaction product; and introducing stream S3a into the first distillation unit.

公开(公告)号：US10202324B2

公开(公告)日：2019-02-12

申请号：US15571107

申请日：2016-05-04

申请人： BASF SE

发明人： Nicolas Vautravers ,  Joaquim Henrique Teles ,  Ralf Pelzer ,  Daniel Schneider ,  Florian Garlichs ,  Andreas Keller ,  Andrei-Nicolae Parvulescu ,  Ulrich Müller

IPC分类号： C07C45/54 ,  C07C45/78 ,  C07C67/39 ,  C07C45/64

摘要： A process for preparing 2,6-dimethyl-5-heptenal, comprising oxidizing citral of which more than 50% are present as geranial with hydrogen peroxide in the presence of a catalyst comprising a Baeyer-Villiger oxidation catalyst, preferably a tin-containing molecular sieve.

公开(公告)号：US10053439B2

公开(公告)日：2018-08-21

申请号：US15636787

申请日：2017-06-29

申请人： BASF SE ,  DOW Global Technologies LLC

发明人： Dominic Riedel ,  Joaquim Henrique Teles ,  Ulrike Wegerle ,  Andrei-Nicolae Parvulescu ,  Alexander Schroeder ,  Luise Spiske ,  Daniel Urbanczyk ,  Ulrich Mueller ,  Werner Witzl ,  Meinolf Weidenbach

IPC分类号： C07D301/12 ,  B01J29/04 ,  B01J29/89 ,  C07D301/36 ,  C07D303/04 ,  B01J35/00 ,  B01J35/02 ,  C01B39/02 ,  C01B39/08 ,  C01B39/12 ,  C01B39/48 ,  B01J27/18 ,  B01J27/188 ,  B01J27/232 ,  B01J29/70 ,  B01J31/04 ,  C07D301/00 ,  B01J37/00 ,  B01J29/86

摘要： A catalytic system containing a titanium zeolite of structure type MWW optionally containing zinc and containing at least one of an inorganic potassium salt and an organic potassium salt is provided. The catalyst system is useful in the preparation of propylene oxide.

公开(公告)号：US09738616B2

公开(公告)日：2017-08-22

申请号：US14908042

申请日：2014-07-16

申请人： BASF SE ,  DOW Global Technologies LLC

发明人： Dominic Riedel ,  Joaquim Henrique Teles ,  Ulrike Wegerle ,  Andrei-Nicolae Parvulescu ,  Alexander Schroeder ,  Luise Spiske ,  Daniel Urbanczyk ,  Ulrich Mueller ,  Werner Witzl ,  Meinolf Weidenbach

IPC分类号： C07D301/12 ,  C07D303/00 ,  B01J29/89 ,  B01J37/00 ,  C07D301/36 ,  C07D303/04 ,  B01J35/00 ,  B01J35/02 ,  C01B39/02 ,  C01B39/08 ,  C01B39/12 ,  C01B39/48 ,  B01J27/18 ,  B01J27/188 ,  B01J27/232 ,  B01J29/70 ,  B01J31/04 ,  C07D301/00 ,  B01J29/86

CPC分类号： C07D301/12 ,  B01J27/1806 ,  B01J27/188 ,  B01J27/232 ,  B01J29/7088 ,  B01J29/86 ,  B01J29/89 ,  B01J31/04 ,  B01J35/002 ,  B01J35/023 ,  B01J37/0045 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/37 ,  B01J2229/40 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/08 ,  C01B39/085 ,  C01B39/12 ,  C01B39/48 ,  C07D301/00 ,  C07D301/36 ,  C07D303/04 ,  Y02P20/52

摘要： A continuous process for the preparation of propylene oxide, comprising (i) providing a liquid feed stream comprising propene, hydrogen peroxide, acetonitrile, water, optionally propane, and at least one dissolved potassium salt; (ii) passing the feed stream provided in (i) into an epoxidation reactor comprising a catalyst comprising a titanium zeolite of structure type MWW, and subjecting the feed stream to epoxidation reaction conditions in the epoxidation reactor, obtaining a reaction mixture comprising propylene oxide, acetonitrile, water, the at least one potassium salt, optionally propene, and optionally pane; (iii) removing an effluent stream from the epoxidation reactor, the effluent stream comprising propylene oxide, acetonitrile, water, at least a portion of the at least one potassium salt, optionally propene, and optionally propane.

公开(公告)号：US20160031714A1

公开(公告)日：2016-02-04

申请号：US14862893

申请日：2015-09-23

申请人： BASF SE

发明人： Ulrich MUELLER ,  Andrei-Nicolae Parvulescu ,  Jeff Yang ,  Hans-Juergen Luetzel ,  Georg Uhl ,  Stefan Dumser

IPC分类号： C01B39/02 ,  B01J29/70 ,  B01J37/06 ,  B01J37/10 ,  B01J37/00 ,  C01B39/48 ,  B01J35/02

CPC分类号： B01J29/04 ,  B01J29/7007 ,  B01J29/7015 ,  B01J29/7038 ,  B01J29/7057 ,  B01J29/7065 ,  B01J29/7088 ,  B01J29/86 ,  B01J29/89 ,  B01J35/002 ,  B01J35/026 ,  B01J37/0072 ,  B01J37/009 ,  B01J37/06 ,  B01J37/10 ,  B01J2229/18 ,  B01J2229/30 ,  B01J2229/37 ,  C01B39/026 ,  C01B39/12 ,  C01B39/48

摘要： The present invention relates to a process for process for the preparation of a zeolitic material which process comprises (i) providing a boron-containing zeolitic material and (ii) deboronating the boron-containing zeolitic material by treating the boron-containing zeolitic material with a liquid solvent system thereby obtaining a deboronated zeolitic material, which liquid solvent system does not contain an inorganic or organic acid, or a salt thereof.

公开(公告)号：US09168513B2

公开(公告)日：2015-10-27

申请号：US13759573

申请日：2013-02-05

申请人： BASF SE

发明人： Ulrich Mueller ,  Andrei-Nicolae Parvulescu ,  Jeff Yang ,  Hans-Juergen Luetzel ,  Georg Uhl ,  Stefan Dumser

IPC分类号： C01B39/02 ,  B01J29/86 ,  B01J29/04 ,  B01J29/89 ,  B01J29/70 ,  B01J35/00 ,  C01B39/12

CPC分类号： B01J29/04 ,  B01J29/7007 ,  B01J29/7015 ,  B01J29/7038 ,  B01J29/7057 ,  B01J29/7065 ,  B01J29/7088 ,  B01J29/86 ,  B01J29/89 ,  B01J35/002 ,  B01J35/026 ,  B01J37/0072 ,  B01J37/009 ,  B01J37/06 ,  B01J37/10 ,  B01J2229/18 ,  B01J2229/30 ,  B01J2229/37 ,  C01B39/026 ,  C01B39/12 ,  C01B39/48

摘要： The present invention relates to a process for process for the preparation of a zeolitic material which process comprises (i) providing a boron-containing zeolitic material and (ii) deboronating the boron-containing zeolitic material by treating the boron-containing zeolitic material with a liquid solvent system thereby obtaining a deboronated zeolitic material, which liquid solvent system does not contain an inorganic or organic acid, or a salt thereof.

摘要翻译： 本发明涉及一种制备沸石材料的方法，该方法包括（i）提供含硼沸石材料和（ii）通过用含硼沸石材料处理含硼沸石材料来使硼含量沸石材料脱硼 液体溶剂系统，从而获得脱硼沸石材料，该液体溶剂体系不含无机或有机酸或其盐。

公开(公告)号：US20140128622A1

公开(公告)日：2014-05-08

申请号：US14072179

申请日：2013-11-05

申请人： BASF SE

发明人： Nicolas Vautravers ,  Joaquim Henrique Teles ,  Andrei-Nicolae Parvulescu ,  Ulrich Müller

IPC分类号： C07B41/06 ,  C07C51/285 ,  C07D309/30 ,  C07C45/29 ,  C07D313/04 ,  C07D315/00

CPC分类号： C07D313/04 ,  B01J23/00 ,  C07C45/54 ,  C07C51/285 ,  C07D309/30 ,  C07D313/00 ,  C07C47/21 ,  C07C57/03

摘要： A process for the oxidation of an organic carbonyl compound comprising reacting the organic carbonyl compound, optionally in the presence of a solvent, with hydrogen peroxide in the presence of a catalyst comprising a tin-containing zeolitic material having an MWW-type framework structure.

摘要翻译： 一种有机羰基化合物的氧化方法，包括有机羰基化合物，任选在溶剂存在下，在含有具有MWW型骨架结构的含锡沸石材料的催化剂存在下，与过氧化氢反应。