公开(公告)号：US10189946B2

公开(公告)日：2019-01-29

申请号：US15121940

申请日：2014-12-12

Applicant: BASF SE

Inventor： Christoph Mueller ,  Thomas Reissner ,  Ansgar Gereon Altenhoff ,  Andreas Kunst ,  Christian Mueller

IPC: C08G73/00 ,  C08G73/02

Abstract: The present invention relates to a process for preparing polyamines having a mean molecular weight of ≥203 g/mol, in which the deviation from the mean molecular weight per ° C. of change in the reaction temperature is

公开(公告)号：US11180467B2

公开(公告)日：2021-11-23

申请号：US16500313

申请日：2018-04-13

Applicant: BASF SE

Inventor： Nicolai Tonio Woerz ,  Ulrich Mueller ,  Andrei-Nicolae Parvulescu ,  Dominic Riedel ,  Marvin Kramp ,  Daniel Urbanczyk ,  Ulrike Wegerle ,  Christian Mueller ,  Bernd Metzen ,  Markus Weber ,  Joaquim Henrique Teles

IPC: C07D301/32 ,  C07D301/19 ,  C07D301/12

Abstract: The invention relates to a process for preparing propylene oxide, comprising (i) providing a stream comprising propene, propane, hydrogen peroxide or a source of hydrogen peroxide, water, and an organic solvent; (ii) passing the liquid feed stream provided in (i) into an epoxidation zone comprising an epoxidation catalyst comprising a titanium zeolite, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation zone, obtaining a reaction mixture comprising propene, propane, propylene oxide, water, and the organic solvent; (iii) removing an effluent stream from the epoxidation zone, the effluent stream comprising propene, propane, propylene oxide, water, and the organic solvent; (iv) separating propene and propane from the effluent stream by distillation, comprising subjecting the effluent stream to distillation conditions in a distillation unit, obtaining a gaseous stream (S1) which is enriched in propene and propane compared to the effluent stream subjected to distillation conditions, and a liquid bottoms stream (S2) which is enriched in propylene oxide, water and organic solvent compared to the effluent stream subjected to distillation conditions; (v) separating propane from the stream (S1) in a separation zone, comprising subjecting the stream (S1) to washing conditions in a scrubber, wherein a solvent mixture comprising organic solvent and water is added as entraining agent, obtaining a bottoms stream (S3), which comprises organic solvent, water and at least 70 weight-% of the propene comprised in (S1); and a gaseous top stream (S4), which comprises at least 5 weight-% of the propane comprised in stream (S1).

公开(公告)号：US10676451B2

公开(公告)日：2020-06-09

申请号：US16315345

申请日：2017-07-19

Applicant: BASF SE ,  Dow Global Technologies LLC

Inventor： Joaquim Henrique Teles ,  Marvin Kramp ,  Christian Mueller ,  Nicolai Tonio Woerz ,  Bernd Metzen ,  Tobias Keller ,  Dominic Riedel ,  Heiner Schelling ,  Markus Weber ,  Daniel Urbanczyk ,  Andrei-Nicolae Parvulescu ,  Ulrike Wegerle ,  Ulrich Mueller ,  Meinolf Weidenbach ,  Werner J. Witzl

IPC: C07D301/32 ,  B01D3/14 ,  C07D303/04

Abstract: Disclosed is a process for purifying propylene oxide. A stream S0 containing propylene oxide, acetonitrile, water, and an organic compound containing one or more of acetone and propionaldehyde is provided. Propylene oxide is separated from S0 by subjecting S0 to distillation in a first distillation unit, obtaining a gaseous top stream S1c enriched in propylene oxide, a liquid bottom stream S1a enriched in acetonitrile and water, and a side stream S1b containing propylene oxide and enriched in the carbonyl compound; reacting the carbonyl compound in S1b with an organic compound containing an amino group to obtain a reaction product; separating propylene oxide from the reaction product in a second distillation unit, obtaining a gaseous top stream S3a enriched in propylene oxide and a liquid bottoms stream S3b enriched in the reaction product; and introducing stream S3a into the first distillation unit.

公开(公告)号：US11351525B2

公开(公告)日：2022-06-07

申请号：US16462430

申请日：2017-12-20

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Hans-Juergen Luetzel ,  Georg Uhl ,  Joaquim Henrique Teles ,  Dominic Riedel ,  Daniel Urbanczyk ,  Ulrike Wegerle ,  Markus Weber ,  Nicolai Tonio Woerz ,  Christian Mueller ,  Ruediger Schmitt ,  Xiana Romani Fernandez ,  Harald Wuerz

IPC: B01J29/70 ,  B01J35/02 ,  B01J37/00 ,  B01J37/02 ,  B01J37/10

Abstract: Use of an acid-treated titanium-containing zeolitic material having framework type MWW for preparing a composition having a relative plasticity of less than 1.

公开(公告)号：US11110442B2

公开(公告)日：2021-09-07

申请号：US16997038

申请日：2020-08-19

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Hans-Juergen Luetzel ,  Joaquim Henrique Teles ,  Dominic Riedel ,  Daniel Urbanczyk ,  Ulrike Wegerle ,  Markus Weber ,  Nicolai Tonio Woerz ,  Christian Mueller

IPC: B01J29/89 ,  B01J29/70 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  B01J37/08 ,  C01B39/02 ,  C01B39/06 ,  C01B39/12 ,  C07D301/12

Abstract: A process for preparing a molding comprising zinc and a titanium-containing zeolitic material having framework type MWW, comprising (i) providing a molding comprising a titanium-containing zeolitic material having framework type MWW; (ii) preparing an aqueous suspension comprising a zinc source and the molding comprising a titanium-containing zeolitic material having framework type MWW prepared in (i); (iii) heating the aqueous suspension prepared in (ii) under autogenous pressure to a temperature of the liquid phase of the aqueous suspension in the range of from 100 to 200° C., obtaining an aqueous suspension comprising a molding comprising zinc and a titanium-containing zeolitic material having framework type MWW; (iv) separating the molding comprising zinc and a titanium-containing zeolitic material having framework type MWW from the liquid phase of the suspension obtained in (iii).

公开(公告)号：US11291980B2

公开(公告)日：2022-04-05

申请号：US16461134

申请日：2017-12-20

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Hans-Juergen Luetzel ,  Georg Uhl ,  Joaquim Henrique Teles ,  Dominic Riedel ,  Daniel Urbanczyk ,  Ulrike Wegerle ,  Markus Weber ,  Nicolai Tonio Woerz ,  Christian Mueller

IPC: B01J29/89 ,  B01J35/10 ,  B01J37/00 ,  C01B37/00

Abstract: A process for preparing an extrudable composition comprising a titanium-containing zeolitic material having framework type MWW, the process comprising providing a titanium-containing zeolitic material having framework type MWW, having a water absorption capacity of at least 11 weight-%, subjecting the titanium-containing zeolitic material having framework type MWW an acid treatment, optionally incorporating zinc in the acid-treated titanium-containing zeolitic material having framework type MWW; preparing a composition comprising the titanium-containing zeolitic material having framework type MWW obtained from (ii) or (iii), a precursor of a silica binder, water, and a kneading agent, wherein the composition does not comprise a polyethylene oxide.

公开(公告)号：US20210253861A1

公开(公告)日：2021-08-19

申请号：US17270972

申请日：2019-08-27

Applicant: BASF SE

Inventor： Donald Charles Mente ,  Gustavo E. Leon ,  Gene Michael Scheffler ,  Christian Mueller ,  Stephan Weinkoetz

IPC: C08L97/02 ,  B27N1/02 ,  B27N3/00 ,  B27N3/02 ,  B27N3/04

Abstract: A lignocellulosic composite article includes a plurality of lignocellulosic pieces and an adhesive system disposed on the plurality of lignocellulosic pieces for bonding the plurality of lignocellulosic pieces. The adhesive system comprises a binder component and an additive component. The binder component comprises a diphenylmethane diisocyanate (MDI), a polymeric diphenylmethane diisocyanate (pMDI), and combinations thereof. The additive component comprises an amine compound and water. The amine compound can be imidazole. The additive component is useful for reducing the amount of press time required during manufacture of the composite article.

公开(公告)号：US10780432B2

公开(公告)日：2020-09-22

申请号：US16470834

申请日：2018-01-18

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Hans-Juergen Luetzel ,  Joaquim Henrique Teles ,  Dominic Riedel ,  Daniel Urbanczyk ,  Ulrike Wegerle ,  Markus Weber ,  Nicolai Tonio Woerz ,  Christian Mueller

IPC: B01J29/89 ,  B01J29/70 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  C01B39/02 ,  C01B39/06 ,  C01B39/12 ,  C07D301/12 ,  B01J37/08

Abstract: A process for preparing a molding comprising zinc and a titanium-containing zeolitic material having framework type MWW, comprising (i) providing a molding comprising a titanium-containing zeolitic material having framework type MWW; (ii) preparing an aqueous suspension comprising a zinc source and the molding comprising a titanium-containing zeolitic material having framework type MWW prepared in (i); (iii) heating the aqueous suspension prepared in (ii) under autogenous pressure to a temperature of the liquid phase of the aqueous suspension in the range of from 100 to 200° C., obtaining an aqueous suspension comprising a molding comprising zinc and a titanium-containing zeolitic material having framework type MWW; (iv) separating the molding comprising zinc and a titanium-containing zeolitic material having framework type MWW from the liquid phase of the suspension obtained in (iii).

公开(公告)号：US10544116B2

公开(公告)日：2020-01-28

申请号：US16315680

申请日：2017-07-19

Applicant: BASF SE

Inventor： Joaquim Henrique Teles ,  Marvin Kramp ,  Christian Mueller ,  Nicolai Tonio Woerz ,  Bernd Metzen ,  Tobias Keller ,  Dominic Riedel ,  Markus Weber ,  Daniel Urbanczyk ,  Andrei-Nicolae Parvulescu ,  Ulrike Wegerle ,  Ulrich Mueller

IPC: C07D301/12 ,  C07D301/32 ,  C07D303/04

Abstract: Disclosed herein is a process for purifying propylene oxide, including the steps of: (i) providing a stream S0 containing propylene oxide, acetonitrile, water, and an organic compound containing a carbonyl group —C(═O)—; and (ii) separating propylene oxide from the stream S0 by subjecting the stream S0 to distillation conditions in a distillation column to obtain a gaseous top stream S1c which is enriched in propylene oxide compared to the stream S0, a liquid bottoms stream S1a which is enriched in acetonitrile and water compared to the stream S0, and a side stream S1b containing propylene oxide which is enriched in the carbonyl compound compared to the stream S0.

公开(公告)号：US10544115B2

公开(公告)日：2020-01-28

申请号：US16076600

申请日：2017-02-16

Applicant: BASF SE

Inventor： Dominic Riedel ,  Joaquim Henrique Teles ,  Heiner Schelling ,  Ulrike Wegerle ,  Ulrich Mueller ,  Andrei-Nicolae Parvulescu ,  Jochen Mannweiler ,  Timo Henn ,  Thomas Luederitz ,  Nicolai Tonio Woerz ,  Christian Mueller ,  Markus Weber ,  Daniel Urbanczyk

IPC: C07D301/12 ,  C07D301/36 ,  B01J19/00 ,  B01J29/70 ,  C07D303/04

Abstract: A continuous process for the preparation of propylene oxide, comprising a start-up stage and normal run stage, wherein the normal run stage comprises (i) continuously providing a liquid feed stream comprising propene, hydrogen peroxide, acetonitrile, a formate salt, water and optionally propane, wherein in the liquid feed stream, the molar amount of the formate salt relative to the molar amount of hydrogen peroxide at a given point of time during the normal run stage is aN(Fo/H2O2); (ii) continuously passing the liquid feed stream provided in (i) into an epoxidation zone comprising a catalyst comprising a titanium zeolite having framework type MWW, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation zone, obtaining a reaction mixture comprising propylene oxide, acetonitrile, water, the formate salt, optionally propene, and optionally propane; (iii) continuously removing an effluent stream from the epoxidation zone, the effluent stream comprising propylene oxide, acetonitrile, water, at least a portion of the formate salt, optionally propene, and optionally propane; wherein the normal run stage is characterized in an average rate of change of aN(Fo/H2O2) of less than 0 h−1.