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1.发明授权Method for producing a supported hydrogenation catalyst having increased hydrogenation activity 有权制备具有增加的氢化活性的负载氢化催化剂的方法公开(公告)号：US09132417B2
公开(公告)日：2015-09-15
申请号：US13510115
申请日：2010-11-16
申请人： Rolf Tompers , Heiko Urtel , Rolf Pinkos , Gerd-Dieter Tebben , Jens Heimann , Maria Guixa Guardia , Sabine Borchers
发明人： Rolf Tompers , Heiko Urtel , Rolf Pinkos , Gerd-Dieter Tebben , Jens Heimann , Maria Guixa Guardia , Sabine Borchers
IPC分类号： B01J23/72 , B01J23/80 , B01J23/78 , B01J23/58 , B01J23/83 , B01J37/06 , C07C29/141 , C07C29/149 , B01J37/00
CPC分类号： B01J23/78 , B01J23/58 , B01J23/72 , B01J23/80 , B01J23/83 , B01J37/0063 , B01J37/06 , C07C29/141 , C07C29/149 , C07C31/22 , C07C31/20
摘要： In a process for preparing a supported hydrogenation catalyst with increased hydrogenation activity, which comprises a hydrogenating metal and/or an oxide of a hydrogenating metal on an Al2O3-containing support material, said calcined supported hydrogenation catalyst is treated before or after the final shaping thereof and before use thereof in the hydrogenation with a base solution having a pH of >10 at a temperature in the range from 20 to 120° C. for 1 to 300 hours.
摘要翻译： 在含有Al 2 O 3的载体材料上制备含氢化金属和/或氢化金属的氢化物的氢化活性增加的负载型氢化催化剂的方法中，所述煅烧的负载氢化催化剂在其最终成型之前或之后进行处理 并且在使用之前，在温度为20〜120℃的pH为> 10的碱溶液中氢化1〜300小时。
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2.发明授权公开(公告)号：US09045382B2
公开(公告)日：2015-06-02
申请号：US12307367
申请日：2007-07-16
申请人： Rolf Pinkos , Jens Heimann , Hans-Martin Polka , Heiko Urtel , Gunther Windecker
发明人： Rolf Pinkos , Jens Heimann , Hans-Martin Polka , Heiko Urtel , Gunther Windecker
IPC分类号： C07C27/26 , C07C29/14 , C07C29/16 , C07B63/00 , C07C29/149 , C07C29/86 , C07C209/48
CPC分类号： C07B63/00 , C07C29/149 , C07C29/86 , C07C209/48 , C07C211/12 , C07C31/20 , C07C31/207 , C07C31/04 , C07C31/08 , C07C31/10 , C07C31/12 , C07C31/202 , C07C31/205
摘要： The present invention relates to a process for separating off solvents from solvent-comprising hydrogenation outputs from a catalytic hydrogenation process, which comprise at least one water-soluble hydrogenation product having at least one alcohol, lactone, ether, lactam or amino group in a solvent which is immiscible or not completely miscible with water and has a boiling point below 100° C., wherein water is added to the hydrogenation output, the solvent-comprising phase is separated off and recirculated to the hydrogenation.
摘要翻译： 本发明涉及一种从溶剂中分离溶剂的方法，该方法包括至少一种在溶剂中具有至少一种醇，内酯，醚，内酰胺或氨基的至少一种水溶性氢化产物的催化氢化方法 其不混溶或不完全与水混溶并且具有低于100℃的沸点，其中向加氢产物中加入水，分离出含溶剂相并再循环至氢化。
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3.发明申请公开(公告)号：US20140155255A1
公开(公告)日：2014-06-05
申请号：US14134660
申请日：2013-12-19
申请人： Guido Henze , Lothar Karrer , Heiko Urtel , Stephan Hatscher
发明人： Guido Henze , Lothar Karrer , Heiko Urtel , Stephan Hatscher
IPC分类号： B01J20/34
CPC分类号： B01J20/3458 , B01J20/06 , B01J20/3078 , B01J20/3085 , B01J20/3483 , B01J2220/42 , C07C7/12 , C10G25/003 , C10G25/12 , C10G2400/20 , C07C11/06
摘要： The invention relates to a process for the regeneration of a copper-, zinc- and zirconium oxide-comprising adsorption composition after use thereof for the adsorptive removal of carbon monoxide from substance streams comprising carbon monoxide and at least one olefin, in which the adsorption composition is heated to a temperature in the range from 160 to 400° C. and a regeneration gas is passed through the adsorption composition, wherein the regeneration gas comprises 1000 to 3000 ppm of oxygen in an inert carrier gas.
摘要翻译： 本发明涉及一种用于在其使用之后再生含铜，锌和氧化锆的吸附组合物用于从包含一氧化碳和至少一种烯烃的物质流吸附除去一氧化碳的方法，其中吸附组合物 加热至160〜400℃的温度，再生气体通过吸附组合物，再生气体在惰性载气中含有1000〜3000ppm的氧气。
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4.发明授权Method for producing 1,2-propandiol by hydrogenating glycerine in a two-step reactor cascade 有权通过在两步反应器级联中氢化甘油来生产1,2-丙二醇的方法公开(公告)号：US08252962B2
公开(公告)日：2012-08-28
申请号：US12675900
申请日：2008-08-29
申请人： Jochem Henkelmann , Roman Prochazka , Oliver Bey , Stephan Maurer , Jochen Steiner , Heiko Urtel , Gerhard Theis , Peter Wahl , Petra Maier , Georg Mehrl
发明人： Jochem Henkelmann , Roman Prochazka , Oliver Bey , Stephan Maurer , Jochen Steiner , Heiko Urtel , Gerhard Theis , Peter Wahl , Petra Maier , Georg Mehrl
IPC分类号： C07C29/60
CPC分类号： B01J23/83 , B01J23/002 , B01J35/0006 , B01J37/0203 , B01J37/18 , B01J2523/00 , C07C29/60 , C07C67/03 , Y02E50/13 , C07C31/205 , C07C69/24 , C07C69/52 , B01J2523/17 , B01J2523/31 , B01J2523/3706
摘要： The present invention relates to a process for preparing 1,2-propanediol, in which a glycerol-containing stream, especially a stream obtained on the industrial scale in the production of biodiesel, is subjected to a hydrogenation in a two-stage reactor cascade.
摘要翻译： 本发明涉及一种制备1,2-丙二醇的方法，其中含有甘油的料流，特别是在生产生物柴油的工业规模上获得的物流在两级反应器级联中进行氢化。
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5.发明申请公开(公告)号：US20120065451A1
公开(公告)日：2012-03-15
申请号：US13228296
申请日：2011-09-08
申请人： GUIDO HENZE , Lothar Karrer , Heiko Urtel , Stephan Hatscher
发明人： GUIDO HENZE , Lothar Karrer , Heiko Urtel , Stephan Hatscher
CPC分类号： B01J20/3458 , B01J20/06 , B01J20/3078 , B01J20/3085 , B01J20/3483 , B01J2220/42 , C07C7/12 , C10G25/003 , C10G25/12 , C10G2400/20 , C07C11/06
摘要： The invention relates to a process for the regeneration of a copper-, zinc- and zirconium oxide-comprising adsorption composition after use thereof for the adsorptive removal of carbon monoxide from substance streams comprising carbon monoxide and at least one olefin, in which the adsorption composition is heated to a temperature in the range from 160 to 400° C. and a regeneration gas is passed through the adsorption composition, wherein the regeneration gas comprises 1000 to 3000 ppm of oxygen in an inert carrier gas.
摘要翻译： 本发明涉及一种用于在其使用之后再生含铜，锌和氧化锆的吸附组合物用于从包含一氧化碳和至少一种烯烃的物质流吸附除去一氧化碳的方法，其中吸附组合物 加热至160〜400℃的温度，再生气体通过吸附组合物，再生气体在惰性载气中含有1000〜3000ppm的氧气。
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6.发明授权Method for depletion of sulfur and/or compounds containing sulfur from a biochemically produced organic compound 有权从生物化学生产的有机化合物中消耗硫和/或含硫化合物的方法公开(公告)号：US07994370B2
公开(公告)日：2011-08-09
申请号：US12570170
申请日：2009-09-30
申请人： Matthias Hinrichs , Heiko Urtel , Jochen Steiner
发明人： Matthias Hinrichs , Heiko Urtel , Jochen Steiner
IPC分类号： C07C29/76
CPC分类号： C07C29/76 , B01D15/00 , B01J20/0233 , B01J20/0277 , B01J20/0281 , B01J20/0285 , B01J20/0288 , B01J20/0296 , B01J20/06 , B01J20/12 , B01J20/3204 , B01J20/3236 , C07C51/47 , C07C53/124 , C07C55/08 , C07C55/10 , C07C53/08 , C07C59/01 , C07C53/122 , C07C59/265 , C07C59/08 , C07C31/08
摘要： Method of reducing the concentration of sulfur and/or a sulfur-containing compound in a biochemically prepared organic compound by bringing the respective organic compound into contact with an adsorbent, wherein the adsorbent is a clay doped with silver and/or a silver compound.
摘要翻译： 通过使各有机化合物与吸附剂接触来降低生物化学制备的有机化合物中硫和/或含硫化合物的浓度的方法，其中吸附剂是掺杂有银和/或银化合物的粘土。
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公开(公告)号：US20090098037A1
公开(公告)日：2009-04-16
申请号：US12279368
申请日：2007-02-07
CPC分类号： B01J23/80 , B01D53/02 , B01D53/865 , B01D2255/20715 , B01D2255/20761 , B01D2257/502 , B01J20/06 , B01J20/3007 , B01J20/3078 , B01J20/3236 , B01J20/3433 , B01J20/3458 , B01J20/3483 , B01J2220/56
摘要： Carbon monoxide is removed from streams by adsorption on an adsorption composition which comprises copper, zinc and zirconium oxides and whose copper-comprising component has a degree of reduction, expressed as weight ratio of metallic copper to the sum of metallic copper and copper oxides, calculated as CuO, of at least 45% and not more than 75%.
摘要翻译： 通过在包含铜，锌和锆的氧化物的吸附组合物上吸附除去一氧化碳，并且其含铜组分具有减少程度，以金属铜与金属铜和铜氧化物之和的重量比表示，计算 作为CuO，为至少45％且不大于75％。
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公开(公告)号：US07507866B2
公开(公告)日：2009-03-24
申请号：US10589049
申请日：2005-02-08
申请人： Heiko Urtel , Markus Rösch , Andrea Haunert , Markus Schubert
发明人： Heiko Urtel , Markus Rösch , Andrea Haunert , Markus Schubert
CPC分类号： C07C29/149 , C07B41/02 , C07B53/00 , C07B2200/07 , C07C213/00 , C07D307/33 , C07C215/08 , C07C215/10 , C07C215/18 , C07C215/28 , C07C31/22 , C07C31/207 , C07C31/205 , C07C31/36 , C07C31/20 , C07C31/12
摘要： The present invention relates to a process for preparing optically active hydroxy-, alkoxy-, amino-, alkyl-, aryl- or chlorine-substituted alcohols or hydroxy carboxylic acids having from 3 to 25 carbon atoms or their acid derivatives or cyclization products by hydrogenating the correspondingly substituted optically active mono- or dicarboxylic acids or their acid derivatives in the presence of a catalyst whose active component consists of rhenium or of rhenium and comprises at least one further element having an atomic number of from 22 to 83, with the provisos that a. the at least one further element having an atomic number of from 22 to 83 is not ruthenium and b. in the case of the preparation of optically active 2-amino-, 2-chloro-, 2-hydroxy- and 2-alkoxy-1-alkanols by catalytically hydrogenating corresponding optically active 2-aminocarboxylic acids, 2-chlorocarboxylic acids, 2-hydroxycarboxylic acids and 2-alkoxycarboxylic acids or their acid derivatives, the at least one further element having an atomic number of from 22 to 83 is not palladium or platinum.
摘要翻译： 本发明涉及通过氢化制备光学活性羟基，烷氧基 - ，氨基 - ，烷基 - ，芳基 - 或氯取代的醇或具有3至25个碳原子的羟基羧酸或其酸衍生物或环化产物的方法 相应地取代的光学活性单羧酸或二羧酸或其酸衍生物在其活性组分由铼或铼组成的催化剂存在下，并且包含至少一种原子序数为22至83的另外的元素，条件是 一个。 原子序数为22〜83的至少一个以上的元素不是钌，而是b。 在通过催化氢化相应的光学活性2-氨基羧酸，2-氯羧酸，2-羟基羧酸的2-氨基 - ，2-氯 - ，2-羟基 - 和2-烷氧基-1-链烷醇的制备 酸和2-烷氧基羧酸或其酸衍生物，原子序数为22至83的至少一种另外的元素不是钯或铂。
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公开(公告)号：US09610567B2
公开(公告)日：2017-04-04
申请号：US13142786
申请日：2009-12-28
申请人： Guido Henze , Heiko Urtel , Martin Sesing , Martin Karches , Thorsten Von Fehren , Toni Kustura
发明人： Guido Henze , Heiko Urtel , Martin Sesing , Martin Karches , Thorsten Von Fehren , Toni Kustura
IPC分类号： C01B7/04 , B01J38/44 , B01J23/46 , B01J23/96 , B01J38/30 , B01J21/04 , B01J21/06 , B01J21/08 , B01J35/02
CPC分类号： B01J23/462 , B01J21/04 , B01J21/06 , B01J21/063 , B01J21/08 , B01J23/96 , B01J35/023 , B01J38/30 , B01J38/44 , C01B7/04 , Y02P20/584
摘要： The invention relates to a process for regenerating a hydrogen chloride oxidation catalyst comprising ruthenium oxide on a support material, which comprises the steps a) reduction of the catalyst in a gas stream comprising hydrogen chloride and optionally an inert gas at a temperature of from 100 to 800° C., b) recalcination of the catalyst in an oxygen-comprising gas stream at a temperature of from 150 to 800° C.
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10.发明申请METHOD FOR PRODUCING A SUPPORTED HYDROGENATION CATALYST HAVING INCREASED HYDROGENATION ACTIVITY 有权生产具有增加氢化活性的支持氢化催化剂的方法公开(公告)号：US20120245394A1
公开(公告)日：2012-09-27
申请号：US13510115
申请日：2010-11-16
申请人： Rolf Tompers , Heiko Urtel , Rolf Pinkos , Gerd-Dieter Tebben , Jens Heimann , Maria Guixa Guardia , Sabine Borchers
发明人： Rolf Tompers , Heiko Urtel , Rolf Pinkos , Gerd-Dieter Tebben , Jens Heimann , Maria Guixa Guardia , Sabine Borchers
IPC分类号： B01J21/18 , C07C29/141 , C07C29/149
CPC分类号： B01J23/78 , B01J23/58 , B01J23/72 , B01J23/80 , B01J23/83 , B01J37/0063 , B01J37/06 , C07C29/141 , C07C29/149 , C07C31/22 , C07C31/20
摘要： In a process for preparing a supported hydrogenation catalyst with increased hydrogenation activity, which comprises a hydrogenating metal and/or an oxide of a hydrogenating metal on an Al2O3-containing support material, said calcined supported hydrogenation catalyst is treated before or after the final shaping thereof and before use thereof in the hydrogenation with a base solution having a pH of >10 at a temperature in the range from 20 to 120° C. for 1 to 300 hours.
摘要翻译： 在含有Al 2 O 3的载体材料上制备含氢化金属和/或氢化金属的氢化物的氢化活性增加的负载型氢化催化剂的方法中，所述煅烧的负载氢化催化剂在其最终成型之前或之后进行处理 并且在使用之前，在温度为20〜120℃的pH为> 10的碱溶液中氢化1〜300小时。
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