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    Preparation of substituted aromatic amines
    1.
    发明授权
    Preparation of substituted aromatic amines 失效
    取代芳族胺的制备

    公开(公告)号：US5925790A

    公开(公告)日：1999-07-20

    申请号：US816612

    申请日：1997-03-13

    Applicant: Edward L. Wheeler ,  Russell E. Malz, Jr. ,  Mark W. Simon

    Inventor： Edward L. Wheeler ,  Russell E. Malz, Jr. ,  Mark W. Simon

    IPC: C07C209/10 ,  C07C211/55 ,  C07C209/02

    CPC classification number: C07C209/10

    Abstract: A method for producing aromatic amines such as N-phenyl-p-phenylenediamine is disclosed wherein an amine substituted aromatic such as aniline is oxidized with oxygen or hydrogen peroxide in the presence of a preferred trisodium pentacyano ferrate(II) complex containing various water soluble ligands, such as ammonia, mono alkyl amine, dialkyl amines, and trialkyl amines. The complex is subsequently catalytically reduced by hydrogenation using certain heterogeneous metal catalysts to yield the desired aromatic amine.

    Abstract translation: 公开了一种生产芳香胺如N-苯基 - 对苯二胺的方法，其中胺取代的芳族化合物如苯胺在优选的含有各种水溶性配体的五氰基高铁酸三钠（II）络合物的存在下用氧或过氧化氢氧化 ，例如氨，单烷基胺，二烷基胺和三烷基胺。 随后通过使用某些多相金属催化剂的氢化催化还原该络合物，得到所需的芳族胺。

    Elastomers and tire with N-alkyl-p-quinonediimino triazine stabilizers
    3.
    发明授权
    Elastomers and tire with N-alkyl-p-quinonediimino triazine stabilizers 失效
    弹性体和具有N-烷基对醌二亚氨基三嗪稳定剂的轮胎

    公开(公告)号：US5208280A

    公开(公告)日：1993-05-04

    申请号：US890496

    申请日：1992-05-28

    Applicant: Edward L. Wheeler

    Inventor： Edward L. Wheeler

    IPC: C07D251/70 ,  C08K5/3492

    CPC classification number: C07D251/70 ,  C08K5/34922

    Abstract: Novel N-alkyl-p-quinonediimino triazine compounds are disclosed which are useful as antiozonants for unsaturated high polymers. The compound may be prepared by oxidizing a 2,4,6-tris(N-alkyl-p-phenylenediamino) 1,3,5-triazine with a neutral or basic oxidizing agent and isolating the product.

    Abstract translation: 公开了可用作不饱和高聚物的抗臭氧剂的新型N-烷基 - 对 - 醌二亚氨基三嗪化合物。 该化合物可以通过用中性或碱性氧化剂氧化2,4,6-三（N-烷基 - 对苯二氨基）1,3,5-三嗪并分离产物来制备。

    1,5-Bis(3',5'-di-hydrocarbyl-4'-hydroxyphenyl)pentyl amines
    7.
    发明授权
    1,5-Bis(3',5'-di-hydrocarbyl-4'-hydroxyphenyl)pentyl amines 失效
    1,5-双（3 {40,5 {40-二烃基-4（40-羟基苯基）戊胺）

    公开(公告)号：US4098764A

    公开(公告)日：1978-07-04

    申请号：US719540

    申请日：1976-09-01

    Applicant: Richard A. Gencarelli ,  Edward L. Wheeler

    Inventor： Richard A. Gencarelli ,  Edward L. Wheeler

    IPC: C08K5/17 ,  C09K15/24 ,  C09K15/28 ,  C08K5/20 ,  C07C109/04

    CPC classification number: C09K15/28 ,  C08K5/17 ,  C09K15/24

    Abstract: This invention is directed to 1,5-bis(3',5'-dihydrocarbyl-4'-hydroxyphenyl)pentyl derivatives, including the 3-pentyl ester, amine and amide compounds. It also deals with the stabilization of organic materials by incorporating such compounds therein, either alone or in combination with a dialkyl 3,3'-thiodipropionate or a tri(alkaryl)phosphite.

    Abstract translation: 本发明涉及1,5-双（3'，5'-二烃基-4'-羟基苯基）戊基衍生物，包括3-戊基酯，胺和酰胺化合物。 它还涉及通过在其中引入这些化合物单独或与3,3'-硫代二丙酸二烷基酯或三（烷芳基）亚磷酸酯组合来处理有机材料的稳定化。

    Preparation of substituted aromatic amines
    10.
    发明授权
    Preparation of substituted aromatic amines 失效
    取代芳族胺的制备

    公开(公告)号：US06229035B1

    公开(公告)日：2001-05-08

    申请号：US09334252

    申请日：1999-06-16

    Applicant: Edward L. Wheeler ,  Mark W. Simon

    Inventor： Edward L. Wheeler ,  Mark W. Simon

    IPC: C07F1502

    CPC classification number: C07C209/64 ,  C07C209/02 ,  C07F15/025 ,  C07C211/55

    Abstract: A method for producing aromatic amines such as N-phenyl-p-phenylenediamine is disclosed wherein an amine substituted aromatic such as aniline is oxidized with oxygen or hydrogen peroxide in the presence of a preferred alkali metal pentacyano ferrate(II) complex made using water soluble ferrous salts with a non-oxidizing anion, preferably, ferrous sulfate, and containing various water soluble ligands, such as ammonia, mono alkyl amine, dialkyl amines, and trialkyl amines. The complex is subsequently catalytically reduced by hydrogenation using certain heterogeneous metal catalysts to yield the desired aromatic amine.

    Abstract translation: 公开了一种用于生产芳族胺如N-苯基 - 对苯二胺的方法，其中胺取代的芳族化合物如苯胺在优选的碱金属五氰基高铁酸盐（II）络合物存在下用氧或过氧化氢氧化， 含有非氧化阴离子的亚铁盐，优选硫酸亚铁，并含有各种水溶性配体，如氨，单烷基胺，二烷基胺和三烷基胺。 随后通过使用某些多相金属催化剂的氢化催化还原该络合物，得到所需的芳族胺。

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