Abstract:
The present invention relates to an electrorheological fluid composition comprising a dispersion of a plurality of solid particles in an electrically non-conducting liquid, the improvement comprising using as said solid particles a composition having the general formula:[(M).sup.p (H.sub.2 O).sub.x (OH).sub.y ].sup.q.sub.cd [A].sub.r.sub.d .multidot.B.sub.z .multidot.nH.sub.2 Owherein M is a metal cation or a mixture of metal cations at various ratios; p is the total valence of M and has a value of greater than zero; x is zero or has a value greater than zero, y is zero or has a value greater than zero, with the proviso that only one of x or y can be zero at any given time; q has a value of p minus y with the proviso that q has a value of at least one; c has a value of greater than zero; A is an anion or a mixture of anions at various ratios; r is the total valence of A with the proviso that r has a value of at least one; d has a value of greater than zero with the proviso that (q.times.c) is always equal to (r.times.d); B is an amino acid or a mixture of amino acids; z has a value of from 0.01 to 100; and n is a number from 0 to 15. The ER fluids of the present invention have greatly improved yield stress increasing potential stress transfer characteristics, and good dispersion stability.
Abstract:
A method for producing a carbonaceous powder which can be used as dielectric fine particles to be dispersed in an insulating oil to produce an electrorheological fluid is provided. The method comprises the steps of subjecting a starting organic material selected from the group consisting of coal, coal tar, coal tar pitch, liquefied coal, coke, petroleum, petroleum tar, petroleum pitch, and resins to a heat treatment at a maximum temperature of 300.degree. to 800.degree. C. to produce carbonaceous material; pulverizing and classifying the material to produce carbonaceous particles having a mean particle size of 0.5 to 40 .mu.m and a maximum particle size of up to 50 .mu.m; and subjecting the particles to an additional treatment at an elevated temperature and/or a reduced pressure, said additional treatment being carried out at a temperature lower than said maximum temperature of the heat treatment. The resulting carbonaceous powder may optionally be subjected to a further pulverization treatment.
Abstract:
Disclosed are electrorheological fluids including vermiculite treated with an amine salt, methods of making the same, propylene carbonate adsorbed on the solid phase, butyl benzoate added for the liquid phase, and methods of using frequency response of electrorheological fluids to vary apparent viscosity and to compensate for temperature.
Abstract:
The present invention relates to electroviscous liquids consisting essentially of(I) a polymer or polymer mixture,(II) an electrolyte dissolved in (I),.(III) optionally an additive miscible with the solution of (I) and (II),(IV) optionally a viscosity-increasing additive reacting with (I);(V) a dispersant and(VI) a non-aqueous dispersion medium.
Abstract:
In an electroviscous fluid comprising electrically insulating fluid as the dispersant and porous solid particles as the dispersed phase, at lease one substance selected from acid, salt and base and at least one substance selected from polyhydric alcohol and water, and further containing dispersing agent, antioxidant and/or corrosion inhibitor are added to obtain the better effects such as high responsiveness in wide temperature range up to high temperature, high reproducibility, excellent electroviscous effect and the higher durability.Therefore, the electroviscous fluid by this invention is useful, for example, for the control systems utilizing viscosity change, and it is capable to increase the control accuracy, particularly in the operation at high temperature.
Abstract:
An electro-rheological fluid comprising an electrically insulating liquid as the dispersion medium, porous solid particles as the dispersed phase, a dispersant, and a polyhydric alcohol having a boiling point of not lower than 250.degree. C., a melting point of not higher than 15.degree. C. and a viscosity of not higher than 300 cp (as measured at 20.degree. C.), or comprising an electrically insulating liquid as the dispersion medium, porous solid particles as the dispersed phase, a polyhydric alcohol and/or water, and an ashless dispersant.
Abstract:
Active analcime having a chemical composition comprising 60 to 95% by weight of SiO.sub.2, 0.3 to 20% by weight of Al.sub.2 O.sub.3 and 0.02 to 11% by weight of Na.sub.2 O based on the three components, an X-ray diffraction pattern inherent to analcime and a moisture adsorption of 5 to 30% by weight as determined under conditions of a relative humidity of 90%, an ambient temperature of 25.degree. C. and a standing time of 24 hours, wherein individual particles have a tetracosahedral or angle-rounded tetracosahedral particulate shape and the primary particle size of 0.1 to 50 .mu.m as determined according to the electron microscope method. This active analcime is obtained by acid-treating a zeolite by using an acid in an amount of 0.1 to 1.2 molar equivalents per mole of the sum of Al.sub.2 O.sub.3 and Na.sub.2 O components in the zeolite so that the crystal structure of analcime is left.Amorphous silica which is obtained by an acid treatment of a zeolite and is X-ray diffractometrically substantially amorphous, wherein individual particles have a tetracosahedral or angle-rounded tetracosahedral particulate shape and the primary particle size is 0.1 to 50 .mu.m as determined according to the electron microscope method. This amorphous silica is obtained by acid-treating a zeolite so that Al.sub.2 O.sub.3 and Na.sub.2 O components are removed in amounts sufficient to render the zeolite amorphous.
Abstract translation:具有根据三种组分包含60至95重量%的SiO 2,0.3至20重量%的Al 2 O 3和0.02至11重量%的Na 2 O的化学组成的活性分析,分析固有的X射线衍射图案和 在相对湿度为90%,环境温度为25℃,停留时间为24小时的条件下测定的水分吸附为5〜30重量%,其中单个颗粒具有四面体或角圆形四面体颗粒形状 一次粒径为0.1〜50μm,根据电子显微镜法测定。 通过使用沸石中每摩尔Al 2 O 3和Na 2 O成分的总和为0.1〜1.2摩尔当量的酸,对沸石进行酸处理,得到沸石的结晶结构,得到该活性分析物。 通过沸石的酸处理得到的无定形二氧化硅,X射线衍射法基本上是无定形的,其中单个颗粒具有四面体或角圆四面体颗粒形状,一次粒径为0.1-50μm,如根据 电子显微镜法。 该无定形二氧化硅通过酸处理沸石获得,使得除去足够使沸石无定形的Al 2 O 3和Na 2 O组分。
Abstract:
Disclosed are electrorheological fluids having ceramic particles of high ion conductivity and a nonconducting or dielectric fluid. The high ion conductive particle may be a material having the formula A.sub.x (L.sub.x/2 Sn.sub.1-(x/2))O.sub.4, where A is a monovalent ion, such as a material comprising at least one selected from the group consisting of Na and K; and x ranges from 0 to 1; and L is a divalent ion, such as a material comprising at least one selected from the group consisting of Mg, Ca and Zn. The liquid phase may include a silicone fluid or mineral oil. In the case of a mineral oil, the oil may also include an amine-terminated polyester to improve stability of the fluid.
Abstract:
An electro-rheological fluid which comprises a solid particulate substance contained in a hydrophobic vehicle which is liquid at atmospheric pressure at least at temperatures below 50.degree. C. and which comprises a compound of the formula:(X).sub.n --Ar[Q--Z].sub.pwherein:Ar represents an aromatic nucleus;Q represents an oxygen or a sulphur atom, or a group of the formula CY.sub.1 Y.sub.2, SO, SO.sub.2, SiF.sub.2, --OSi(Y.sub.1 Y.sub.2)O-- in which Y.sub.1 and Y.sub.2, which may be the same or different, each represents a halogen or a fluorine atom or an alkyl group;X represents a halogen atom, or a nitro group, a thio(substituted or unsubstituted hydrocarbyl) group or a substituted or unsubstituted hydrocarbyl group;Z represents a substituted or unsubstituted aliphatic or alicyclic group; andn and p, which may be the same or different, each represent a number of at least 1, (n+p) not being greater than the total number of substituted sites on the aromatic nucleus, with the proviso that, where n is greater than 1, not all the n X groups need be the same and that the, or at least one of the, X group(s) represents a halogen atom; and that, where p is greater than 1, not all the pQ groups nor the pZ groups need to be the same.
Abstract:
Electrorheological fluids display swift and reversible increase in apparent viscosity under application of an electrical potential difference to the fluid, and are composed generally of electrical insulating oily medium and dielectric fine-particles dispersed therein.At the initial stage of development, electrorheological fluids are prepared by dispersing water-carrying hydrophilic particulates in an electrical insulating oily medium. However, there are such defects as a restriction on usable temperatures so as to avoid evaporation or freezing of the water, an extreme increase in the electric current flow as the temperature raises, inferior stability caused by transfer of water etc.It is an object of the persent invention is to provide nonaqueous type electrorheological fluids having improved electrorheological property.The electrorheological fluid of the present invention is a nonaqueous type electrorheological fluid which comprises organic or inorganic particulates containing not more than 1 wt. % of water and dispersed in an oily medium superior in electrical insulation, wherein the improvement is that said fluid comprises from 0.001 wt. % to 10 wt. % of a compound having a functional group containing at least one atom selected from the group consisted of oxygen atom, nitrogen atom, sulfur atom and phosphorous atom.