CONJUGATED POLYMERS WITH CARBONYL SUBSTITUTED THIENO[3,4-B]THIOPHENE UNITS FOR POLYMER SOLAR CELL ACTIVE LAYER MATERIALS
    46.
    发明申请
    CONJUGATED POLYMERS WITH CARBONYL SUBSTITUTED THIENO[3,4-B]THIOPHENE UNITS FOR POLYMER SOLAR CELL ACTIVE LAYER MATERIALS 有权
    带有碳取代的三联[3,4-B]聚合物太阳能电池活性层材料的共聚物聚合物

    公开(公告)号:US20110017956A1

    公开(公告)日:2011-01-27

    申请号:US12509359

    申请日:2009-07-24

    Abstract: In one embodiment of the present disclosure, a series of conjugated polymers used, among other things, as polymer solar cell or polymer photovoltaic device active layer materials, is provided. In one embodiment, the conjugated polymers have the general structure and formula shown in (I), wherein: R1 and R2 are independently selected from proton, halogens, alkyls, aryls and substituted aryls; Ar is selected from the group consisting of monocyclic, bicyclic and polycyclic arylene, or monocyclic, bicyclic and polycyclic heteroarylene. In another embodiment, the conjugated photovoltaic polymers are comprised of repeated units having the general structure of formula (II), wherein, R1, R2, R3, R4, R5, and R6 are independently selected from proton, alkyls, halogens, aryls, substituted aryls, and other kinds of substituents. Synthesis methods of several polymers of the present disclosure are provided, and absorption spectra and electrochemical cyclic voltammetry data of some polymers, and also the photovoltaic properties of the polymers in this present disclosure are also provided.

    Abstract translation: 在本公开的一个实施方案中,提供了一系列共轭聚合物,其中包括聚合物太阳能电池或聚合物光伏器件活性层材料。 在一个实施方案中,共轭聚合物具有(I)所示的一般结构和式,其中:R 1和R 2独立地选自质子,卤素,烷基,芳基和取代的芳基; Ar选自单环,双环和多环亚芳基,或单环,双环和多环亚杂芳基。 在另一个实施方案中,共轭光伏聚合物由具有通式(II)的通式结构的重复单元组成,其中R1,R2,R3,R4,R5和R6独立地选自质子,烷基,卤素,芳基,取代的 芳基和其它种类的取代基。 提供本公开的几种聚合物的合成方法,并且还提供了一些聚合物的吸收光谱和电化学循环伏安法数据,以及本公开内容中聚合物的光伏特性。

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