公开(公告)号：US20140084220A1

公开(公告)日：2014-03-27

申请号：US14004563

申请日：2012-03-09

Applicant: Takuya Inagaki ,  Hiromasa Shibuya ,  Takashi Sugioka ,  Takafumi Izawa ,  Yasushi Morihara ,  Atsuhiro Nakahara ,  Akio Fujita ,  Hiroyuki Ogi

Inventor： Takuya Inagaki ,  Hiromasa Shibuya ,  Takashi Sugioka ,  Takafumi Izawa ,  Yasushi Morihara ,  Atsuhiro Nakahara ,  Akio Fujita ,  Hiroyuki Ogi

IPC: H01L51/00

CPC classification number: H01L51/0043 ,  C08G61/126 ,  C08G2261/124 ,  C08G2261/126 ,  C08G2261/1428 ,  C08G2261/3243 ,  C08G2261/3246 ,  C08G2261/344 ,  C08G2261/364 ,  C08G2261/414 ,  C08G2261/91 ,  H01L51/0036 ,  H01L51/0039 ,  H01L51/4253

Abstract: Provided is a conjugated block copolymer that is capable of morphology control and that can achieve superior conversion efficiency. A π-electron conjugated block copolymer contiguously or non-contiguously bonding polymer block (A) involving a monomer unit having in a portion of a chemical structure at least one heteroaryl skeleton selected from a thiophene, a fluorine, a carbazole, a dibenzosilole and a dibenzogermole; and a polymer block (B) involving a monomer unit similarly having at least one heteroaryl skeleton; wherein the polymer block (A) comprises a homopolymer block of a monomer unit having a substituent RnA that is an alkoxy group or an alkyl group having 1-18 carbon atoms, and the polymer block (B) comprises a copolymer block of at least two different each other types of monomer units having substituent RnB selected from an alkoxy group or an alkyl group having 1-18 carbon atoms, which may be substituted with an alkoxy group, a halogen atom, a hydroxyl group, an amino group, a thiole group, a silyl group, an ester group, an aryl group, hetero aryl group.

Abstract translation: 提供能够形态控制并且可以实现优异的转化效率的共轭嵌段共聚物。 涉及具有化学结构部分中的至少一个选自噻吩，氟，咔唑，二苯并噻唑的杂芳基骨架的单体单元的邻苯二胺共轭嵌段共聚物连续或非连续键合聚合物嵌段（A） 二苯并呋喃; 和包含类似地具有至少一个杂芳基骨架的单体单元的聚合物嵌段（B）; 其中所述聚合物嵌段（A）包含具有取代基RnA（其为烷氧基或具有1-18个碳原子的烷基）的单体单元的均聚物嵌段，并且所述聚合物嵌段（B）包含至少两个 具有可以被烷氧基，卤素原子，羟基，氨基，硫代基团取代的具有1-18个碳原子的烷氧基或烷基的取代基RnB的不同类型的单体单元 甲硅烷基，酯基，芳基，杂芳基。

公开(公告)号：US20140166942A1

公开(公告)日：2014-06-19

申请号：US14008654

申请日：2012-03-30

Applicant: Takafumi Izawa ,  Hiromasa Shibuya ,  Takashi Sugioka ,  Takuya Inagaki ,  Yasushi Morihara ,  Atsuhiro Nakahara ,  Akio Fujita ,  Hiroyuki Ogi

Inventor： Takafumi Izawa ,  Hiromasa Shibuya ,  Takashi Sugioka ,  Takuya Inagaki ,  Yasushi Morihara ,  Atsuhiro Nakahara ,  Akio Fujita ,  Hiroyuki Ogi

IPC: H01L51/00

CPC classification number: H01L51/0036 ,  C08G61/124 ,  C08G61/126 ,  C08G2261/126 ,  C08G2261/3223 ,  C08G2261/3241 ,  C08G2261/3243 ,  C08G2261/3246 ,  C08G2261/344 ,  C08G2261/91 ,  C08K3/045 ,  H01L51/0043 ,  H01L51/4253 ,  C08L65/00

Abstract: Provide are: a conjugated block copolymer capable of increasing the amount of optical absorption by a photoelectric conversion active layer and controlling the morphology thereof and capable of achieving excellent photoelectric conversion efficiency; and a photoelectric conversion element comprising a composition including an electron accepting material and this kind of conjugated block polymer. A π-electron conjugated block copolymer comprising: a polymer block (A) which involving a monomer unit having at least one heteroaryl skeleton selected from the group consisting of a fused π-conjugated skeleton, a fluorene, a carbazole, a dibenzosilole and a dibenzogermole containing at least one thiophene ring in a part of a chemical structure thereof; and a polymer block (B) involving a monomer unit of a thiophene-2,5-diyl group having a substituent at least at a 3-position thereof.

Abstract translation: 提供：能够增加光电转换活性层的光吸收量并控制其形态并能够获得优异的光电转换效率的共轭嵌段共聚物; 和包含电子接受材料和这种共轭嵌段聚合物的组合物的光电转换元件。 一种电子共轭嵌段共聚物，其包含：聚合物嵌段（A），其包含具有至少一个杂芳基骨架的单体单元，所述杂芳基骨架选自稠合和共轭骨架，芴，咔唑，二苯并噻唑和 在其化学结构的一部分中含有至少一个噻吩环的二苯并茂莫; 和包含至少在其3位具有取代基的噻吩-2,5-二基的单体单元的聚合物嵌段（B）。

公开(公告)号：US20140124710A1

公开(公告)日：2014-05-08

申请号：US14008823

申请日：2012-03-30

Applicant: Takafumi Izawa ,  Hiromasa Shibuya ,  Takashi Sugioka ,  Takuya Inagaki ,  Yasushi Morihara ,  Atsuhiro Nakahara ,  Akio Fujita ,  Hiroyuki Ogi

Inventor： Takafumi Izawa ,  Hiromasa Shibuya ,  Takashi Sugioka ,  Takuya Inagaki ,  Yasushi Morihara ,  Atsuhiro Nakahara ,  Akio Fujita ,  Hiroyuki Ogi

IPC: H01L51/00 ,  H01L51/44

CPC classification number: H01L51/0036 ,  C08G61/123 ,  C08G61/124 ,  C08G61/126 ,  C08G2261/126 ,  C08G2261/1428 ,  C08G2261/3223 ,  C08G2261/3243 ,  C08G2261/3246 ,  C08G2261/344 ,  C08G2261/414 ,  C08G2261/91 ,  C08K3/045 ,  H01L51/0043 ,  H01L51/0094 ,  H01L51/4253 ,  H01L51/44 ,  C08L65/00

Abstract: Provided are: a conjugated block copolymer capable of increasing the amount of optical absorption by a photoelectric conversion active layer and controlling the morphology thereof and capable of achieving excellent photoelectric conversion efficiency; and a photoelectric conversion element comprising a composition including an electron accepting material using this kind of conjugated block polymer.A π-electron conjugated block copolymer comprises: a polymer block (A) and a polymer block (B), each of which involves a monomer unit having at least one fused π-conjugated skeleton including at least one thiophene ring in one part of the chemical structure thereof, the polymer block (A) and the polymer block (B) have different monomer units from each other.

Abstract translation: 提供：能够增加光电转换活性层的光吸收量并控制其形态并能够获得优异的光电转换效率的共轭嵌段共聚物; 以及包含使用这种共轭嵌段聚合物的包含电子接受材料的组合物的光电转换元件。 一种电子共轭嵌段共聚物包括：聚合物嵌段（A）和聚合物嵌段（B），它们各自包含具有至少一个稠合的共轭骨架的单体单元，其包含至少一个噻吩环的一部分 的化学结构，聚合物嵌段（A）和聚合物嵌段（B）彼此具有不同的单体单元。