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    Method For The Preparation Of X-Ray Amorphous Or Weakly Crystalline Metal Oxide Fluorides And New Uses Thereof
    21.
    发明申请
    Method For The Preparation Of X-Ray Amorphous Or Weakly Crystalline Metal Oxide Fluorides And New Uses Thereof 审中-公开
    用于制备X射线非晶态或弱结晶金属氧化物氟化物的方法及其新用途

    公开(公告)号：US20080274037A1

    公开(公告)日：2008-11-06

    申请号：US11720796

    申请日：2005-12-05

    申请人： Udo Gross ,  Erhard Kemnitz ,  Stephan Ruediger

    发明人： Udo Gross ,  Erhard Kemnitz ,  Stephan Ruediger

    IPC分类号： C01F7/50 ,  C01B11/24

    CPC分类号： C01F5/28 ,  B01J27/12 ,  B01J27/125 ,  B01J27/138 ,  B01J35/002 ,  B01J35/1019 ,  C01B9/08 ,  C01F7/50 ,  C01P2002/02 ,  C01P2006/12 ,  C01P2006/14 ,  C03C17/22 ,  C03C2217/285

    摘要： The present invention is related to a method for preparing an X-ray amorphous or weakly crystalline metal oxide fluoride of a composition represented by the formula Ma+ObFc comprising the steps of b) providing a precursor, whereby the precursor is a fluorinated metal compound having a composition which is represented by the formula Ma+F(a−d)BdLxb) converting the precursor into an metal oxide/hydroxide fluoride; and c) calcinating the metal oxide/hydroxide fluoride having the formula Ma+OcHfFc to generate the X-ray amorphous or weakly crystalline metal oxide fluoride of the formula Ma+ObFc, whereby M is selected from the group comprising metals of the first, second, third and fourth main group and any subgroup of the periodic table; B is a group or an anion which is selected from the group comprising alkoxide, enolates, alkyl, chloride, bromide, iodide, nitrate, and organic acid anions; B is preferably an alkoxy group; L is a solvent other than water; a is any integer of 1, 2, 3, 4, 5 or 6, preferably 2 or 3; and b and c are any numbers obeying the formula b/2+c=a, and c is 0.1b to 10b; d is a number between 0 and 0.8a, preferable between 0.1 and 0.3a; e is (a−c+f)/2; f is a number between 0 and (a−c); and x is between 0 and 6.

    摘要翻译： 本发明涉及一种制备由下式表示的组合物的X射线无定形或弱结晶金属氧化物氟化物的方法： c）包括以下步骤：b）提供前体，由此所述前体是具有由下式表示的组成的氟化金属化合物：（a） b）将前体转化为金属氧化物/氢氧化物氟化物; 和c）将具有下式的金属氧化物/氢氧化物氟化物煅烧：将式M a -O + 产生式M a O b O b C c C的X射线无定形或弱结晶金属氧化物氟化物，其中M选自 包括第一，第二，第三和第四主族的金属和周期表的任何亚组; B是选自醇盐，烯醇化物，烷基，氯化物，溴化物，碘化物，硝酸盐和有机酸阴离子的基团或阴离子; B优选为烷氧基; L是水以外的溶剂; a是1,2,3,4,5或6，优选2或3的整数; b和c是符合公式b / 2 + c = a的任何数字，c是0.1b〜10b; d是0和0.8a之间的数，优选在0.1和0.3a之间; e为（a-c + f）/ 2; f是0和（a-c）之间的数字; x在0和6之间。

    Processes for the recovery and recycling of boron trifluoride or complexes thereof
    23.
    发明授权
    Processes for the recovery and recycling of boron trifluoride or complexes thereof 有权
    回收利用三氟化硼或其配合物的方法

    公开(公告)号：US07235509B2

    公开(公告)日：2007-06-26

    申请号：US10532726

    申请日：2003-10-27

    申请人： Yoshio Hironaka ,  Hiroki Sekiguchi ,  Yukio Yoshida ,  Toshiyuki Tsubouchi

    发明人： Yoshio Hironaka ,  Hiroki Sekiguchi ,  Yukio Yoshida ,  Toshiyuki Tsubouchi

    IPC分类号： B01J31/00

    CPC分类号： C08F6/02 ,  B01J27/12 ,  B01J27/32 ,  B01J38/54 ,  C01B35/061 ,  C08F10/00 ,  Y02P20/584 ,  C08F4/14

    摘要： The invention provides processes for the recovery of a catalyst which are to be applied to the reactions wherein boron trifluoride or a complex thereof is used as the catalyst, that is, (I) a process for the recovery of a catalyst which comprises using as the reaction solvent a solvent containing a hydrofluorocarbon compound and/or an oxygenic hydrofluorocarbon compound and, after the completion of the reaction, separating the reaction solvent from the reaction mixture; and (II) a process for the recovery of a catalyst which comprises extracting boron trifluoride or a complex thereof from the reaction mixture after the completion of the reaction by using a hydrofluorocarbon compound and/or an oxygenic hydrofluorocarbon compound as the extracting solvent. According to the processes, boron trifluoride or complexes thereof used as catalyst can be easily separated from the reaction mixtures and re-used.

    摘要翻译： 本发明提供回收催化剂的方法，该催化剂应用于其中使用三氟化硼或其络合物作为催化剂的反应，即（I）回收催化剂的方法，该方法包括使用 反应溶剂含有氢氟烃化合物和/或含氧氟碳化合物的溶剂，反应完成后，将反应溶剂与反应混合物分离; 和（II）回收催化剂的方法，其包括通过使用氢氟烃化合物和/或含氧氢氟烃化合物作为萃取溶剂，在反应完成后从反应混合物中提取三氟化硼或其配合物。 根据该方法，用作催化剂的三氟化硼或其配合物可以容易地从反应混合物中分离并重新使用。

    Method for producing metal fluoride materials
    28.
    发明申请
    Method for producing metal fluoride materials 失效
    生产金属氟化物材料的方法

    公开(公告)号：US20040126309A1

    公开(公告)日：2004-07-01

    申请号：US10662961

    申请日：2003-09-15

    申请人： Platinum Research Organization LLC

    发明人： F. Conrad Greer

    IPC分类号： C01B009/08

    CPC分类号： B01J27/12 ,  B01J35/0013 ,  B01J35/006 ,  C01B7/035 ,  C01B9/08 ,  C01G1/06 ,  C01G49/10

    摘要： A method of producing nano metal fluoride powders comprising the steps of mixing an aqueous or organic continuous phase comprising at least one metal cation salt with a hydrophilic or organic polymeric disperse phase forming a metal cation salt/polymer gel and then treating said gel with anhydrous hydrofluoric acid to convert said metal cation salt to metal cation fluoride and heat treating the gel at a temperature sufficient to drive off water and/or organics within the gel, leaving a residue of nano-size metal fluoride powder.

    摘要翻译： 一种制备纳米金属氟化物粉末的方法，包括以下步骤：将包含至少一种金属阳离子盐的水性或有机连续相与形成金属阳离子盐/聚合物凝胶的亲水或有机聚合物分散相混合，然后用无水氢氟酸处理所述凝胶 酸以将所述金属阳离子盐转化为金属阳离子氟化物，并在足以驱除凝胶内的水和/或有机物的温度下热处理凝胶，留下纳米尺寸金属氟化物粉末的残余物。

    Process for the manufacture of 1,1,1,3,3-pentafluoropropene, 2-chloro-pentafluoropropene and compositions comprising saturated derivatives thereof
    29.
    发明授权
    Process for the manufacture of 1,1,1,3,3-pentafluoropropene, 2-chloro-pentafluoropropene and compositions comprising saturated derivatives thereof 失效
    用于制备1,1,1,3,3-五氟丙烯，2-氯 - 五氟丙烯的方法和包含其饱和衍生物的组合物

    公开(公告)号：US06548720B2

    公开(公告)日：2003-04-15

    申请号：US10061002

    申请日：2002-01-30

    申请人： William H. Manogue ,  V. N. Mallikarjuna Rao ,  Allen Capron Sievert ,  Steven H. Swearingen

    发明人： William H. Manogue ,  V. N. Mallikarjuna Rao ,  Allen Capron Sievert ,  Steven H. Swearingen

    IPC分类号： C07C1700

    CPC分类号： C07C19/08 ,  B01J23/868 ,  B01J27/12 ,  B01J27/132 ,  B01J37/0009 ,  B01J37/06 ,  C07C17/00 ,  C07C17/087 ,  C07C17/21 ,  C07C17/23 ,  C07C17/354 ,  C07C17/38 ,  C07C43/12 ,  Y02P20/582 ,  C07C21/18

    摘要： A process is disclosed for producing the pentfluropropenes of the formula CF3CX═CF2, where X is H or Cl. The process involves hydrodehalogenating CF3CCl2CF3 with hydrogen at an elevated temperature in the vapor phase over a catalyst comprising an elemental metal, metal oxide, metal halide and/or metal oxyhalide (the metal being copper, nickel, chromium and the halogen of said halides and said oxyhalides being fluorine and/or chlorine. Processes for producing the hydrofluorocarbons CF3CH2CHF2, CF3CHFCF3 and CF3CH2CF3 are also disclosed which involve (a) hydrodehalogenating CF3CCl2CF3 with the hydrogen as indicated above to produce a product comprising CF3CCl═CF2, CF3CH═CF2, HCl and HF; and (b) either reacting the CF3CCl═CF2 and/or CF3CH═CF2 produced in (a) in the vapor phase with hydrogen to produce CF3CH2CHF2, reacting CF3CCl═CF2 produced in (a) with HF to produce CF3CHFCF3, or reacting the CF3CH═CF2produced in (a) with HF to produce CF3CH2CF3. Azeotrope compositions of CF3CHFCH3 with HF, and a process for recovering HF from a product mixture comprising HF and CF3CHFCF3 are also disclosed. Also disclosed are compositions and a process for producing compositions comprising (c1) CF3CHFCF3, CF3CH2CF3 or CHF2CH2CF3 and (c2) at least one saturated halogenated hydrocarbon and/or ether having the formula: CnH2n+2−a−bClaFbOc wherein n is an integer from 1 to 4, a is an integer from 0 to 2n+1, b is an integer from 1 to 2n+2−a, and c is 0 or 1, provided that when c is 1 then n is an integer from 2 to 4, and provided that component (c2) does not include the selected component (c1) compound, wherein the molar ratio of component (c2) to component (c1) is between about 1:99 and a molar ratio of HF to component (c1) in an azeotrope or azeotrope-like composition of component (c1) with HF. The process involves (A) combining (i) the azeotropic composition with (ii) the fluorination precursor to component (c2); and (B) reacting a sufficient amount of the HF from the azeotrope or azeotrope-like composition(i) with precursor component (ii) to provide a composition containing components (c1) and (c2) in the desired ratio. The compositions include at least two (c1) compounds, at least one of which is an ether.

    摘要翻译： 公开了制备式CF 3 C X = CF 2的五氟丙烯的方法，其中X是H或Cl。 该方法包括在气相中在升高的温度下在含有元素金属，金属氧化物，金属卤化物和/或金属卤氧化物（金属为铜，镍，铬和所述卤化物的卤素和所述卤化物的催化剂）的催化剂中用氢气脱氢CF 3 CCl 2 CF 3 还公开了用于制备氢氟烃CF 3 CH 2 CHF 2，CF 3 CHFCF 3和CF 3 CH 2 CF 3的方法，其涉及（a）如上所述用氢气将CF 3 CCl 2 CF 3加氢脱卤以产生包含CF 3 CCl = CF 2，CF 3 CH = CF 2，HCl和HF的产物 将（a）中产生的CF 3 CCl = CF 2和/或CF 3 CH = CF 2与氢气反应以产生CF 3 CH 2 CHF 2，使（a）中制备的CF 3 CCl = CF 2与HF反应产生CF 3 CHFCF 3，或使 CF3CH = CF2，在HF中产生CF 3 CH 2 CF 3，CF 3 CHFCH 3与HF的共沸组合物，以及从含有HF和CF 3 CHFCF 3的产物混合物中回收HF的方法也被公开 。 还公开了组合物和制备组合物的方法，其包含（c1）CF 3 CHFCF 3，CF 3 CH 2 CF 3或CHF 2 CH 2 CF 3和（c2）至少一种具有下式的饱和卤代烃和/或醚：CnH2n + 2-a-bClaFbOc其中n是 如图1〜图4所示，a为0〜2n + 1的整数，b为1〜2n + 2-a的整数，c为0或1，条件是当c为1时，n为2〜4的整数 ，并且条件是组分（c2）不包括选择

    PROCESSES FOR THE MANUFACTURE OF 1,1,1,3,3- PENTAFLUOROPROPENE, 2-CHLORO-PENTAFLUOROPROPENE AND COMPOSITIONS COMPRISING SATURATED DERIVATIVES THEREOF
    30.
    发明申请
    PROCESSES FOR THE MANUFACTURE OF 1,1,1,3,3- PENTAFLUOROPROPENE, 2-CHLORO-PENTAFLUOROPROPENE AND COMPOSITIONS COMPRISING SATURATED DERIVATIVES THEREOF 失效

    公开(公告)号：US20020035300A1

    公开(公告)日：2002-03-21

    申请号：US09367900

    申请日：1999-08-19

    发明人： V.N. MALLIKARJUNA RAO ,  ALLEN CAPRON SIEVERT

    IPC分类号： C07C017/00

    CPC分类号： C07C19/08 ,  B01J23/868 ,  B01J27/12 ,  B01J27/132 ,  B01J37/0009 ,  B01J37/06 ,  C07C17/00 ,  C07C17/087 ,  C07C17/21 ,  C07C17/23 ,  C07C17/354 ,  C07C17/38 ,  C07C43/12 ,  Y02P20/582 ,  C07C21/18

    摘要： A process is disclosed for producing the pentafluoropropenes of the formula CF 3 CXnullCF 2 , where X is H or Cl. The process involves hydrodehalogenating CF 3 CCl 2 CF 3 with hydrogen at an elevated temperature in the vapor phase over a catalyst comprising an elemental metal, metal oxide, metal halide and/or metal oxyhalide (the metal being copper, nickel, chromium and the halogen of said halides and said oxyhalides being fluorine and/or chlorine). Processes for producing the hydrofluorocarbons CF 3 CH 2 CHF 2, CF 3 CHFCF 3 and CF 3 CH 2 CF 3 are also disclosed which involve (a) hydrodehalogenating CF 3 CCl 2 CF 3 with hydrogen as indicated above to produce a product comprising CF 3 CC1nullCF 2, CF 2 CHnullCF 2 , HCl and HF; and (b) either reacting the CF 3 CClnullCF 2 and/or CF 3 CHnullCF 2 produced in (a) in the vapor phase with hydrogen to produce CF 3 CH 2 CHF 2 reacting the CF 3 CC 1nullCF 2 produced in (a) with HF to produce CF 3 CHFCF 3, or reacting the CF 3 CHnullCF 2 produced in (a) with HF to produce CF 3 CH 2 CF 3 . Azeotrope compositions of CF 3 CHFCF 3 with HF, and a process for recovering HF from a product mixture comprising HF and CF 3 CHFCF 3 are also disclosed. Also disclosed are compositions and a process for producing compositions comprising (c1) CF 3 CHFCF 3 , CF 3 CH 2 CF 3 or CHF 2 CH 2 CF 3 and (c2) at least one saturated halogenated hydrocarbon and/or ether having the formula: C n H 2nnull2nullanullb Cl a F b O c wherein n is an integer from 1 to 4, a is an integer from 0 to 2nnull1, b is an integer from 1 to 2nnull2nulla, and c is 0 or 1, provided that hen c is 1 then n is an integer from 2 to 4 and provided that component (c2) does not include the selected component (c1) compound, wherein the molar ratio of component (c2) to component (c1) is between about 1:99 and a molar ratio of HF to component (c1) in an azeotrope or azeotrope-like composition of component (c1) with HF. The process involves (A) combining (i) the azeotropic composition with (ii) the fluorination precursor to component (c2); and (B) reacting a sufficient amount of the HF from the azeotrope or azeotrope-like composition (i) with precursor component (ii) to provide a composition containing components (c1) and (c2) in the desired ratio. The compositions include at least two (c1) compounds, at least one of which is an ether.