摘要:
A hydrogen sulphide adsorbent is formed from an alkali metal nanotitanate having a portion of the alkali metal cations exchanged with metal cations reactive with hydrogen sulphide, and heat treated. A method for producing the adsorbent includes the steps of mixing an alkali metal nanotitanate in powder form into an aqueous metal cation solution to produce a slurry, which is subsequently dehydrated to produce a powder, which is heat treated. A low temperature method for removing hydrogen sulphide from a gaseous mixture involves exposing the gaseous mixture to the aforementioned adsorbent, at a temperature less than 250° C. The adsorbent maintains a high adsorption capacity over a range of activation temperatures and humidity conditions.
摘要:
Provided is a carbon dioxide adsorbent with which large quantities of carbon dioxide can be adsorbed and removed even under conditions having low carbon dioxide concentrations such as when under subatmospheric pressure or when under an environment having a carbon dioxide partial pressure of less than atmospheric pressure, said carbon dioxide adsorbent exhibiting excellent adsorption activity. A carbon dioxide adsorbent including at least a ZSM-5 zeolite including barium (Ba) or strontium (Sr) is characterized in that the ZSM-5 zeolite includes M-O-M bonds (M being Ba or Sr, and O being oxygen). The M-O-M bonds interact strongly with carbon dioxide, and thus carbon dioxide can be adsorbed effectively and in large volumes even under conditions having low carbon dioxide concentrations.
摘要:
The present invention relates to a process for the preparation of a zeolitic material comprising the steps of: (1) providing a mixture comprising one or more sources for YO2 and one or more alkenyltrialkylammonium cation R1R2R3R4N+-containing compounds as structure directing agent; and (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material; wherein Y is a tetravalent element, and wherein R1, R2, and R3 independently from one another stand for alkyl; and R4 stands for alkenyl, as well as to zeolitic materials which may be obtained according to the inventive process and to their use.
摘要翻译:本发明涉及一种制备沸石材料的方法,包括以下步骤:(1)提供包含一种或多种YO 2源和一种或多种烯基三烷基铵阳离子R 1 R 2 R 3 R 4 N +化合物作为结构导向剂的混合物; 和(2)使步骤(1)中获得的混合物结晶以获得沸石材料; 其中Y是四价元素,并且其中R 1,R 2和R 3彼此独立地代表烷基; 并且R4代表烯基,以及可以根据本发明方法获得的沸石材料及其用途。
摘要:
The present invention relates to a process for the preparation of a zeolitic material comprising the steps of: (1) providing a mixture comprising one or more sources for YO2 and one or more alkenyltrialkylammonium cation R1R2R3R4N+-containing compounds as structure directing agent; and (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material; wherein Y is a tetravalent element, and wherein R1, R2, and R3 independently from one another stand for alkyl; and R4 stands for alkenyl, as well as to zeolitic materials which may be obtained according to the inventive process and to their use.
摘要翻译:本发明涉及一种制备沸石材料的方法,包括以下步骤:(1)提供包含一种或多种YO 2源和一种或多种烯基三烷基铵阳离子R 1 R 2 R 3 R 4 N +化合物作为结构导向剂的混合物; 和(2)使步骤(1)中获得的混合物结晶以获得沸石材料; 其中Y是四价元素,并且其中R 1,R 2和R 3彼此独立地代表烷基; 并且R4代表烯基,以及可以根据本发明方法获得的沸石材料及其用途。
摘要:
A composition for an outside surface, includes at least a mixture of a microporous mineral of the zeolite type and a salt in order to allow for an adsorption and/or desorption effect, the composition including a permeable film at least partially coating the microporous mineral.
摘要:
Provided is a radioactive iodine adsorbent capable of adsorbing radioactive iodine more effectively than in the conventional art, and removing hydrogen, which is a factor in nuclear reactor accidents. A granulated radioactive iodine adsorbent of zeolite X, wherein ion exchange sites of the zeolite X are substituted with silver so that a size of minute pores of the zeolite X is suited to a size of a hydrogen molecule, and the radioactive iodine adsorbent has a silver content of 36 wt % or more when dried, a particle size of 10×20 mesh, a hardness of 94% or more, and a water content of 12 wt % or less when dried at 150° C. for 3 h and thereby reduced in weight.
摘要:
A method of forming the highly selective ultra-small pore amorphous adsorbent includes introducing an ion-exchange material to a sodium aluminosilicate zeolite such that an ion-exchanged zeolite forms, calcinating the ion-exchanged zeolite at a calcination temperature such that the ion-exchanged zeolite collapses and forms the decationized amorphous adsorbent, and introducing a back ion-exchange material to the decationized amorphous adsorbent such that the highly selective ultra-small pore amorphous adsorbent forms. The highly selective ultra-small pore amorphous adsorbent has a pore aperture size operable to permit carbon dioxide to adsorb into the amorphous adsorbent and operable to deny methane from adsorbing into the amorphous adsorbent.
摘要:
Methods for drying seeds comprising: a) contacting seeds with zeolite particles and allowing said zeolite particles to take up moisture from said seeds; or b) passing an airflow over zeolite particles, thereby allowing said zeolite particles to dry the air in said airflow and passing said dried airflow over the seeds; or c) placing said seeds and zeolite particles in an air-tight container and allowing said zeolite particles to take up the moisture evaporated by said seed.
摘要:
Enhanced concentration of carbon dioxide, typically of carbon dioxide in the air, is advantageous in areas such as agriculture and horticulture involving raising of plants which utilize carbon dioxide for photosynthesis. Various carbon dioxide concentration apparatus have been developed, but the problems thereof are numerous. It is accordingly the purpose of the present invention to develop an adsorbent having exceptional adsorption of carbon dioxide, and to provide an apparatus for concentration of carbon dioxide in the air through the use thereof. Provided is a pressure swing concentration apparatus that uses ferrierite as the adsorbent, the ferrierite having been subjected to alkali treatment to give a pore diameter of 0.01-1 μm and a pore volume of 0.1 mL/g or above.
摘要:
The present invention relates to an amorphous adsorbent composition capable of purifying a gaseous hydrocarbon fraction and methods for synthesizing the composition. The composition is advantageously capable of filtering non-combustible contaminants for increasing the quality and heating value of a gaseous hydrocarbon such as methane. The composition comprises a zeolite based framework that is at least partially collapsed and capable of selectively adsorbing and desorbing gaseous components such as methane and carbon dioxide for purifying the gaseous hydrocarbon fraction.