公开(公告)号：US20130296159A1

公开(公告)日：2013-11-07

申请号：US13869418

申请日：2013-04-24

Applicant: BASF SE

Inventor： Mathias FEYEN ,  Ulrich Mueller ,  Andrei-Nicolae Parvulescu ,  Bernd Bastian Schaack ,  Sebastian Ahrens ,  Dirk Gerhard ,  Sunghee Son ,  Gabriele Iffland ,  Bianca Seelig

IPC: B01J29/89 ,  B01J29/00 ,  B01J29/40

CPC classification number: C01B39/48 ,  B01J20/18 ,  B01J20/186 ,  B01J20/28057 ,  B01J20/3085 ,  B01J29/00 ,  B01J29/035 ,  B01J29/06 ,  B01J29/40 ,  B01J29/89 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0018 ,  B01J37/009 ,  B01J37/04 ,  B01J37/06 ,  B01J37/30 ,  B01J2229/183 ,  B01J2229/186 ,  C01B37/005 ,  C01B37/02 ,  C01B39/04 ,  C01B39/085 ,  C01B39/40 ,  C01P2002/72 ,  C01P2006/12

Abstract: The present invention relates to a process for the preparation of a zeolitic material comprising the steps of: (1) providing a mixture comprising one or more sources for YO2 and one or more alkenyltrialkylammonium cation R1R2R3R4N+-containing compounds as structure directing agent; and (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material; wherein Y is a tetravalent element, and wherein R1, R2, and R3 independently from one another stand for alkyl; and R4 stands for alkenyl, as well as to zeolitic materials which may be obtained according to the inventive process and to their use.

Abstract translation: 本发明涉及一种制备沸石材料的方法，包括以下步骤：（1）提供包含一种或多种YO 2源和一种或多种烯基三烷基铵阳离子R 1 R 2 R 3 R 4 N +化合物作为结构导向剂的混合物; 和（2）使步骤（1）中获得的混合物结晶以获得沸石材料; 其中Y是四价元素，并且其中R 1，R 2和R 3彼此独立地代表烷基; 并且R4代表烯基，以及可以根据本发明方法获得的沸石材料及其用途。

公开(公告)号：US09475041B2

公开(公告)日：2016-10-25

申请号：US13869418

申请日：2013-04-24

Applicant: BASF SE

Inventor： Mathias Feyen ,  Ulrich Mueller ,  Andrei-Nicolae Parvulescu ,  Bernd Bastian Schaack ,  Sebastian Ahrens ,  Dirk Gerhard ,  Sunghee Son ,  Gabriele Iffland ,  Bianca Seelig

IPC: C01B39/40 ,  B01J29/89 ,  B01J29/40 ,  B01J29/00 ,  B01J29/035 ,  B01J29/06 ,  C01B39/04 ,  C01B39/08 ,  B01J20/18 ,  B01J20/30 ,  B01J20/28 ,  C01B37/02

CPC classification number: C01B39/48 ,  B01J20/18 ,  B01J20/186 ,  B01J20/28057 ,  B01J20/3085 ,  B01J29/00 ,  B01J29/035 ,  B01J29/06 ,  B01J29/40 ,  B01J29/89 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0018 ,  B01J37/009 ,  B01J37/04 ,  B01J37/06 ,  B01J37/30 ,  B01J2229/183 ,  B01J2229/186 ,  C01B37/005 ,  C01B37/02 ,  C01B39/04 ,  C01B39/085 ,  C01B39/40 ,  C01P2002/72 ,  C01P2006/12

Abstract: The present invention relates to a process for the preparation of a zeolitic material comprising the steps of: (1) providing a mixture comprising one or more sources for YO2 and one or more alkenyltrialkylammonium cation R1R2R3R4N+-containing compounds as structure directing agent; and (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material; wherein Y is a tetravalent element, and wherein R1, R2, and R3 independently from one another stand for alkyl; and R4 stands for alkenyl, as well as to zeolitic materials which may be obtained according to the inventive process and to their use.

Abstract translation: 本发明涉及一种制备沸石材料的方法，包括以下步骤：（1）提供包含一种或多种YO 2源和一种或多种烯基三烷基铵阳离子R 1 R 2 R 3 R 4 N +化合物作为结构导向剂的混合物; 和（2）使步骤（1）中获得的混合物结晶以获得沸石材料; 其中Y是四价元素，并且其中R 1，R 2和R 3彼此独立地代表烷基; 并且R4代表烯基，以及可以根据本发明方法获得的沸石材料及其用途。

公开(公告)号：US10562009B2

公开(公告)日：2020-02-18

申请号：US15765821

申请日：2016-10-04

Applicant: BASF SE

Inventor： Bernd Bastian Schaack ,  Helmut Wanisch ,  Barbara Wucher ,  Sabine Huber

IPC: B01J37/03 ,  B01J21/18 ,  B01J23/89 ,  B01J33/00 ,  C07C29/141 ,  B01J37/00 ,  B01J37/18 ,  C07C33/025

Abstract: The present invention relates to a process for producing iron-doped ruthenium-carbon support catalysts and also their use for the selective liquid-phase hydrogenation of carbonyl compounds to the corresponding alcohols, in particular for the hydrogenation of citral to geraniol or nerol or of citronellal to citronellal.

公开(公告)号：US10201806B2

公开(公告)日：2019-02-12

申请号：US15105611

申请日：2014-12-18

Applicant: BASF SE

Inventor： Kirsten Braunsmann ,  Bernd Bastian Schaack ,  Ekkehard Schwab ,  Manuela Gaab ,  Mathias Feyen

IPC: B01J29/06 ,  C07C1/20 ,  B01J29/40 ,  B01J37/00 ,  B01J35/00 ,  C07C11/06 ,  C07C11/02 ,  C07C1/207 ,  C07C11/08 ,  B01J37/28 ,  B01J29/70 ,  B01J35/02 ,  B01J35/10 ,  B01J37/02 ,  B01J37/04 ,  B01J37/08 ,  B01J38/02 ,  B01J29/90

Abstract: The present invention relates to a catalyst for the conversion of oxygenates to olefins, wherein the catalyst comprises one or more zeolites of the MFI, MEL and/or MWW structure type and particles of one or more metal oxides, the one or more zeolites of the MFI, MEL and/or MWW structure type comprising one or more alkaline earth metals selected from the group consisting of Mg, Ca, Sr, Ba and combinations of two or more thereof, wherein the catalyst displays a water uptake of 9.0 wt.-% or less, as well as to a process for the production thereof and to its use, in particular in a process for converting oxygenates to olefins.

公开(公告)号：US09873658B2

公开(公告)日：2018-01-23

申请号：US15103789

申请日：2014-12-10

Applicant: BASF SE

Inventor： Andreas Weickgenannt ,  Bernd Bastian Schaack ,  Barbara Wucher ,  Alexander Panchenko ,  Frank Hettche ,  Martin Bock ,  Aik Meam Tan ,  Kirsten Dahmen

IPC: C07C209/72 ,  B01J23/46 ,  B01J35/10 ,  B01J37/02 ,  B01J37/08 ,  B01J37/18

CPC classification number: C07C209/72 ,  B01J23/462 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0225 ,  B01J37/0236 ,  B01J37/08 ,  B01J37/18 ,  Y02P20/582 ,  C07C211/36

Abstract: The present invention relates to a process for hydrogenating 4,4′-methylenedianiline and/or polymeric MDA with hydrogen in the presence of a catalyst comprising ruthenium on a zirconium oxide support material, and also to the use of a catalyst comprising ruthenium on a zirconium oxide support material for hydrogenating 4,4′-methylenedianiline and/or polymeric MDA.

公开(公告)号：US20150105479A1

公开(公告)日：2015-04-16

申请号：US14396396

申请日：2013-04-15

Applicant: BASF SE

Inventor： Alexander Schäfer ,  Mathias Feyen ,  Andrei-Nicolae Parvulescu ,  Ulrich Müller ,  Bernd Bastian Schaack

IPC: B01J29/76 ,  C07C41/09 ,  B01J29/46

CPC classification number: B01J29/76 ,  B01J23/80 ,  B01J29/06 ,  B01J29/40 ,  B01J29/46 ,  C07C41/01 ,  C07C41/09 ,  C07C43/043

Abstract: The invention relates to a catalytically active body for the synthesis of dimethyl ether from synthesis gas. In particular, the invention relates to an improved catalytically active body for the synthesis of dimethyl ether, whereby the components of the active body comprise a methanol active component and an acid component comprising a zeolitic material being crystallized by means of one or more alkenyltrialkylammonium cation R1R2R3R4N+-containing compounds as structure directing agent. Furthermore, the present invention concerns a method for the preparation of a catalytically active body, the use of the catalytically active body and a method for the preparation of dimethyl ether from synthesis gas.

Abstract translation: 本发明涉及用于从合成气合成二甲醚的催化活性体。 特别地，本发明涉及用于合成二甲醚的改进的催化活性体，其中活性体的组分包含甲醇活性组分和酸组分，该组分包含通过一个或多个烯基三烷基铵阳离子R1R2R3R4N +结晶的沸石材料， 作为结构导向剂的化合物。 此外，本发明涉及制备催化活性体的方法，催化活性体的用途以及从合成气中制备二甲醚的方法。

公开(公告)号：US10329237B2

公开(公告)日：2019-06-25

申请号：US15103652

申请日：2014-12-10

Applicant: BASF SE

Inventor： Bernd Bastian Schaack ,  Martin Bock ,  Kirsten Dahmen

IPC: C07C209/72

Abstract: The present invention relates to a method for hydrogenating aromatic compounds with hydrogen in the presence of a catalyst, in which the catalyst comprises ruthenium on a zirconium oxide support material, and also the use of a catalyst comprising ruthenium on a zirconium oxide support material for hydrogenating aromatic compounds.

公开(公告)号：US10266417B2

公开(公告)日：2019-04-23

申请号：US15264314

申请日：2016-09-13

Applicant: BASF SE

Inventor： Mathias Feyen ,  Ulrich Müller ,  Andrei-Nicolae Parvulescu ,  Bernd Bastian Schaack ,  Sebastian Ahrens ,  Dirk Gerhard ,  Sunghee Son ,  Gabriele Iffland ,  Bianca Seelig

IPC: C01B39/40 ,  B01J29/40 ,  C01B39/48 ,  B01J29/89 ,  B01J29/00 ,  B01J20/18 ,  C01B39/06 ,  B01J29/035 ,  B01J29/06 ,  C01B39/04 ,  C01B39/08 ,  B01J20/30 ,  B01J20/28 ,  C01B37/02 ,  B01J35/10 ,  B01J37/00 ,  B01J37/04 ,  B01J37/06 ,  B01J37/30 ,  C01B37/00

Abstract: The present invention relates to a process for the preparation of a zeolitic material comprising the steps of: (1) providing a mixture comprising one or more sources for YO2 and one or more alkenyltrialkylammonium cation R1R2R3R4N+-containing compounds as structure directing agent; and (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material; wherein Y is a tetravalent element, and wherein R1, R2, and R3 independently from one another stand for alkyl; and R4 stands for alkenyl, as well as to zeolitic materials which may be obtained according to the inventive process and to their use.