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公开(公告)号:US09803049B2
公开(公告)日:2017-10-31
申请号:US15113548
申请日:2015-03-25
Applicant: SABIC Global Technologies B.V.
Inventor: Ignacio Vic Fernandez
CPC classification number: C08G64/40 , B05D1/265 , C08J3/203 , C08J2369/00 , C08K5/00 , C08L27/12 , C08L69/00
Abstract: In an embodiment, a melt polymerization process comprises melt polymerizing reactants in at least two polymerization units, in the presence of a catalyst composition to form polymerized polycarbonate; adding a quencher composition comprising one or both of a liquid quencher composition and a solid quencher composition; mixing the quencher composition with the polymerized polycarbonate for a period of time of greater than or equal to 5 seconds prior to the addition to the polymerized polycarbonate of any additives having a reactive OH group or reactive ester group; directing the polymerized polycarbonate to an extruder; and directing an additive to the extruder.
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公开(公告)号:US09796813B1
公开(公告)日:2017-10-24
申请号:US15522858
申请日:2015-10-30
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Ignacio Vic Fernandez , William E. Hollar, Jr. , Donald E. Owens, III
CPC classification number: C08G64/226 , C08G64/40 , C08G64/403 , C08G64/406 , C08G64/42
Abstract: In an embodiment, a polycarbonate polymerization process comprises interfacially polymerizing a carbonate compound and dihydroxy compound in the presence of an interfacial catalyst to form a polycarbonate and adding a viscosity reducing agent and a transesterification catalyst to polycarbonate upstream of a first filter to form an adjusted polycarbonate. The first filter can be replaced with a replacement filter and the adjusted polycarbonate can be introduced to the replacement filter. The flow can be diverted to a replacement filter. The process further comprises reducing the addition rate of the viscosity reducing agent and the transesterification catalyst until the addition rate is 0 mol/hr.
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公开(公告)号:US11529602B2
公开(公告)日:2022-12-20
申请号:US16625926
申请日:2018-06-29
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
IPC: C08G64/30 , B01J4/00 , B01J19/00 , B01J19/18 , B01F23/47 , B01F27/91 , B01F27/1131 , B01F101/00
Abstract: In an embodiment, a reactor for carrying out a melt transesterification reaction at a reactor temperature of 160 to 300° C. and a reactor pressure of 5 to 200 mbar, comprises a cylindrical tank comprising a top, a side, and a bottom, wherein the bottom is convex, extending away from the top; a stirring shaft disposed within the cylindrical tank along an axis thereof so that it is rotatable from outside of the cylindrical tank; a stirring blade extending from the stirring shaft in the cylindrical tank; a reactant solution inlet located on the bottom; and a reaction solution outlet located on the bottom. The reactor can be used for the polymerization of a polycarbonate oligomer.
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公开(公告)号:US11155695B2
公开(公告)日:2021-10-26
申请号:US16061427
申请日:2016-12-12
Applicant: SABIC Global Technologies B.V.
Inventor: Tamara Marijke Eggenhuisen , Roland Sebastian Assink , Eduardus Ludovicus Louisa Broekaart , Robert Dirk Van De Grampel , David Del Agua Hernandez , Ignacio Vic Fernandez
IPC: C08K5/42 , C08K5/3475 , C08K5/3492 , C08K5/50 , C08K5/523 , C08K5/526 , C08K5/5393 , G02B1/04 , C08G64/22 , C08L69/00 , C08K5/5333 , C08K3/32 , C08K3/30 , B29C45/00 , B29K69/00 , B29K105/00
Abstract: A molded article includes a polycarbonate resin, an ultraviolet (UV) absorbing component, a heat stabilizer component and an acid stabilizer component. The polycarbonate resin is produced by an interfacial polymerization process and has an end-cap level of at least about 98%, and includes a ratio of bound UV absorbing component to free UV absorbing component of less than about 1.0 when molded under abusive molding conditions. The polycarbonate resin may include high purity polycarbonate. The acid stabilizer component may include a sulfonic acid ester. Methods of forming molded articles are also described.
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公开(公告)号:US20200171452A1
公开(公告)日:2020-06-04
申请号:US16625926
申请日:2018-06-29
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Abstract: In an embodiment, a reactor for carrying out a melt transesterification reaction at a reactor temperature of 160 to 300° C. and a reactor pressure of 5 to 200 mbar, comprises a cylindrical tank comprising a top, a side, and a bottom, wherein the bottom is convex, extending away from the top; a stirring shaft disposed within the cylindrical tank along an axis thereof so that it is rotatable from outside of the cylindrical tank; a stirring blade extending from the stirring shaft in the cylindrical tank; a reactant solution inlet located on the bottom; and a reaction solution outlet located on the bottom. The reactor can be used for the polymerization of a polycarbonate oligomer.
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16.
公开(公告)号:US10465061B2
公开(公告)日:2019-11-05
申请号:US15467007
申请日:2017-03-23
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
IPC: C08K5/103 , B29C48/04 , C08G64/30 , C08L69/00 , C08J3/20 , C08K5/11 , B29B9/10 , C08K5/526 , B29K69/00
Abstract: A process for manufacturing a polycarbonate composition includes melt polymerizing a dihydroxy compound and a carbonate compound in the presence of a catalyst to form a polycarbonate; and adding 1 to 400 ppm of glycerol tristearate to form the polycarbonate composition, wherein the polycarbonate composition is unquenched.
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17.
公开(公告)号:US10106648B2
公开(公告)日:2018-10-23
申请号:US15520541
申请日:2015-11-19
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Ignacio Vic Fernandez
Abstract: In an embodiment, a melt polymerization process comprises melt polymerizing a carbonate compound and a dihydroxy compound in the presence of a catalyst composition to form a polycarbonate; and adding an end-capping agent comprising a mono-phenolic compound to the polycarbonate, wherein the adding of the end-capping agent comprises at least one of adding the end-capping agent just upstream of a final polymerization unit, adding the end-capping agent directly into the final polymerization unit, and adding the end-capping agent downstream of the final polymerization unit; wherein a molecular weight of the polycarbonate increases by less than 10% downstream of the final polymerization unit.
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公开(公告)号:US09738590B1
公开(公告)日:2017-08-22
申请号:US15502539
申请日:2015-09-04
Applicant: SABIC Global Technologies B.V.
Inventor: Ignacio Vic Fernandez , Paulus Johannes Maria Eijsbouts
CPC classification number: C07C68/06 , C07C37/20 , C08G64/04 , C08G64/06 , C08G64/307 , C07C69/96 , C07C39/16
Abstract: In an embodiment, a method for producing an aryl alkyl carbonate can comprise: reacting methanol with a dicarbonate in the presence of a catalyst to form a mixture comprising an aryl alkyl carbonate and a hydroxy compound, where methanol is in an acetone monomer mixture comprising acetone and at least one of diaryl carbonate and dihydroxy compound separating the aryl alkyl carbonate from the mixture.
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19.
公开(公告)号:US20170190871A1
公开(公告)日:2017-07-06
申请号:US15467007
申请日:2017-03-23
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Abstract: A process for manufacturing a polycarbonate composition includes melt polymerizing a dihydroxy compound and a carbonate compound in the presence of a catalyst to form a polycarbonate; and adding 1 to 400 ppm of glycerol tristearate to form the polycarbonate composition, wherein the polycarbonate composition is unquenched.
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公开(公告)号:US20160362537A1
公开(公告)日:2016-12-15
申请号:US15111929
申请日:2015-03-04
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Marco Roncaglia , Ignacio Vic Fernandez , Rein Mollerus Faber , Christianus Johannes Jacobus Maas , Cornelis Jan Maria Rijken
IPC: C08K5/3475 , B29C47/00 , C08K5/103
CPC classification number: C08K5/3475 , B29C47/0004 , B29C47/06 , B29C47/68 , B29K2069/00 , C08G64/406 , C08J5/18 , C08J2369/00 , C08K5/005 , C08K5/103 , C08K5/11 , C08L69/00
Abstract: In an embodiment, a method for making a thermoplastic composition, comprising: melt polymerizing a polycarbonate, extruding and melt filtering the polycarbonate to form a melt filtered polycarbonate; forming the thermoplastic composition comprising the melt filtered polycarbonate, 0.03 to 0.05 wt % of a triacylglyceride release agent; and 0.10 to 0.14 wt % of a UV stabilizer; wherein the weight percentages are based on the total weight of the composition; and extruding the thermoplastic composition.
Abstract translation: 在一个实施方案中,制备热塑性组合物的方法包括:熔融聚合聚碳酸酯,挤出和熔融过滤聚碳酸酯以形成熔融过滤的聚碳酸酯; 形成包含熔融过滤的聚碳酸酯的热塑性组合物,0.03至0.05重量%的三酰基甘油酯脱模剂; 和0.10〜0.14重量%的UV稳定剂; 其中所述重量百分比基于所述组合物的总重量; 并挤出热塑性组合物。
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