Method for reclaiming lead
    8.
    发明授权
    Method for reclaiming lead 有权
    回收铅的方法

    公开(公告)号:US08105416B1

    公开(公告)日:2012-01-31

    申请号:US12774220

    申请日:2010-05-05

    CPC classification number: C22B13/025 C22B13/06 Y02P10/214

    Abstract: A method for reducing tin in lead bullion has the steps of adding an Arrhenius base to a kettle containing lead bullion and tin, adding a byproduct of conventional detinning to the kettle, agitating contents of the kettle, and removing a layer of slag from the kettle. The disclosed method removes tin via chemical oxidation, adds lead via chemical reduction of an oxide from the byproduct of conventional detinning, and preserves most of the antimony content of the lead bullion.

    Abstract translation: 铅锭中的锡的还原方法具有以下步骤:在含有铅块和锡的釜中加入Arrhenius碱,向釜中加入常规分配的副产物,搅拌釜的内容物,并从釜中除去一层渣 。 所公开的方法通过化学氧化除去锡,通过化学还原氧化物从常规鉴定的副产物添加铅,并保留铅块的大部分锑含量。

    PROCESS FOR PRODUCING METALLIC LEAD STARTING FROM DESULFURIZED PASTEL
    9.
    发明申请
    PROCESS FOR PRODUCING METALLIC LEAD STARTING FROM DESULFURIZED PASTEL 有权
    从脱硫PASTEL生产金属铅起始的工艺

    公开(公告)号:US20110083970A1

    公开(公告)日:2011-04-14

    申请号:US12745067

    申请日:2008-11-27

    CPC classification number: C22B13/045 C22B7/008 C25C1/18 Y02P10/122 Y02P10/234

    Abstract: The present invention relates to an electrolytic process for producing metallic lead starting from desulfurized lead pastel comprising the following operative phases: a) leaching the desulfurized pastel by putting it in contact with a solution comprising ammonium chloride, with the formation of a leach liquor and evolution of gaseous CO2; b) separating a first solid residue and a first clarified leach liquor from the leach liquor coming from phase a); c) leaching the solid residue separated in phase b) by putting it in contact with a solution comprising ammonium chloride and hydrogen peroxide; d) separating a second solid residue and a second clarified leach liquor from the leach liquor coming from phase c); e) joining the first clarified leach liquor coming from phase b) with the second clarified leach liquor coming from phase d) and forming a single solution; f) subjecting the solution leaving phase e) to electrolysis in a flow cell, with a current density ranging from 50 to 10,000 A/m2, said electrolysis resulting in the formation of a lead sponge. The present invention also relates to the relative desulfurization process of the pastel.

    Abstract translation: 本发明涉及一种用于从脱硫铅膏制备金属铅的电解方法,其包括以下操作阶段:a)通过将脱硫粉末与包含氯化铵的溶液接触,浸出脱硫粉末,形成浸出液并进行 的气态二氧化碳; b)从第一阶段a)的浸出液中分离出第一固体残余物和第一澄清浸出液; c)通过使其与包含氯化铵和过氧化氢的溶液接触来浸出在相b)中分离的固体残余物; d)从相c)的浸出液中分离出第二固体残渣和第二澄清浸出液; e)将来自相b)的第一澄清浸出液与来自相d)的第二澄清浸出液接合并形成单一溶液; f)使离开相e)的溶液在流动池中电解,电流密度范围为50至10,000A / m 2,所述电解导致形成铅海绵。 本发明还涉及到粉笔的相对脱硫工艺。

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