Coating formulation and process for the production of titanate-based ceramic film with the coating formulation
    2.
    发明授权
    Coating formulation and process for the production of titanate-based ceramic film with the coating formulation 有权
    涂层配方及其制备方法,用于生产具有涂层配方的钛酸酯基陶瓷膜

    公开(公告)号:US07819965B2

    公开(公告)日:2010-10-26

    申请号:US11866107

    申请日:2007-10-02

    Abstract: A coating formulation contains the following components (A), (B) and (C): (A) an organic acid-titanium compound having at least one titanium atom and at least one C2-12 aliphatic organic acid residual group as essential constituents and having no constituent other than the essential constituents, (B) fine particles of a titanate-based compound, said fine particles having an average particle size of from 10 to 100 nm, and (C) an organic solvent. A content of the components (A) is from 0.1 to 1.5 mol/kg in terms of titanium atoms, and a content of the component (B) is from 0.1 to 1.5 mol/kg in terms of titanium atoms. A production process for a titanate-based ceramic film, which makes use of the coating formulation, is also disclosed.

    Abstract translation: 涂料配方含有以下组分(A),(B)和(C):(A)具有至少一个钛原子和至少一个C 2-12脂族有机酸残基作为必要组分的有机酸 - 钛化合物,以及 不含有必要成分的成分,(B)钛酸酯系化合物的微粒,所述微粒的平均粒径为10〜100nm,(C)有机溶剂。 组分(A)的含量以钛原子计为0.1至1.5mol / kg,组分(B)的含量以钛原子计为0.1至1.5mol / kg。 还公开了利用涂料配方的钛酸酯系陶瓷膜的制造方法。

    Method for the production of a grip-promoting and/or slip-resistant coating on a holding section or grip section of a household utensil
    3.
    发明申请
    Method for the production of a grip-promoting and/or slip-resistant coating on a holding section or grip section of a household utensil 审中-公开
    用于在家用器具的保持部分或抓握部分上生产抓握促进和/或防滑涂层的方法

    公开(公告)号:US20050244582A1

    公开(公告)日:2005-11-03

    申请号:US10525570

    申请日:2003-08-14

    Inventor: Georg Weihrauch

    CPC classification number: B41M1/40 B05D5/02 B05D5/06 C09D11/037

    Abstract: The invention relates to a method for producting a dotted and/or planar grip-promoting and/or slip-resistant coating on a holding section or grip section of a house-hold utensil, said coating being printed onto the surface of the holding section or grip section by means of a silk screen printing process or a transfer printing process, and especially a tampon printing process. The coating material is disposed in a predetermined configuration that corresponds to a desired printed image on a pattern support (printing block), is then transferred to a transfer element, and is applied to or printed onto the holding section or grip section.

    Abstract translation: 本发明涉及一种在家庭用具的保持部分或抓握部分上产生点状和/或平面的抓握促进和/或防滑涂层的方法,所述涂层被印刷到保持部分的表面上,或 通过丝网印刷工艺或转印印刷工艺,特别是棉塞印刷工艺的夹持部分。 将涂料以与图案支撑体(印刷块)上的所需印刷图像相对应的预定构造设置,然后转印到转印元件上,并被施加到或打印到保持部分或抓握部分上。

    Ionic additives for extreme low dielectric constant chemical formulations
    6.
    发明授权
    Ionic additives for extreme low dielectric constant chemical formulations 失效
    用于极低介电常数化学配方的离子添加剂

    公开(公告)号:US06896955B2

    公开(公告)日:2005-05-24

    申请号:US10219164

    申请日:2002-08-13

    Abstract: A process for depositing porous silicon oxide-based films using a sol-gel approach utilizing a precursor solution formulation which includes a purified nonionic surfactant and an additive among other components, where the additive is either an ionic additive or an amine additive which forms an ionic ammonium type salt in the acidic precursor solution. Using this precursor solution formulation enables formation of a film having a dielectric constant less than 2.5, appropriate mechanical properties, and minimal levels of alkali metal impurities. In one embodiment, this is achieved by purifying the surfactant and adding ionic or amine additives such as tetraalkylammonium salts and amines to the stock precursor solution. In some embodiments, the ionic additive is a compound chosen from a group of cationic additives of the general composition [NR(CH3)3]+A−, where R is a hydrophobic ligand of chain length 1 to 24, including tetramethylammonium and cetyltrimethylammonium, and A− is an anion, which may be chosen from the group consisting essentially of formate, nitrate, oxalate, acetate, phosphate, carbonate, and hydroxide and combinations thereof. Tetramethylammonium salts, or more generally tetraalkylammonium salts, or tetraorganoammonium salts or organoamines in acidic media are added to surfactant templated porous oxide precursor formulations to increase the ionic content, replacing alkali ion impurities (sodium and potassium) removed during surfactant purification, but which are found to exhibit beneficial effects in promoting the formation of the resulting dielectric.

    Abstract translation: 一种使用溶胶 - 凝胶方法沉积多孔氧化硅基膜的方法,该方法使用前体溶液制剂,其包含纯化的非离子表面活性剂和其它组分中的添加剂,其中添加剂是形成离子的离子添加剂或胺添加剂 铵型盐在酸性前体溶液中。 使用这种前体溶液制剂可以形成介电常数小于2.5,适当的机械性能和最低水平的碱金属杂质的薄膜。 在一个实施方案中,这通过纯化表面活性剂并将离子或胺添加剂例如四烷基铵盐和胺添加到原料前体溶液中来实现。 在一些实施方案中,离子添加剂是选自一般组成的阳离子添加剂组合物[NR(CH 3)3) 其中R是链长1至24的疏水性配体,包括四甲基铵和十六烷基三甲基铵,并且A是一种阴离子,其可以选自下组: 基本上由甲酸盐,硝酸盐,草酸盐,乙酸盐,磷酸盐,碳酸盐和氢氧化物组成。 在表面活性剂模板化的多孔氧化物前体制剂中加入四甲基铵盐或更一般的四烷基铵盐或四官能铵盐或有机胺,以增加离子含量,代替在表面活性剂纯化过程中除去的碱离子杂质(钠和钾),但发现 以促进所形成的电介质的形成。

    Coating solution and method for preparing the coating solution, method
for forming insulating films for semiconductor devices, and method for
evaluating the coating solution
    8.
    发明授权
    Coating solution and method for preparing the coating solution, method for forming insulating films for semiconductor devices, and method for evaluating the coating solution 失效
    涂布液及其制备方法,半导体装置用绝缘膜的形成方法以及涂布液的评价方法

    公开(公告)号:US5998522A

    公开(公告)日:1999-12-07

    申请号:US42668

    申请日:1998-03-17

    Abstract: A coating solution for forming an insulating film used in production of semiconductor devices includes siloxanes represented by a general formula:[SiR.sub.3 O.sub.1/2 ].sub.k [SiR.sub.2 O.sub.2/2 ].sub.l [SiRO.sub.3/2 ].sub.m [SiO.sub.4/2 ].sub.nwhere each of k, l, m and n is an integer, R may be the same or different and represents at least one organic group, and a ratio of (3k+21+m) to (k+l+m+n) is between about 0.8 and about 1.3. The present invention further relates to a method for preparing the coating solution, and a method for forming the insulating film using the coating solution, including the steps of coating the coating solution on a surface of a substrate of the semiconductor device to form a coated film, fluidizing the coated film at a temperature between about 150.degree. C. to about 300.degree. C. to planarize the surface of the substrate, and curing the fluidized coated film to form the insulating film. The present invention permits the formation of the insulating film with excellent properties such as an ability of fill up fine grooves and to planarize the surface of the substrate, and a small shrinkage factor. The method for evaluating the coating solution using .sup.29 Si-NMR technique is also described.

    Abstract translation: 用于形成用于制造半导体器件的绝缘膜的涂布溶液包括由以下通式表示的硅氧烷:[SiR 3 O 1/2/2] k [SiR 2 O 2/2] l [SiRO 3/2] m [SiO 4/2] n,其中k ,l,m和n是整数,R可以相同或不同,表示至少一个有机基团,(3k + 21 + m)与(k + 1 + m + n)的比例在约0.8之间 约1.3。 本发明还涉及一种涂布溶液的制备方法以及使用该涂布液形成绝缘膜的方法,包括以下步骤:将涂布溶液涂布在半导体器件的基板的表面上以形成涂膜 在约150℃至约300℃的温度下使涂覆膜流化,使基材表面平坦化,并使流化涂膜固化形成绝缘膜。 本发明允许形成具有优异性能的绝缘膜,例如填充细槽的能力和使基板的表面平坦化,并且收缩率小。 还描述了使用29Si-NMR技术评价涂布溶液的方法。

    Method for providing high temperature conductive-resistant coating,
medium and articles
    9.
    发明授权
    Method for providing high temperature conductive-resistant coating, medium and articles 失效
    提供耐高温导电涂层,介质和制品的方法

    公开(公告)号:US5888429A

    公开(公告)日:1999-03-30

    申请号:US685244

    申请日:1996-07-23

    Inventor: Walter C. Lovell

    Abstract: The temperature adjustable coating and medium and method for providing an electrically-resistant temperature-adjustable article and structure. The coating provides a continuous electrically-conductive electrically-resistive path for the application of electrical current to the coating. The electrically-resistant temperature-adjustable article consists of a surface on which a high-temperature conductive-resistive coating is bound. The surface temperature of the article along the path is thereby adjustable between ambient and 2000.degree. F. in response to electric current applied to it without oxidization destroying the electrical conductivity of the medium in temperatures above 600.degree. F. The medium possesses the high-temperature conductive-resistive quality of the coating while maintaining a clay consistency capable of being formed into various shapes without a substrate.

    Abstract translation: 温度可调的涂层和介质以及提供电阻温度可调的制品和结构的方法。 涂层提供了连续的导电电阻路径,用于向涂层施加电流。 耐电温度可调制品由其上结合有高温导电电阻涂层的表面组成。 因此,沿着路径的物品的表面温度可以响应于施加到其上的电流而在环境温度和2000°F之间可调节,而不会在高于600°F的温度下破坏介质的导电性而不会氧化。介质具有高温 导电性质的涂层,同时保持能够形成为各种形状而没有基底的粘土稠度。

    Coating solution and method for preparing the coating solution, method
for forming insulating films for semiconductor devices, and method for
evaluating the coating solution
    10.
    发明授权
    Coating solution and method for preparing the coating solution, method for forming insulating films for semiconductor devices, and method for evaluating the coating solution 失效
    涂布液及其制备方法,半导体装置用绝缘膜的形成方法以及涂布液的评价方法

    公开(公告)号:US5840821A

    公开(公告)日:1998-11-24

    申请号:US545736

    申请日:1995-11-21

    Abstract: A coating solution for forming an insulating film used in production of semiconductor devices includes siloxanes represented by a general formula:�SiR.sub.3 O.sub.1/2 !.sub.k �SiR.sub.2 O.sub.2/2 !.sub.l �SiRO.sub.3/2 !.sub.m �SiO.sub.4/2 !.sub.n where each of k, l, m and n is an integer, R may be the same or different and represents at least one organic group, and a ratio of (3k+2l+m) to (k+l+m+n) is between about 0.8 and about 1.3. The present invention further relates to a method for preparing the coating solution, and a method for forming the insulating film using the coating solution, including the steps of coating the coating solution on a surface of a substrate of the semiconductor device to form a coated film, fluidizing the coated film at a temperature between about 150.degree. C. to about 300.degree. C. to planarize the surface of the substrate, and curing the fluidized coated film to form the insulating film. The present invention permits the formation of the insulating film with excellent properties such as an ability of fill up fine groves and to planarize the surface of the substrate, and a small shrinkage factor. The method for evaluating the coating solution using .sup.29 Si-NMR technique is also described.

    Abstract translation: PCT No.PCT / JP94 / 01910 Sec。 371日期:1995年11月21日 102(e)日期1995年11月21日PCT 1994年11月11日PCT公布。 公开号WO95 / 24639 日期1995年9月14日,用于制造半导体器件的绝缘膜形成用涂布液包括由以下通式表示的硅氧烷:[SiR 3 O 1/2/2] k [SiR 2 O 2/2] l [SiRO 3/2] m [SiO 4/2] 其中k,l,m和n各自为整数,R可以相同或不同,表示至少一个有机基团,并且(3k + 21 + m)与(k + 1 + m + n) 在约0.8和约1.3之间。 本发明还涉及一种涂布溶液的制备方法以及使用该涂布液形成绝缘膜的方法,包括以下步骤:将涂布溶液涂布在半导体器件的基板的表面上以形成涂膜 在约150℃至约300℃的温度下使涂覆膜流化,使基材表面平坦化,并使流化涂膜固化形成绝缘膜。 本发明允许形成具有优异性能的绝缘膜,例如填充细小树脂的能力和使基板的表面平坦化,并且收缩率小。 还描述了使用29Si-NMR技术评价涂布溶液的方法。

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