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    Metal complex carrying a 2-phospa-tricyclo[3.3.1.1(3.7)]decyl radical as a ligand in hydroformylation
    1.
    发明授权
    Metal complex carrying a 2-phospa-tricyclo[3.3.1.1(3.7)]decyl radical as a ligand in hydroformylation 失效
    在加氢甲酰化中携带2-磷杂三环[3.3.1.1（3.7）]癸基作为配体的金属络合物

    公开(公告)号：US06835855B2

    公开(公告)日：2004-12-28

    申请号：US10275562

    申请日：2002-11-07

    申请人： Wolfgang Ahlers

    发明人： Wolfgang Ahlers

    IPC分类号： C07C4550

    CPC分类号： C07F15/008 ,  B01J31/1845 ,  B01J31/2485 ,  B01J2231/321 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/827 ,  B01J2531/828 ,  C07C45/50 ,  C07C47/02

    摘要： In a process for the hydroformylation of ethylenically unsaturated compounds, at least one ethylenically unsaturated compound is reacted with carbon monoxide and hydrogen in the presence of a ligand-metal complex of ruthenium, rhodium, palladium, iridium and/or platinum, where the ligand-metal complex comprises a monophosphine, monophosphinite or monophosphinamidite ligand of the formula I where A together with the phosphorus atom to which it is bound forms a 2-phosphatricyclo[3.3.1.1{3,7}]decyl radical in which one or more nonadjacent carbon atoms may be replaced by heteroatoms and which may be substituted, and R′ is hydrogen or an organic radical having a molecular weight of up to 20 000 bound via a carbon atom or oxygen atom or nitrogen atom. The process is particularly useful for the hydroformylation of internal branched olefins and lower pressures and/or temperatures are required in the hydroformylation than when using other phosphorus ligands.

    Process for producing alcohols
    3.
    发明授权
    Process for producing alcohols 有权
    醇的制备方法

    公开(公告)号：US06365783B1

    公开(公告)日：2002-04-02

    申请号：US09577981

    申请日：2000-05-25

    申请人： Yorozu Yokomori ,  Tsukasa Hayashi ,  Toshiaki Ogata ,  Junichi Yamada ,  Seiji Saito

    发明人： Yorozu Yokomori ,  Tsukasa Hayashi ,  Toshiaki Ogata ,  Junichi Yamada ,  Seiji Saito

    IPC分类号： C07C4550

    CPC分类号： C07C45/50 ,  C07C29/16 ,  C07C31/125 ,  C07C47/02

    摘要： Provided is a process for producing alcohols or aldehydes by reacting monoolefins with carbon monoxide and hydrogen with less formation of by-products. The process comprises the step of reacting a monoolefin with carbon monoxide and hydrogen in the presence of a cobalt carbonyl catalyst until the conversion of monoolefin reaches 50-90% (the first reaction step), the step of separating unreacted monoolefin from the reaction mixture obtained in the first reaction step (the step of separation of unreacted monoolefin) and the step of reacting the separated unreacted monoolefin with carbon monoxide and hydrogen in the presence of a cobalt carbonyl catalyst (the second reaction step), wherein at least one of the first reaction step and the second reaction step is carried out in the presence of water.

    摘要翻译： 提供了通过使单烯烃与一氧化碳和氢气反应而形成副产物而生产醇或醛的方法。 该方法包括在羰基钴催化剂存在下使单烯烃与一氧化碳和氢气反应的步骤，直到单烯烃的转化率达到50-90％（第一反应步骤），从获得的反应混合物中分离未反应的单烯烃的步骤 在第一反应步骤（分离未反应的单烯烃的步骤）和在羰基钴催化剂（第二反应步骤）的存在下使分离的未反应的单烯烃与一氧化碳和氢气反应的步骤，其中第一 反应步骤和第二反应步骤在水的存在下进行。

    Process for the continuous preparation of alkyl 5-formylvalerate compounds using homogeneous rhodium hydroformylation catalysts
    4.
    发明授权
    Process for the continuous preparation of alkyl 5-formylvalerate compounds using homogeneous rhodium hydroformylation catalysts 失效
    使用均相铑加氢甲酰化催化剂连续制备5-甲酰基戊酸烷基酯化合物的方法

    公开(公告)号：US06274773B1

    公开(公告)日：2001-08-14

    申请号：US09304668

    申请日：1999-05-04

    申请人： Onko J. Gelling ,  Peter C. Borman

    发明人： Onko J. Gelling ,  Peter C. Borman

    IPC分类号： C07C4550

    CPC分类号： C07C67/347 ,  C07C69/716

    摘要： Process for the continuous preparation of an alkyl 5-formylvalerate by reacting an alkyl-3-pentenoate with carbon monoxide and hydrogen by hydroformylation using a catalyst system comprising rhodium or iridium and a multidentate organic phosphite ligand according to the general formula: in which n is 2-6, X is an n-valent organic bridging group, and in which the end groups R1-R2 are monovalent aryl groups, wherein the process is carried out in the presence of an acid compound having a pKa between 1 and 12 measured in water at 18° C.

    摘要翻译： 通过使用包含铑或铱的催化剂体系和根据通式的多齿有机亚磷酸酯配体通过加氢甲酰化反应使3-戊烯酸烷基酯与一氧化碳和氢气反应来连续制备5-甲酰基烷基烷基的方法：其中n是 2-6，X是n价有机桥连基团，其中端基R1-R2是一价芳基，其中该方法在pKa在1和12之间的酸化合物存在下进行，其在 18°C水

    Process for the preparation of aldehydes
    7.
    发明授权
    Process for the preparation of aldehydes 失效
    醛的制备方法

    公开(公告)号：US06753450B2

    公开(公告)日：2004-06-22

    申请号：US10275563

    申请日：2002-11-07

    申请人： Wolfgang Ahlers ,  Michael Slany

    发明人： Wolfgang Ahlers ,  Michael Slany

    IPC分类号： C07C4550

    CPC分类号： C07C45/50 ,  C07C47/02

    摘要： The invention relates to a process for the preparation of aldehydes in which at least one compound containing a vinyl or vinylidene group is reacted with carbon monoxide and hydrogen in the presence of a source of a metal from sub-group VIII and in the presence of a bidentate diphosphine ligand, where the diphosphine ligand has the general formula I in which A together with the phosphorus atom to which it is bonded, in each case forms a 2-phosphatricyclo[3.3.1.1{3,7}]decyl radical, in which one or more non-adjacent carbon atoms may be replaced by oxygen atoms and which is substituted or unsubstituted, and X is a bridging chain having 1 to 10 carbon atoms, and the molar ratio between the diphosphine ligand and the metal is at least 5. The process gives predominantly n-aldehydes.

    摘要翻译： 本发明涉及一种制备醛的方法，其中至少一种含有乙烯基或亚乙烯基的化合物与来自第VIII族的金属源存在下的一氧化碳和氢气反应， 二膦配体，其中二膦配体具有通式Iin，其中A与其键合的磷原子一起形成2-磷酸三环[3.3.1.1 {3,7}]癸基，其中一个或 更多的不相邻的碳原子可以被氧原子取代并且是取代或未被取代的，X是具有1-10个碳原子的桥连链，二膦配体和金属之间的摩尔比至少为5.该方法给出 主要是正醛。

    Process for the catalytic preparation of aldehydes from olefins using ligand mixtures
    10.
    发明授权
    Process for the catalytic preparation of aldehydes from olefins using ligand mixtures 失效
    使用配体混合物从烯烃催化制备醛的方法

    公开(公告)号：US06403837B1

    公开(公告)日：2002-06-11

    申请号：US09708624

    申请日：2000-11-09

    申请人： Dieter Hess ,  Dirk Roettger ,  Detlef Selent ,  Armin Boerner

    发明人： Dieter Hess ,  Dirk Roettger ,  Detlef Selent ,  Armin Boerner

    IPC分类号： C07C4550

    CPC分类号： C07C45/50 ,  C07C47/02

    摘要： A process for preparing aldehydes having from 4 to 25 carbon atoms by catalytic hydroformylation of the corresponding olefins, wherein the catalyst used comprises a metal of transition group 8 of the Periodic Table in the presence of a ligand A of the formula I where X=As, Sb or P and R1,R2,R3: are each a substituted or unsubstituted aliphatic, cycloaliphatic or aromatic hydrocarbon radical having from 1 to 50 carbon atoms, where two of the radicals R1, R2, R3 can be covalently linked with the proviso that at least one of the hydrocarbon radicals R1, R2, R3 contains a heteroatom selected from the group consisting of O, S, N, F, Cl, Be, I, Se and Te, and a ligand B of the formula II where R4, R5, R6: are each a substituted or unsubstituted aliphatic, cycloaliphatic or aromatic hydrocarbon having from 1 to 50 carbon atoms, where two of the radicals R4, R5 and R6 can be covalently linked.

    摘要翻译： 通过相应烯烃的催化加氢甲酰化制备具有4至25个碳原子的醛的方法，其中所用的催化剂包括在式I的配体A的存在下的周期表的过渡族8的金属，其中X = As，Sb 或P和R 1，R 2，R 3：各自是具有1至50个碳原子的取代或未取代的脂族，脂环族或芳族烃基，其中基团R 1，R 2，R 3中的两个可以共价连接，条件是至少一个 的烃基R1，R2，R3含有选自O，S，N，F，Cl，Be，I，Se和Te的杂原子和式II的配体B，其中R4，R5，R6： 各自为具有1至50个碳原子的取代或未取代的脂族，脂环族或芳族烃，其中基团R 4，R 5和R 6中的两个可以共价连接。