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    HYDROFORMYLATION PROCESS
    2.
    发明申请
    HYDROFORMYLATION PROCESS 有权
    氢化工艺

    公开(公告)号：US20070015942A1

    公开(公告)日：2007-01-18

    申请号：US11427247

    申请日：2006-06-28

    申请人： Wilhelmus MUL

    发明人： Wilhelmus MUL

    IPC分类号： C07C45/49

    CPC分类号： C07C45/50 ,  C07C29/16 ,  C07C2601/08 ,  C07C31/125 ,  C07C31/36 ,  C07C31/135 ,  C07C33/20 ,  C07C47/02

    摘要： A hydroformylation process comprising reacting a feedstock composition comprising a compound having at least one olefinic carbon-to-carbon bond with hydrogen and carbon monoxide in the presence of an organophosphine modified cobalt hydroformylation catalyst, wherein the hydroformylation process is carried out in at least two reaction zones, wherein the at least two reaction zones comprise an earlier reaction zone and a later reaction zone, wherein the temperature of the later reaction zone is at least about 2° C. greater than the temperature in the earlier reaction zone, and the temperature of the later reaction zone is in the range of from about 140° C. to about 220° C., and the temperature of the earlier reaction zone is at least about 130° C.

    摘要翻译： 加氢甲酰化方法包括在有机膦改性的羰基羰基化催化剂的存在下使包含具有至少一个烯属碳 - 碳键的化合物与氢气和一氧化碳的原料组合物反应，其中加氢甲酰化方法在至少两个反应 区，其中所述至少两个反应区包含较早的反应区和较后的反应区，其中较晚的反应区的温度比较早的反应区中的温度高至少约2℃， 后一反应区的范围为约140℃至约220℃，较早反应区的温度为至少约130℃。

    Hydroformylation process
    9.
    发明授权
    Hydroformylation process 有权
    加氢甲酰化过程

    公开(公告)号：US08017811B2

    公开(公告)日：2011-09-13

    申请号：US12600700

    申请日：2008-05-22

    申请人： Wilhelmus Peter Mul

    发明人： Wilhelmus Peter Mul

    IPC分类号： C07C45/50

    CPC分类号： C07C29/16 ,  C07C2601/08 ,  C07C31/125 ,  C07C31/36 ,  C07C31/135 ,  C07C33/20

    摘要： A hydroformylation process for the production of alcohols comprising reacting, in a reactor system comprising one or more feed streams, a reaction environment and an output stream, a feedstock composition comprising a compound having at least one olefinic carbon-to-carbon bond with hydrogen and carbon monoxide in the presence of an organophosphine modified cobalt hydroformylation catalyst, wherein the hydroformylation process is carried out in the reaction environment, which comprises at least two reaction zones, wherein the at least two reaction zones comprise an earlier reaction zone and a later reaction zone, wherein the temperature of the later reaction zone is at a temperature which is at least 2° C. greater than the temperature in the earlier reaction zone, and the temperature of the later reaction zone is in the range of from 140° C. to 220° C., and the temperature of the earlier reaction zone is at least 130° C., wherein the molar ratio of hydrogen to carbon monoxide entering the earlier reaction zone is in the range of from 0.5 to 1.65, and wherein water is added into the reactor system.

    摘要翻译： 一种用于生产醇的加氢甲酰化方法，包括在包含一种或多种进料流的反应器系统，反应环境和输出流中反应原料组合物，其包含具有至少一个与碳的碳 - 碳键烯烃的化合物和 一氧化碳在有机膦改性的钴加氢甲酰化催化剂存在下，其中加氢甲酰化方法在包含至少两个反应区的反应环境中进行，其中至少两个反应区包含较早的反应区和较后的反应区 其中较晚的反应区的温度比在较早的反应区中的温度高至少2℃的温度，后一反应区的温度在140℃至 220℃，而较早的反应区的温度为至少130℃，其中氢与一氧化碳的摩尔比 较早的反应区域在0.5至1.65的范围内，并且其中将水加入到反应器系统中。