Preparation of lactones such as substituted delta valerolactones
    1.
    发明授权
    Preparation of lactones such as substituted delta valerolactones 失效
    乳液的制备如取代的三氯甲烷

    公开(公告)号:US3607885A

    公开(公告)日:1971-09-21

    申请号:US3607885D

    申请日:1968-08-15

    Inventor: DOMBRO ROBERT A

    CPC classification number: C07D315/00

    Abstract: Lactones may be prepared from alcohols by treating said alcohol with methyl alcohol in the presence of an alkaline substance and an oxidizing agent at an elevated temperature to prepare the desired product. Examples of such lactones are dimethyl, diphenyl, dicyclohexyl and di-p-tolyl-delta-valerolactones. These compounds have utility as solvents and as starting monomers in the preparation of polyester formulations, among other uses.

    Preparation of delta valero-lactones
    5.
    发明授权
    Preparation of delta valero-lactones 失效
    三角法的制备

    公开(公告)号:US3644426A

    公开(公告)日:1972-02-22

    申请号:US3644426D

    申请日:1969-08-15

    Inventor: DOMBRO ROBERT A

    CPC classification number: C07D315/00

    Abstract: LACTONES MAY BE PREPARED BY TREATING MERCAPTANS OR DISULFIDES WITH AN OXIDIZING AGENT SUCH AS DIMETHYL SULFOXIDE IN THE PRESENCE OF A POLAR SOLVENT SUCH AS AN ALCOHOL, IN AN ALKALINE SOLUTION, SUCH AS SODIUM HYDROXIDE AT AN ELEVATED TEMPERATURE. THUS, N-PROPYL MERCAPTAN CAN BE CONVERTED TO ALPHA, GAMMA-DIMETHYL DELTA-VALEROLACTONE.

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