摘要:
Disclosed are a hydrocarbon adsorption and desorption complex showing hydrocarbon adsorption and oxidation performance by controlling the cation ratio in zeolite, and a preparation method therefor. The hydrocarbon adsorption and desorption complex controls a cation ratio to exhibit the excellent hydrocarbon adsorption ability and oxidation performance even at a temperature lower than the catalyst activation temperature, and increases hydrothermal stability of the hydrocarbon adsorption and desorption complex through hydrothermal treatment to exhibit the excellent hydrocarbon adsorption and desorption performance even in a situation where water is present at a high temperature.
摘要:
This disclosure relates generally to vehicles with reduced emissions. More particularly, this disclosure relates to systems, methods, and apparatuses related to vehicles with reduced carbon dioxide emissions. The carbon dioxide emissions may be stored in a carbon dioxide clathrate.
摘要:
Hydrocarbon traps used to trap then release unburned hydrocarbons upon startup of a spark ignition internal combustion engine are sensitive to degradation if exposed to normal temperature exhaust gases. On board diagnostics of HC traps are provided by the invention, by incorporating a heat sensitive oxygen storage material in the HC trap material, and using conventional determination of OSC efficiency to determine if the HC trap material has been exposed to excessive temperature.
摘要:
The present invention describes an exhaust-gas purification system for an internal combustion engine made of an oxidation catalyst arranged close to the engine, a subsequent hydrocarbon adsorber and a particulate filter arranged downstream thereof and provided with another oxidation catalyst. The oxidation catalyst ensures that emission limits with respect to carbon monoxide and hydrocarbons are satisfied in normal driving mode. During operating states with exhaust-gas temperatures below about 200° C., the oxidation catalyst can no longer oxidize carbon monoxide and hydrocarbons. Instead, the hydrocarbons are adsorbed by the hydrocarbon adsorber during these operating phases. In order to initiate the periodical regeneration of the particulate filter, the exhaustgas temperature of the internal combustion engine is raised by engine modifications. The increased exhaust-gas temperature leads to desorption of the previously stored hydrocarbons, which are then burned at the oxidation catalyst of the particulate filter, thereby supporting the regeneration of the particulate filter.
摘要:
The device presents an ionization cell (14, 114) housed inside a casing (13, 113) fitted inside the exhaust conduit (6, 106) of the engine (5, 105); and the cell (14, 114) presents at least one circularly symmetrical cathode (23, 64) supplied by an electronic circuit to generate a discharge of negative ions at such a speed as to break the peripheral electron bonds of the toxic or pollutant component molecules of the exhaust gas. In an embodiment for spark-ignition combustion engines (5), the casing (13) presents two coaxial fittings (21, 22), each surrounded by a metal sponge filter (33) for storing the heat of the gas. In a further embodiment for diesel engines (105), the casing (113) presents an inverting chamber (47) for inverting the gas flow and located upstream from the ionization cell (114); and the gas is heated in the inverting chamber (47) by resistors (61) supplied by the battery. In a variation of the device, a further fitting is provided for feeding part of the purified, ionized exhaust gas back to the intake conduit of the engine to improve engine efficiency during cold-starting and when accelerating sharply.
摘要:
A change-over valve unit has a change-over valve for switching a bypass passage and an exhausting passage disposed in parallel therewith. An adsorbent is disposed in the bypass passage to adsorb exhaust components. An actuator of the change-over valve is isolated from an adsorption cylinder by a pedestal. Furthermore, rotary shafts of the control mechanism of the change-over valve are positioned within the bypass passage of the adsorber when the change-over valve is positioned to open the main exhaust passage. Thus, the heat of the exhaust gas flowing through the main exhaust passage is not transmitted to the rotary shafts.
摘要:
An apparatus for purifying an exhaust gas for an internal combustion engine having units for the adsorption of HC gases in the exhaust gas, arranged in an exhaust manifold of the engine facing corresponding exhaust ports in such a manner that straight flows from the corresponding exhaust ports contact the corresponding adsorption units. A controller receives a signal indicating a temperature of one of a catalytic converter and the adsorption units. The controller sends a signal to a cooling apparatus, such as a fan, indicating a desired on condition of the cooling apparatus based on the temperature signal. The cooling apparatus is provided for generating air flows for cooling the adsorption units. The fan is operated when the engine, in a cold state, is started. The operation of the fan is continued until a catalytic converter arranged downstream from the adsorption units becomes effective, i.e. the temperature of the catalytic converter is higher than a predetermined value.
摘要:
A reactor that can be attached to the exhaust manifold of a diesel or gasoline engine, or other internal combustion engines such as a jet engine or a gas turbine to oxidize and burn carbon soot particles, carbon monoxide, and unburned hydrocarbons, and to dissociate nitrogen and sulfur oxides. The reactor has a reaction zone that contains porous heat-retaining foam cells and that is bounded by a porous heat-retaining zone, which in turn is surrounded by ceramic insulation materials to minimize energy losses. Engine exhaust at elevated temperatures and containing some oxygen (air) enters the reaction chamber. By means of impinging heat transfer, thermal radiation enhancement, energy trapping and combustion of engine emissions, temperatures sufficient to oxidize carbon soot particles, carbon monoxide, and unburned hydrocarbons are attained. Harmless product of the oxidation reactions, H.sub.2 O and CO.sub.2 are released from the reactor.
摘要:
This invention relates to a process for minimizing hydrocarbon emissions from the exhaust streams of engines when the engines are first started, i.e., cold start. The process involves sequentially flowing the engine exhaust stream, which typically contains hydrocarbons, carbon monoxide and nitrogen oxide pollutants over a catalyst, the turbine side of a turbocharger and an adsorbent bed before discharging it into the atmosphere. The initial low temperature of the exhaust stream necessitates the use of the adsorbent bed. When the adsorbent bed (containing one or more molecular sieve beds) warms up (about 150.degree. C. to about 200.degree. C.), the majority of the exhaust stream is diverted around the adsorbent bed, while a minor portion is used to desorb the hydrocarbons adsorbed on the adsorbent bed and flowing these hydrocarbons through the compressor side of the turbocharger and then into the engine exhaust stream in front of the catalyst. When all the hydrocarbons are desorbed, the adsorbent bed is completely bypassed. The turbocharger lowers the temperature of the exhaust stream allowing hydrocarbons to be adsorbed for a longer period of time. The molecular sieves used in the invention are those that: 1) have a framework Si:Al ratio of at least 2.4; 2) are hydrothermally stable and 3) have a hydrocarbon selectivity greater than 1.
摘要:
A selective catalytic reduction catalyst for the treatment of an exhaust gas stream of a passive ignition engine, the catalyst comprising a porous wall-flow filter substrate comprising an inlet end, an outlet end, a substrate axial length (w) extending between the inlet end and the outlet end, and a plurality of passages defined by porous internal walls of the porous wall flow filter substrate; wherein the catalyst further comprises a first coating, said first coating extending over x % of the substrate axial length from the inlet end toward the outlet end of the substrate, x being in the range of from 10 to 100, wherein the first coating comprises copper and an 8-membered ring pore zeolitic material; wherein the catalyst further comprises a second coating, the second coating extending over y % of the substrate axial length from the outlet end toward the inlet end of the substrate, y being in the range of from 20 to 90, wherein the second coating comprises copper, and optionally an 8-membered ring pore zeolitic material; wherein the catalyst optionally further comprises a third coating; wherein x+y is at least 90; wherein y % of w from the outlet end toward the inlet end of the substrate define the outlet zone of the coated substrate and (100−y) % of w from the inlet end toward the outlet end of the substrate define the inlet zone of the coated substrate; wherein the ratio of the loading of copper in the inlet zone, Cu(in), calculated as CuO, relative to the loading of copper in the outlet zone, Cu(out), calculated as CuO, Cu(in):Cu(out), is less than 1:1.